52 Te Tellurium 127.6
Metalloid p-block Period 5 Group 16

Tellurium

Te · Element 52 · Chalcogens

Rare on Earth, common in the universe, and the element that makes rewritable optical discs work.

STATE AT 20°C Solid
ATOMIC MASS 127.6 u
ELECTRON CONFIGURATION [Kr] 4d¹⁰ 5s² 5p⁴

Structure

The tellurium atom

Not a diagram of dots on rings — a Monte-Carlo sample of the actual probability density |ψ|² for each occupied subshell. Drag to rotate. Blue and violet mark opposite signs of the wavefunction, which is what makes bonding possible.

Orbital cloud

Measured values

Property sheet

Every bar shows where tellurium sits among all 118 elements for that property.

Physical

Density 6.24 g/cm³ 36%
Melting point 722.7 K 36%
Boiling point 1261 K 31%
Specific heat 0.202 J/g·K
Thermal conductivity 3 W/m·K 19%

Atomic

Atomic radius 139 pm 30%
Covalent radius 139 pm
Van der Waals radius 206 pm

Electronic

Electronegativity 2.1 74%
Ionisation energy 869.3 kJ/mol 78%
Electron affinity 190.1 kJ/mol 90%

Occurrence

Abundance in crust 0.001 mg/kg 32%

Identity

SymbolTe
Atomic number52
Atomic mass127.6 u
CategoryMetalloid
Blockp
Crystal structurehexagonal
Oxidation states-2, +2, +4, +5, +6
Discovered1783
Discovered byFranz-Joseph Muller von Reichenstein

Sources: IUPAC 2021 standard atomic weights · CRC Handbook of Chemistry and Physics · NIST. Values marked ~ are predicted rather than measured.

Size, to scale

How big is a tellurium atom?

Radius 139 pm — that is 0.139 nm, so about 3597 million of them side by side would span a millimetre.

Thermal range

Solid, liquid, gas — and when

Tellurium is liquid over a 538 K window, from 723 K to 1261 K.

Where it sits

Position in the table

Tellurium sits in period 5, group 16. Everything in group 16 shares the same outer-electron count, which is why they behave so similarly.

OTHER METALLOIDS

All metalloids

The story

What tellurium is, and how we found it

Rare on Earth, common in the universe, and the element that makes rewritable optical discs work.

The discovery of tellurium

The Accidental Discovery in Gold Country

Transylvania, 1782

Franz-Joseph Müller von Reichenstein, chief inspector of mines in Transylvania (now Romania), encountered a peculiar metallic ore in the Zlatna gold mines. Local miners called it "aurum paradoxum" (paradoxical gold) because it resembled gold but behaved strangely when processed.

The Chemical Detective Work

Müller spent three years investigating this mysterious substance:

  • 1782: Initial chemical tests showed it wasn't antimony, bismuth, or any known metal
  • 1783: Proved it contained a new metallic element combined with gold
  • 1784: Isolated the element but couldn't determine its exact nature
  • 1785: Published findings as "Tellurium" from Latin "tellus" (earth)
"This mineral contains a peculiar metal of a white color, not yet described, which I propose to call tellurium from the Latin word for earth." - Müller's original description

Berlin Confirmation

Martin Heinrich Klaproth (1798), the renowned German chemist who discovered uranium and zirconium, confirmed Müller's work. Klaproth independently isolated tellurium from the same Transylvanian ore and verified its elemental nature.

Early Misunderstandings

For decades, tellurium was confused with selenium due to similar properties:

  • Color Changes: Both elements formed colored compounds
  • Metalloid Behavior: Similar semiconductor properties
  • Chemical Similarity: Both belonged to the same chemical group
  • Rarity: Both were extremely rare in pure form

The Gold Connection Revealed

1860s Discovery: Geologists realized that tellurium-rich gold ores in places like Cripple Creek, Colorado, and Kalgoorlie, Australia, contained some of the world's richest gold deposits. Tellurides became synonymous with bonanza gold strikes.

Industrial Applications Emerge

  • 1900s: Tellurium used in cast iron and steel alloys for improved machinability
  • 1920s: Discovery of thermoelectric properties in bismuth telluride
  • 1940s: Military applications in infrared detection systems
  • 1960s: Semiconductor research revealed unique electronic properties

Solar Revolution

1970s Breakthrough: Scientists at the University of Delaware developed the first efficient cadmium telluride solar cells, launching tellurium's most important modern application. This discovery transformed an obscure metalloid into a critical material for renewable energy.

Digital Age Applications

1990s-2000s: Phase-change memory research revealed tellurium's unique ability to rapidly switch between crystalline and amorphous states, enabling:

  • Rewritable optical media (CDs, DVDs, Blu-ray)
  • Next-generation computer memory
  • High-speed data storage systems
From Mystery to Marvel: Tellurium's journey from a puzzling ore in Transylvanian gold mines to enabling solar energy and quantum computing shows how scientific curiosity about rare phenomena can lead to world-changing technologies!

Applications

What tellurium is used for

Solar Energy Revolution

Cadmium telluride (CdTe) solar cells represent one of the most cost-effective photovoltaic technologies, converting sunlight to electricity with over 22% efficiency. These thin-film solar panels require only 3-5 grams of tellurium per kilowatt, making large-scale solar deployment economically viable.

Thermoelectric Applications

  • Bismuth Telluride (Bi₂Te₃): Premier thermoelectric material for solid-state cooling and power generation
  • Peltier Coolers: CPU cooling, laser diode temperature control, and scientific instrumentation
  • Thermoelectric Generators: Converting waste heat to electricity in automotive and industrial applications
  • Space Applications: Radioisotope thermoelectric generators for deep space missions

Data Storage Technology

  • Phase-Change Memory (PCM): Ge₂Sb₂Te₅ (GST) alloys for next-generation computer memory
  • Blu-ray Discs: Tellurium alloys enable high-density optical data storage
  • DVD Technology: Silver-indium-antimony-tellurium for rewritable optical media
  • Holographic Storage: Advanced tellurium compounds for 3D data storage systems

Metallurgical Applications

  • Free-Machining Steel: 0.04-0.1% tellurium improves machinability and surface finish
  • Lead Alloys: Tellurium hardens lead for battery grids and cable sheathing
  • Copper Alloys: Improved electrical conductivity and corrosion resistance
  • Cast Iron: Tellurium refines grain structure and reduces chill depth

Chemical Catalysis

  • Rubber Vulcanization: Tellurium accelerators for high-temperature rubber applications
  • Oxidation Catalysts: Tellurium compounds in selective oxidation reactions
  • Polymerization: Tellurium-mediated radical polymerization for controlled polymer synthesis

Optical Applications

  • Infrared Optics: Zinc telluride windows for CO₂ laser systems
  • Electro-optic Devices: Cadmium telluride for infrared detection and imaging
  • Nonlinear Optics: Tellurium crystals for frequency conversion and optical switching
  • Fiber Optics: Tellurite glass fibers for mid-infrared laser delivery

Semiconductor Technology

  • Mercury Cadmium Telluride (HgCdTe): Premier infrared detector material for military and space applications
  • Topological Insulators: Bismuth telluride for quantum computing research
  • X-ray Detectors: Cadmium zinc telluride for medical imaging systems
  • Photovoltaic Research: Novel tellurium compounds for next-generation solar cells

Defense & Security

  • Thermal Imaging: Tellurium-based infrared sensors for night vision systems
  • Nuclear Detection: Cadmium telluride gamma-ray detectors for security screening
  • Missile Guidance: Infrared seekers using mercury cadmium telluride sensors
Future Technology: Tellurium enables the renewable energy transition, quantum computing advancement, and next-generation data storage - making it one of the most strategically important elements for 21st-century technology!

Tellurium in Daily Life

Renewable Energy

  • Solar Panels: Many commercial solar installations use cadmium telluride thin-film technology
  • Home Solar Systems: CdTe panels provide cost-effective residential solar power
  • Solar Calculators: Small CdTe cells power pocket calculators and watches
  • Garden Solar Lights: Tellurium-based photovoltaic cells in outdoor lighting

Digital Media & Storage

  • Blu-ray Players: Tellurium alloys enable high-definition movie storage and playback
  • Rewritable DVDs: Phase-change materials allow data to be written and erased multiple times
  • Computer Memory: Advanced tellurium-based memory in high-end electronics
  • Archival Storage: Long-term data preservation systems use tellurium compounds

Cooling & Temperature Control

  • Thermoelectric Coolers: Wine coolers, mini-fridges, and portable cooling devices
  • CPU Cooling: Computer processors use bismuth telluride thermoelectric coolers
  • Car Seat Coolers: Luxury vehicles with thermoelectric seat climate control
  • Medical Devices: Temperature-controlled sample storage and patient cooling systems

Automotive Applications

  • Precision Parts: Tellurium-enhanced steel for improved machining in engine components
  • Lead Batteries: Tellurium improves battery performance in some automotive applications
  • Thermal Management: Waste heat recovery systems using thermoelectric generators

Imaging & Detection

  • Security Cameras: Infrared night vision systems using tellurium-based detectors
  • Medical Imaging: X-ray detectors in hospitals and clinics
  • Thermal Cameras: Building inspection and energy auditing equipment
  • Fire Detection: Smoke and heat detectors with tellurium sensors
Invisible Impact: Tellurium is one of chemistry's most "invisible" elements - you benefit from it daily through solar power, digital storage, and cooling systems, yet most people have never heard of it!

Where it comes from

Natural occurrence

0.001 mg/kg of Earth's crust · more abundant than 32% of elements

Tellurium: Earth's Rarest Stable Element

Extreme Rarity

Tellurium is rarer than gold in Earth's crust, with an abundance of only 0.001 ppm (1 ppb). This extreme scarcity makes it one of the rarest stable elements, more than 1,000 times rarer than tin or antimony.

Primary Minerals

  • Tellurides: Tellurium typically occurs combined with metals rather than as native element
  • Calaverite (AuTe₂): Gold telluride, a major source in some gold mines
  • Sylvanite (AuAgTe₄): Gold-silver telluride found in epithermal deposits
  • Altaite (PbTe): Lead telluride in hydrothermal veins
  • Hessite (Ag₂Te): Silver telluride in precious metal deposits
  • Native Tellurium: Rare metallic crystals in oxidized zones

Commercial Sources

No primary tellurium mines exist - all commercial tellurium comes as a byproduct from:

  • Copper Refining (80%): Electrolytic copper refining produces tellurium-rich anode slimes
  • Lead Refining (15%): Lead smelting concentrates tellurium in dross and residues
  • Gold Mining (5%): Processing gold telluride ores yields tellurium concentrate

Global Production Centers

  • China (50%): Jiangxi Copper Company and other smelters dominate global production
  • Japan (20%): JX Nippon Mining recovers tellurium from copper refining
  • Russia (10%): Norilsk Nickel and other mining companies
  • United States (8%): Kennecott Utah Copper and ASARCO refineries
  • Canada (5%): Various copper and precious metal operations

Geochemical Behavior

Tellurium's chalcophile nature means it concentrates in sulfide minerals and follows sulfur in geological processes. Its extreme rarity results from:

  • Volatile Loss: Tellurium escaped to space during early Earth formation
  • Mantle Depletion: Preferential concentration in Earth's core
  • Hydrothermal Mobility: Easily dissolved and dispersed by hot fluids

Cosmic Abundance

In the universe, tellurium forms through s-process nucleosynthesis in asymptotic giant branch stars. Despite being cosmically rare, Earth's tellurium depletion makes it extraordinarily scarce compared to neighboring elements.

Supply Chain Criticality

  • Strategic Material: Limited supply constrains solar panel production
  • Recycling Efforts: CdTe solar panel recycling recovers valuable tellurium
  • Substitution Research: Scientists seek alternatives due to supply constraints
Rarity Perspective: If Earth's crust were a football field, tellurium would occupy less than the area of a pinhead - yet this incredibly rare element powers the renewable energy revolution!

Handling

Safety

Tellurium Safety Profile

Moderately Toxic - Unique Hazards

Tellurium and its compounds are moderately toxic, with some unique biological effects not seen with other elements. While less toxic than mercury or lead, tellurium requires careful handling and specific safety precautions.

Distinctive "Garlic Breath" Effect

Tellurium breath is the most characteristic effect of exposure:

  • Dimethyl Telluride: Body converts tellurium to volatile compound with strong garlic odor
  • Duration: Tellurium breath can persist for weeks after exposure ends
  • Detection: Serves as biological indicator of tellurium exposure
  • Low-hazard Indicator: The odor itself isn't dangerous but signals exposure

Respiratory & Systemic Effects

  • Inhalation: Tellurium dust causes respiratory irritation and pneumonia-like symptoms
  • Chronic Exposure: May lead to tellurium accumulation in liver and kidneys
  • Neurological: High doses potentially affect peripheral nervous system
  • Reproductive: Limited data suggests potential developmental effects

Workplace Safety

  • Exposure Limit: OSHA PEL of 0.1 mg/m³ for tellurium and compounds
  • Protective Equipment: Respirators, gloves, and eye protection required
  • Ventilation: Local exhaust systems for tellurium processing
  • Hygiene: Thorough handwashing and separate work clothing essential

Electronic Industry Safety

  • Semiconductor Fab: Tellurium compounds require specialized handling procedures
  • Solar Panel Manufacturing: CdTe production involves both tellurium and cadmium hazards
  • Recycling Operations: Electronic waste containing tellurium needs proper protocols

Consumer Product Safety

  • Solar Panels: Encapsulated CdTe poses minimal risk during normal use
  • Electronic Devices: Tellurium in memory devices is sealed and poses no exposure risk
  • Disposal: Electronic waste should be recycled through proper channels

Emergency Response

  • Inhalation: Remove to fresh air, monitor for respiratory symptoms
  • Skin Contact: Wash thoroughly with soap and water
  • Eye Contact: Flush with water for 15 minutes, seek medical attention
  • Ingestion: Contact poison control, do not induce vomiting
Safety Note: While tellurium requires caution in industrial settings, consumer exposure through solar panels and electronics is minimal. The distinctive "garlic breath" effect makes tellurium exposure easy to detect and monitor.

Quick answers

Tellurium: common questions

What is Tellurium?

Tellurium (symbol Te) is element 52 on the periodic table, a metalloid in period 5, group 16. Rare on Earth, common in the universe, and the element that makes rewritable optical discs work. At room temperature it is a solid.

What is the electron configuration of Tellurium?

Tellurium's ground-state electron configuration is [Kr] 4d¹⁰ 5s² 5p⁴, giving 5 occupied shells holding 2, 8, 18, 18, 6 electrons respectively. Its outer shell holds 6 electrons, which is what sets its bonding behaviour.

What are the melting and boiling points of Tellurium?

Tellurium melts at 722.7 K (449.5 °C) and boils at 1261 K (987.9 °C).

What is the atomic mass of Tellurium?

The standard atomic weight of Tellurium is 127.6 u. That is a weighted average across its naturally occurring isotopes, which is why it is rarely a whole number.

How dense is Tellurium?

Tellurium has a density of 6.24 g/cm³. Water is 1.0 g/cm³, so a block of tellurium is about 6.2× heavier.

What is the electronegativity of Tellurium?

Tellurium has a Pauling electronegativity of 2.1. The scale runs from 0.70 (francium, the least greedy for electrons) to 3.98 (fluorine, the most). Values in this middle band tend to form covalent rather than strongly ionic bonds.

Who discovered Tellurium, and when?

Tellurium was discovered in 1783 by Franz-Joseph Muller von Reichenstein. It is named after latin tellus, "earth".

How common is Tellurium on Earth?

Tellurium makes up about 0.001 mg/kg of the Earth's crust — genuinely rare, which is why it is expensive.