59 Pr Praseodymium 140.908
Lanthanide f-block Period 6

Praseodymium

Pr · Element 59

A rare earth that colours welder's goggles and, alloyed with neodymium, makes formidable magnets.

STATE AT 20°C Solid
ATOMIC MASS 140.908 u
ELECTRON CONFIGURATION [Xe] 4f³ 6s²

Structure

The praseodymium atom

Not a diagram of dots on rings — a Monte-Carlo sample of the actual probability density |ψ|² for each occupied subshell. Drag to rotate. Blue and violet mark opposite signs of the wavefunction, which is what makes bonding possible.

Orbital cloud

Measured values

Property sheet

Every bar shows where praseodymium sits among all 118 elements for that property.

Physical

Density 6.77 g/cm³ 38%
Melting point 1208 K 53%
Boiling point 3793 K 81%
Specific heat 0.193 J/g·K
Thermal conductivity 10.5 W/m·K 30%

Atomic

Atomic radius 182 pm 70%
Covalent radius 203 pm
Van der Waals radius 239 pm

Electronic

Electronegativity 1.13 14%
Ionisation energy 526.8 kJ/mol 9%
Electron affinity 48.2 kJ/mol 31%

Occurrence

Abundance in crust 9.2 mg/kg 68%

Identity

SymbolPr
Atomic number59
Atomic mass140.9077 u
CategoryLanthanide
Blockf
Crystal structurehexagonal
Oxidation states+3, +4
Discovered1885
Discovered byCarl Auer von Welsbach

Sources: IUPAC 2021 standard atomic weights · CRC Handbook of Chemistry and Physics · NIST. Values marked ~ are predicted rather than measured.

Size, to scale

How big is a praseodymium atom?

Radius 182 pm — that is 0.182 nm, so about 2747 million of them side by side would span a millimetre.

Thermal range

Solid, liquid, gas — and when

Praseodymium is liquid over a 2585 K window, from 1208 K to 3793 K.

Where it sits

Position in the table

Praseodymium sits in the lanthanide series, printed below the main grid.

OTHER LANTHANIDES

All lanthanides

The story

What praseodymium is, and how we found it

A rare earth that colours welder's goggles and, alloyed with neodymium, makes formidable magnets.

The discovery of praseodymium

The Discovery Story

1885 - The Austrian Connection

Carl Auer von Welsbach, an Austrian chemist and inventor, was studying didymium - a supposed element that had puzzled scientists for decades. Using the newly developed technique of fractional crystallization, he suspected didymium was not a single element.

The Great Separation

Through painstaking crystallization experiments, Welsbach successfully separated didymium into two distinct elements. The process required hundreds of recrystallizations and took months to complete.

Naming the "Green Twin"

Welsbach named one element "praseodymium" from the Greek words "prasios" (green) and "didymos" (twin), referring to its green salts and its twin relationship with neodymium, which he discovered simultaneously.

The Didymium Mystery

For over 40 years, scientists had been studying "didymium," thinking it was a single element. The mystery began in 1841 when Carl Mosander first separated it from cerium. The breakthrough came when Welsbach applied systematic spectroscopy to study the supposed element's properties.

"The spectroscope revealed lines that could not belong to a single element - the puzzle of didymium was finally solved."

— Carl Auer von Welsbach, 1885

Welsbach's Innovations

Carl Auer von Welsbach was not just a discoverer but an inventor whose work changed daily life:

  • Gas mantles: Invented the incandescent gas mantle using rare earth oxides
  • Lighter flints: Developed the cerium-iron alloy still used in cigarette lighters
  • Incandescent bulbs: Improved tungsten filaments for electric lighting

Scientific Impact

Welsbach's separation of praseodymium and neodymium proved that careful analytical chemistry could reveal hidden complexity in nature. His techniques became the foundation for separating all the rare earth elements.

Recognition and Legacy

Though Welsbach received numerous honors during his lifetime, including being made a baron by the Austrian Emperor, his contributions to rare earth chemistry are often overlooked. Modern high-tech industries owe their existence to his fundamental discoveries.

Applications

What praseodymium is used for

Advanced Industrial Applications

Praseodymium is the "color master" of the rare earth family, producing the most vibrant green colors in materials science. Its unique electronic structure makes it invaluable in optical and magnetic applications.

Glass & Ceramics Coloring

Praseodymium yellow-green is one of the most stable and vibrant colorants known to science. Unlike organic dyes that fade, praseodymium maintains its brilliant color for centuries. It's used in:

  • High-end architectural glass for landmark buildings
  • Art glass and stained glass for churches and museums
  • Specialty ceramics for luxury tableware
  • Protective eyewear for welders and glassworkers

Magnetic Materials

Praseodymium is crucial in manufacturing the world's strongest permanent magnets:

  • Neodymium-Praseodymium-Iron-Boron (NdPrFeB) magnets - stronger than pure neodymium magnets
  • Electric vehicle motors (Tesla, Nissan Leaf, Chevy Bolt)
  • Wind turbine generators for renewable energy
  • Hard disk drive actuators for data storage
  • MRI machine magnets for medical imaging

Lighting & Display Technology

Praseodymium's unique optical properties make it essential for:

  • Phosphors in energy-efficient lighting
  • Laser crystals for industrial cutting and medical procedures
  • Optical amplifiers in fiber optic communications
  • Specialized filters for photography and astronomy

High-Tech Applications

  • Quantum computing research - magnetic quantum bits
  • Superconducting materials for energy transmission
  • Nuclear reactor components for neutron detection
  • Specialty alloys for aerospace applications

Everyday Applications

Automotive Technology

  • Electric vehicle motor magnets (Prius, Model S)
  • Hybrid vehicle generators
  • Advanced headlight systems
  • Engine control sensors
  • Catalytic converter components

Consumer Electronics

  • Computer hard drive magnets
  • Smartphone speaker magnets
  • High-end headphone drivers
  • Camera lens elements
  • Gaming console components

Renewable Energy

  • Wind turbine generators
  • Solar panel tracking systems
  • Energy storage systems
  • Smart grid components
  • Electric bike motors

Decorative & Artistic

  • Art glass and sculptures
  • Luxury ceramic dinnerware
  • Architectural glass features
  • Jewelry and gemstone coloring
  • Stained glass windows

Professional Equipment

  • Welding safety glasses
  • Scientific instruments
  • Precision optical devices
  • Industrial laser systems
  • Analytical equipment

Market Dynamics

Praseodymium prices are highly volatile due to limited supply and growing demand from the electric vehicle industry. A typical electric car requires 200-600 grams of praseodymium in its various components.

Where it comes from

Natural occurrence

9.2 mg/kg of Earth's crust · more abundant than 68% of elements

Natural Distribution

Praseodymium is one of the rarer rare earth elements, making up only about 5% of all lanthanide content in ore deposits. Despite being "rare," it's still more abundant than silver or mercury.

Abundance Statistics

  • Earth's Crust: 9.2 parts per million (ppm)
  • Ranking: 39th most abundant element
  • Ocean Water: 6.4 × 10⁻⁷ ppm
  • Rare Earth Distribution: 5% of total lanthanides

Primary Mineral Sources

Bastnäsite

Chemical formula: (Ce,La,Pr,Nd)CO₃F
Pr content: 4-6%
Major source: Mountain Pass (USA), Bayan Obo (China)

Monazite

Chemical formula: (Ce,La,Nd,Th)PO₄
Pr content: 3-5%
Found in: Beach sand deposits, placer mines

Xenotime

Chemical formula: YPO₄ (with Pr substitution)
Pr content: 1-3%
Specialty source: Heavy mineral sands

Global Production

  • China: 85% of world production (Inner Mongolia, Jiangxi)
  • United States: Mountain Pass mine (rare earth revival)
  • Australia: Mount Weld project (developing capacity)
  • India: Orissa and Kerala beach sand operations
  • Brazil: Minas Gerais alkaline complexes
  • South Africa: Steenkampskraal mine (potential)

Geological Formation

Praseodymium forms in carbonatite complexes and alkaline igneous intrusions through extreme magmatic differentiation. The element concentrates during late-stage crystallization processes, often associated with fluorine-rich fluids.

Recycling Sources

  • End-of-life magnets from hard drives and motors
  • Manufacturing waste from magnet production
  • Electronic device recycling (speakers, sensors)
  • Automotive component recovery from hybrid vehicles

Recycling efficiency is low (5-10%) but improving rapidly due to rising prices and supply concerns.

Supply Chain Challenges

Praseodymium faces significant supply chain vulnerabilities due to geographic concentration of production and the technical difficulty of separation from other rare earth elements. Processing requires sophisticated chemical separation techniques.

Handling

Safety

Safety Information

Moderate Hazard Level

Praseodymium compounds require careful handling due to respiratory and skin sensitization risks, plus fire hazards with the metal form.

Fire and Reactivity Hazards

Praseodymium Metal: Highly pyrophoric when finely divided.

  • Can ignite spontaneously in air at room temperature
  • Reacts vigorously with water to produce hydrogen gas
  • Store under mineral oil or inert atmosphere
  • Class D fire extinguisher required (never use water!)

Respiratory Health Risks

  • Acute exposure: Respiratory tract irritation, coughing
  • Chronic exposure: Potential pneumoconiosis (lung scarring)
  • Sensitization: May cause allergic reactions in sensitive individuals
  • Protection: Use NIOSH-approved respirators with P100 filters

Skin and Eye Contact

  • Skin: May cause irritation and sensitization
  • Eyes: Severe irritation and potential corneal damage
  • Absorption: Limited skin absorption but prolonged contact should be avoided
  • PPE: Nitrile gloves and full-coverage safety glasses required

Emergency Response

Metal Fire

Use class D extinguisher or dry sand. Evacuate area. Never use water - causes violent reaction.

Inhalation

Remove to fresh air immediately. Monitor for delayed respiratory effects. Seek medical attention.

Eye Contact

Flush with clean water for 15 minutes. Hold eyelids open. Remove contacts if safe to do so.

Skin Contact

Wash thoroughly with soap and water. Remove contaminated clothing immediately.

Storage and Handling

  • Metal form: Store under mineral oil in sealed, inert containers
  • Compounds: Cool, dry storage away from acids and moisture
  • Incompatibles: Strong acids, oxidizers, and water
  • Ventilation: Use local exhaust ventilation when handling

Environmental Impact

Ecotoxicity: Praseodymium compounds can be toxic to aquatic life. Prevent release to waterways and soil. Dispose through licensed hazardous waste facilities only.

Special Handling Equipment

  • Inert atmosphere glove boxes for metal handling
  • Explosion-proof electrical equipment in work areas
  • Emergency shower and eyewash stations nearby
  • Class D fire extinguishers readily available

Quick answers

Praseodymium: common questions

What is Praseodymium?

Praseodymium (symbol Pr) is element 59 on the periodic table, a lanthanide in period 6. A rare earth that colours welder's goggles and, alloyed with neodymium, makes formidable magnets. At room temperature it is a solid.

What is the electron configuration of Praseodymium?

Praseodymium's ground-state electron configuration is [Xe] 4f³ 6s², giving 6 occupied shells holding 2, 8, 18, 21, 8, 2 electrons respectively.

What are the melting and boiling points of Praseodymium?

Praseodymium melts at 1208 K (934.9 °C) and boils at 3793 K (3519.9 °C).

What is the atomic mass of Praseodymium?

The standard atomic weight of Praseodymium is 140.908 u. That is a weighted average across its naturally occurring isotopes, which is why it is rarely a whole number.

How dense is Praseodymium?

Praseodymium has a density of 6.77 g/cm³. Water is 1.0 g/cm³, so a block of praseodymium is about 6.8× heavier.

What is the electronegativity of Praseodymium?

Praseodymium has a Pauling electronegativity of 1.13. The scale runs from 0.70 (francium, the least greedy for electrons) to 3.98 (fluorine, the most). A value this low means it readily gives its outer electrons away, forming positive ions.

Who discovered Praseodymium, and when?

Praseodymium was discovered in 1885 by Carl Auer von Welsbach. It is named after greek prasios didymos, "green twin".

How common is Praseodymium on Earth?

Praseodymium makes up about 9.2 mg/kg of the Earth's crust — uncommon, but not rare.