61 Pm Promethium 145*
Lanthanide f-block Period 6 Radioactive Synthetic

Promethium

Pm · Element 61 · Lanthanide

The only lanthanide with no stable isotope — it decayed away and had to be made in a reactor.

State at 20°C Solid
Atomic mass 145 u
Electron configuration[Xe] 4f⁵ 6s²

Structure

The promethium atom

Not a diagram of dots on rings — a Monte-Carlo sample of the actual probability density |ψ|² for each occupied subshell. Drag to rotate. Blue and violet mark opposite signs of the wavefunction, which is what makes bonding possible.

Orbital cloud

Measured values

Property sheet

Every bar shows where promethium sits among all 118 elements for that property.

Physical

Density 7.26 g/cm³ 46%
Melting point 1315 K 57%
Boiling point 3273 K 68%
Specific heat 0.18 J/g·K
Thermal conductivity 17.9 W/m·K 45%

Atomic

Atomic radius 183 pm 72%
Covalent radius 199 pm
Van der Waals radius 236 pm

Electronic

Electronegativity 1.13 14%
Ionisation energy 538.4 kJ/mol 13%
Electron affinity —

Occurrence

Abundance in crust 0 mg/kg 0%

Identity

SymbolPm
Atomic number61
Atomic mass145 u
CategoryLanthanide
Blockf
Crystal structurerhombohedral
Oxidation states+3
Discovered1945
Discovered byMarinsky, Glendenin & Coryell

Sources: IUPAC 2021 standard atomic weights · CRC Handbook of Chemistry and Physics · NIST. Values marked ~ are predicted rather than measured.

Same element, different neutrons

Isotopes of promethium

All promethium atoms have the same number of protons, 61, and differ only in their number of neutrons: those variants are its isotopes. None of them is stable. The longest-lived known isotope, Pm-145, has 84 neutrons and a half-life of 17.7 yrs.

Long-lived and well-known isotopes of promethium
ISOTOPE Neutrons Natural Abundance Half-life Decay Mode
Pm-143 82 — 265 days ε/β⁺
Pm-144 83 — 363 days ε/β⁺
Pm-145 longest-lived 84 — 17.7 yrs ε
Pm-146 85 — 5.53 yrs ε (65.7%), β⁻ (34.3%)
Pm-147 86 — 2.6234 yrs β⁻

Here the classroom shortcut, rounded atomic mass (145) minus atomic number, gives the same answer: 84.

Decay modes

ε
electron capture
β⁺
positron emission
β⁻
beta-minus decay

Data: IAEA Nuclear Data Section, LiveChart of Nuclides, ground-state evaluations, retrieved October 10, 2026. Abundance is the share of atoms in the natural element; a dash means the isotope has no standard natural abundance.

Size, to scale

How big is a promethium atom?

Radius 183 pm — that is 0.183 nm, so about 2.73 million of them side by side would span a millimetre.

Thermal range

Solid, liquid, gas — and when

Promethium is liquid over a 1958 K window, from 1315 K to 3273 K.

Where it sits

Position in the table

Promethium sits in the lanthanide series, printed below the main grid.

Other lanthanides

All lanthanides

The story

What promethium is, and how we found it

The only lanthanide with no stable isotope — it decayed away and had to be made in a reactor.

The discovery of promethium

🔍 The Missing Element Mystery

Brauner's Prediction (1902)

In 1902 Bohuslav Brauner noticed that neodymium and samarium differed more than any other neighbouring rare earths and proposed an element between them. For over 40 years, this remained chemistry's most elusive missing piece.

False Claims and Confusion (1900s-1920s)

Several scientists predicted or claimed element 61:

  • 1902: Bohuslav Brauner predicted an element between neodymium and samarium
  • 1914: Henry Moseley's X-ray studies suggested its existence
  • 1924: Italian scientists claimed isolation from Brazilian monazite

All discovery claims were later proven incorrect due to inadequate separation techniques and contamination with neighboring elements.

The Oak Ridge Breakthrough (1945)

Charles Coryell, Jacob Marinsky, and Lawrence Glendenin at Oak Ridge National Laboratory finally isolated element 61 from uranium fission products during the Manhattan Project. Using advanced ion-exchange chromatography, they definitively identified and separated the radioactive element.

Naming Controversy (1945-1950)

The discoverers initially proposed "clintonium" after Clinton Laboratories; Grace Mary Coryell, Charles Coryell's wife, suggested "prometheum", later spelled promethium, after Prometheus, the Greek Titan who stole fire from the gods - symbolizing humanity's mastery over nuclear fire.

Scientific Validation

The discovery was confirmed through:

  • Beta radiation analysis showing characteristic decay patterns
  • X-ray crystallography of promethium compounds
  • Mass spectrometry confirming the isotope promethium-147
  • Chemical separation proving lanthanide properties
⚡ Historical Impact: Promethium's discovery marked the completion of the lanthanide series and demonstrated that all gaps in the periodic table below uranium could be filled through nuclear synthesis.

Applications

What promethium is used for

🚀 Advanced Nuclear Applications

Promethium, the only radioactive rare earth element with no stable isotopes, serves unique roles in specialized nuclear technologies. Promethium-147 generates beta radiation with a relatively safe energy level (225 keV), making it useful for small nuclear (betavoltaic) batteries with a useful life of about five years.

Space Exploration Technology

NASA's deep-space radioisotope thermoelectric generators (RTGs) run on plutonium-238; promethium has only been proposed as an auxiliary power source for probes. These compact power sources provide decades of reliable electricity for instruments on missions to Saturn, Uranus, and interstellar space.

Medical Research Applications

Promethium-147 has no established role in nuclear medicine; as a nearly pure beta emitter it cannot be imaged.

Precision Instrumentation

High-end scientific instruments employ promethium as a thickness gauge for measuring extremely thin materials in semiconductor manufacturing. The consistent beta emission provides precise measurements critical for quality control in microelectronics production.

Specialized Lighting Systems

Emergency exit signs and aircraft instrument panels utilize promethium's phosphorescent properties, where beta radiation excites phosphor coatings to produce self-powered illumination lasting years without external power sources.

⚠️ Special Handling Required: All promethium applications require strict radiation safety protocols and specialized containment systems due to its radioactive nature.

🔬 Specialized Scientific Uses

Nuclear Batteries

Promethium-147 powers betavoltaic cells used in pacemakers, remote weather stations, and scientific equipment in harsh environments. These batteries have a useful lifetime of about five years, their output halving every 2.6 years, making them invaluable for inaccessible installations.

Luminous Paint Technology

Military and aviation industries use promethium-based radioluminescent paint for instrument dials, compass markings, and emergency lighting systems. The self-luminous property eliminates dependence on external light sources in critical applications.

Research Laboratory Equipment

Scientific research facilities employ promethium sources for beta radiation calibration of detection equipment, ensuring accurate measurements in nuclear physics experiments and environmental monitoring systems.

Quality Control Systems

Manufacturing industries utilize promethium-147 in thickness monitoring systems for paper, plastic, and metal sheet production, providing real-time quality assurance without physical contact with materials.

🚀 Emerging Applications

  • Micro-nuclear batteries for Internet of Things (IoT) sensors
  • Deep-sea exploration equipment power sources
  • Autonomous vehicle sensor calibration systems
  • Space habitat emergency lighting systems

Where it comes from

Natural occurrence

0 mg/kg of Earth's crust · more abundant than 0% of elements

🧪 Unique Synthetic Origin

No Natural Stability

Promethium holds the distinction of being the only lanthanide with no stable isotopes. Unlike other rare earth elements found in mineral deposits, promethium exists naturally only in trace amounts as a fission product in uranium ores, with concentrations so minimal they're virtually undetectable.

Nuclear Reactor Production

Virtually all promethium used today originates from nuclear reactor operations. The most useful isotope, Promethium-147, is produced by neutron bombardment of neodymium-146 in specialized research reactors, yielding approximately 1-2 grams per year globally.

Stellar Nucleosynthesis

In the cosmos, promethium forms during stellar nuclear processes but decays too rapidly to accumulate in detectable quantities. Astronomers have identified promethium spectral lines in certain variable stars, providing insights into stellar interior conditions and nucleosynthesis mechanisms.

Uranium Decay Chain

Spontaneous fission of natural uranium-238, and rare alpha decay of europium-151, occasionally produce promethium isotopes, but these decay within years to decades. Even in the most uranium-rich deposits, promethium makes up only about 4 parts per quintillion by mass (about 4 × 10⁻¹⁵ grams per kilogram of ore).

Laboratory Synthesis

Research facilities produce promethium through:

  • Neutron activation of neodymium targets
  • Ion bombardment of samarium samples
  • Separation from nuclear reactor fission products
  • Particle accelerator synthesis for research quantities
💎 Rarity: Promethium is considered one of the rarest elements on Earth, with total global inventory estimated at less than 1 kilogram at any given time.

Handling

Safety

Promethium is radioactive. It has no stable isotope — every nucleus decays. Handling requires appropriate shielding and licensing.

☢️ Radiation Safety Critical

Radiation Hazards

Primary Risk: Promethium-147 emits beta radiation (electrons) with maximum energy of 225 keV. While external exposure is relatively low-risk due to beta particles' limited penetration, internal contamination poses serious health threats.

Personal Protective Equipment

  • Laboratory coat and nitrile gloves (double-layered)
  • Safety glasses with side shields
  • Respiratory protection when handling powders
  • Personal dosimetry badges required

Handling Procedures

Work must be conducted in radiological fume hoods with negative pressure. Use remote handling tools when possible. Never eat, drink, or apply cosmetics in promethium work areas. Maintain strict inventory control of all sources.

Contamination Prevention

Work surfaces must be covered with absorbent plastic-backed paper. Monitor hands, clothing, and work areas with radiation detection equipment before leaving the laboratory. Decontaminate surfaces with appropriate cleaning solutions.

Emergency Procedures

Contamination incidents: Immediately notify radiation safety officer. Remove contaminated clothing and shower thoroughly. Seek medical evaluation for potential internal exposure. Spill cleanup requires specialized procedures and equipment.

Storage Requirements

Store in shielded containers within locked, posted radiological areas. Maintain temperature logs and visual inspection schedules. Sources must be inventoried and leak-tested at the intervals the license sets, typically at least every six months for sealed sources.

🚨 Emergency: Contact institutional radiation safety officer immediately for any promethium-related incidents or suspected contamination.

Quick answers

Promethium: common questions

What is promethium?

Promethium (symbol Pm) is element 61 on the periodic table, a lanthanide in period 6. The only lanthanide with no stable isotope — it decayed away and had to be made in a reactor. At room temperature it is a solid, and it is radioactive.

What is the electron configuration of promethium?

Promethium's ground-state electron configuration is [Xe] 4f⁵ 6s², giving 6 occupied shells with the distribution 2, 8, 18, 23, 8, 2.

What are the melting and boiling points of promethium?

Promethium melts at 1315 K (1041.9 °C) and boils at 3273 K (2999.9 °C).

What is the atomic mass of promethium?

Promethium has no stable isotope, so it has no standard atomic weight. The figure quoted, 145, is the mass number of its longest-lived known isotope.

How many neutrons does promethium have?

Promethium has no stable isotope. Its longest-lived known isotope, Pm-145, has 84 neutrons (mass number 145 minus atomic number 61) and a half-life of 17.7 yrs. The classroom shortcut, rounded atomic mass (145) minus atomic number, gives the same 84.

How dense is promethium?

Promethium has a density of 7.26 g/cm³. Water is 1.0 g/cm³, so a block of promethium is about 7.3× heavier.

What is the electronegativity of promethium?

Promethium has a Pauling electronegativity of 1.13. The scale runs from 0.70 (francium, the least greedy for electrons) to 3.98 (fluorine, the most). A value this low means it readily gives its outer electrons away, forming positive ions.

Who discovered promethium, and when?

Promethium was discovered in 1945 by Marinsky, Glendenin & Coryell. Origin of the name: Prometheus, who stole fire from the gods.

How common is promethium on Earth?

Promethium does not occur naturally on Earth in any meaningful quantity — it is made in a reactor or an accelerator.

Is promethium radioactive?

Yes. Promethium has no stable isotope — every one of its nuclei decays. It does not occur in usable quantities in nature and must be synthesised.