93 Np Neptunium 237*
Actinide f-block Period 7 Radioactive

Neptunium

Np · Element 93

The first transuranic element, made by bombarding uranium with neutrons in 1940.

STATE AT 20°C Solid
ATOMIC MASS 237 u
ELECTRON CONFIGURATION [Rn] 5f⁴ 6d¹ 7s²

Structure

The neptunium atom

Not a diagram of dots on rings — a Monte-Carlo sample of the actual probability density |ψ|² for each occupied subshell. Drag to rotate. Blue and violet mark opposite signs of the wavefunction, which is what makes bonding possible.

Orbital cloud

Measured values

Property sheet

Every bar shows where neptunium sits among all 118 elements for that property.

Physical

Density 20.45 g/cm³ 89%
Melting point 917 K 39%
Boiling point 4300 K 86%
Specific heat 0.12 J/g·K
Thermal conductivity 10 W/m·K 25%

Atomic

Atomic radius 156 pm 50%
Covalent radius 190 pm
Van der Waals radius 239 pm

Electronic

Electronegativity 1.36 41%
Ionisation energy 605 kJ/mol 35%
Electron affinity 48.2 kJ/mol 31%

Occurrence

Abundance in crust 0 mg/kg 0%

Identity

SymbolNp
Atomic number93
Atomic mass237 u
CategoryActinide
Blockf
Crystal structureorthorhombic
Oxidation states+3, +4, +5, +6
Discovered1940
Discovered byMcMillan & Abelson

Sources: IUPAC 2021 standard atomic weights · CRC Handbook of Chemistry and Physics · NIST. Values marked ~ are predicted rather than measured.

Size, to scale

How big is a neptunium atom?

Radius 156 pm — that is 0.156 nm, so about 3205 million of them side by side would span a millimetre.

Thermal range

Solid, liquid, gas — and when

Neptunium is liquid over a 3383 K window, from 917 K to 4300 K.

Where it sits

Position in the table

Neptunium sits in the actinide series, printed below the main grid.

OTHER ACTINIDES

All actinides

The story

What neptunium is, and how we found it

The first transuranic element, made by bombarding uranium with neutrons in 1940.

The discovery of neptunium

Historic Discovery - 1940

Edwin McMillan and Philip Abelson at the University of California, Berkeley, made history by discovering the first transuranium element on May 27, 1940. This groundbreaking achievement opened the door to an entire new class of superheavy elements.

The Breakthrough Experiment

Cyclotron Innovation: Using Berkeley"s powerful cyclotron, McMillan bombarded uranium-238 with neutrons, expecting to create more uranium isotopes. Instead, they observed mysterious radioactive decay patterns that didn"t match any known element.

Chemical Detective Work: Abelson joined the project and used brilliant chemical analysis to separate the unknown element from uranium. They discovered that this new element had chemical properties similar to uranium but with distinct differences that proved it was element 93.

Naming the Element

Planetary Inspiration: The discoverers named the element "neptunium" after the planet Neptune, following the pattern established by uranium (named after Uranus). Since Neptune is the next planet beyond Uranus in our solar system, neptunium became the next element beyond uranium in the periodic table.

Manhattan Project Connection

Wartime Secrecy: The discovery was initially kept secret due to World War II and the Manhattan Project. Scientists realized that if neptunium could be created from uranium, it might lead to other synthetic elements with potential military applications.

Scientific Revolution: This discovery proved that elements heavier than uranium could exist and be synthesized in the laboratory, revolutionizing nuclear physics and chemistry. It earned McMillan the Nobel Prize in Chemistry in 1951.

Technical Achievement

Detection Challenge: The team had to detect neptunium despite its relatively short half-life and the presence of much more abundant uranium. Their innovative use of chemical separation techniques and radiation detection methods became the foundation for discovering all subsequent transuranium elements.

Applications

What neptunium is used for

Nuclear Research Applications

Neutron Detection Systems: Neptunium-237 serves as a crucial component in advanced neutron detection equipment used in nuclear facilities worldwide. Its unique nuclear properties make it invaluable for monitoring neutron flux in research reactors and helping scientists understand complex nuclear reactions.

Nuclear Fuel Cycle Research: Scientists use neptunium to study the behavior of actinide elements in nuclear fuel cycles. This research is essential for developing safer, more efficient nuclear power technologies and understanding long-term nuclear waste management strategies.

Space Exploration Technology

Radioisotope Power Systems: Neptunium-238 shows promise as a potential fuel for radioisotope thermoelectric generators (RTGs) in deep space missions. While not used operationally, research continues into its potential for powering spacecraft beyond the reach of solar energy.

Space Radiation Shielding: Studies of neptunium help scientists understand how heavy elements behave under intense cosmic radiation, contributing to the development of better radiation shielding for long-duration space missions to Mars and beyond.

Scientific Research

Fundamental Physics: Neptunium isotopes are used in cutting-edge research to understand the limits of nuclear stability and the properties of superheavy elements. This research pushes the boundaries of our understanding of atomic structure and nuclear physics.

Chemical Research: As the first transuranium element, neptunium serves as a model for studying the chemical behavior of the entire actinide series, helping chemists predict properties of even heavier, more exotic elements.

Nuclear Forensics

Nuclear Material Tracking: Neptunium signatures help nuclear forensics experts trace the origin and history of nuclear materials, playing a crucial role in nuclear security and non-proliferation efforts worldwide.

Limited Commercial Applications

Research Laboratory Standard: Neptunium-237 is primarily used as a reference standard in nuclear research laboratories for calibrating detection equipment and studying actinide chemistry. Its long half-life (2.14 million years) makes it valuable for long-term research projects.

Precursor for Plutonium Production: In specialized nuclear facilities, neptunium-237 can be converted to plutonium-238 through neutron bombardment, providing a source of Pu-238 for space applications and medical devices.

Specialized Research Tools

Neutron Source Applications: Small quantities of neptunium are used in neutron activation analysis, helping scientists determine the composition of various materials by analyzing the radiation emitted when they absorb neutrons.

Educational Demonstrations: Extremely small, carefully controlled samples are sometimes used in advanced university physics courses to demonstrate the properties of transuranium elements, though this requires extensive safety protocols.

Important Note: Neptunium has no consumer applications due to its radioactivity and rarity. All uses are restricted to specialized research facilities with proper radiation safety protocols.

Where it comes from

Natural occurrence

0 mg/kg of Earth's crust · more abundant than 0% of elements

Entirely Synthetic Element

No Natural Occurrence: Neptunium does not occur naturally on Earth in any detectable quantities. While trace amounts might theoretically be produced in uranium ore deposits through rare nuclear reactions, these quantities are so infinitesimally small that neptunium is considered entirely synthetic.

Laboratory Production

Cyclotron Synthesis: Neptunium is produced in particle accelerators by bombarding uranium-238 with neutrons or deuterons. The most common method involves neutron bombardment of U-238, which creates U-239 that then undergoes beta decay to form Np-239.

Nuclear Reactor Byproduct: Small amounts of neptunium are produced as a byproduct in nuclear reactors when uranium fuel undergoes neutron capture. However, these quantities are minimal and require extensive processing to isolate.

Global Production

Limited Worldwide Supply: Only a few specialized facilities worldwide can produce neptunium, with total global production measured in grams per year. The United States, Russia, and a few European facilities are the primary sources.

Cost and Rarity: Due to its synthetic nature and complex production process, neptunium is extremely expensive to produce, costing thousands of dollars per gram. This limits its use to essential research applications only.

Handling

Safety

Neptunium is radioactive. It has no stable isotope — every nucleus decays. Handling requires appropriate shielding and licensing.

significant radiation hazard in quantity

Alpha Emitter: Neptunium-237 emits dangerous alpha radiation with a half-life of 2.14 million years. While alpha particles cannot penetrate skin, they cause severe internal damage if neptunium dust is inhaled or ingested.

Inhalation Dangers

Respiratory Hazard: Neptunium particles can lodge in lung tissue, causing long-term radiation exposure and significantly increasing cancer risk. Even microscopic amounts pose serious health threats.

Protective Equipment: Work with neptunium requires specialized containment facilities, protective suits, respirators, and continuous air monitoring to prevent inhalation or skin contact.

Handling Protocols

Authorized Personnel Only: Only trained nuclear professionals with proper licensing and extensive safety training should handle neptunium. All work must be conducted in specially designed nuclear facilities with multiple containment barriers.

Emergency Procedures: Facilities must have immediate decontamination protocols and direct communication with specialized medical teams trained in radiation exposure treatment.

Quick answers

Neptunium: common questions

What is Neptunium?

Neptunium (symbol Np) is element 93 on the periodic table, a actinide in period 7. The first transuranic element, made by bombarding uranium with neutrons in 1940. At room temperature it is a solid, and it is radioactive.

What is the electron configuration of Neptunium?

Neptunium's ground-state electron configuration is [Rn] 5f⁴ 6d¹ 7s², giving 7 occupied shells holding 2, 8, 18, 32, 22, 9, 2 electrons respectively.

What are the melting and boiling points of Neptunium?

Neptunium melts at 917 K (643.9 °C) and boils at 4300 K (4026.9 °C).

What is the atomic mass of Neptunium?

Neptunium has no stable isotope, so it has no standard atomic weight. The figure quoted, 237, is the mass number of its longest-lived known isotope.

How dense is Neptunium?

Neptunium has a density of 20.45 g/cm³. Water is 1.0 g/cm³, so a block of neptunium is about 20.5× heavier.

What is the electronegativity of Neptunium?

Neptunium has a Pauling electronegativity of 1.36. The scale runs from 0.70 (francium, the least greedy for electrons) to 3.98 (fluorine, the most). Values in this middle band tend to form covalent rather than strongly ionic bonds.

Who discovered Neptunium, and when?

Neptunium was discovered in 1940 by McMillan & Abelson. It is named after the planet Neptune, next out from Uranus.

How common is Neptunium on Earth?

Neptunium does not occur naturally on Earth in any meaningful quantity — it is made in a reactor or an accelerator.

Is Neptunium radioactive?

Yes. Neptunium has no stable isotope — every one of its nuclei decays. Trace amounts occur naturally as decay products of heavier elements.