8 O Oxygen 15.999
Nonmetal p-block Period 2 Group 16

Oxygen

O · Element 8 · Chalcogens

The element that rusts iron, burns fuel and keeps you alive — and the most abundant element in the Earth's crust.

STATE AT 20°C Gas
ATOMIC MASS 15.999 u
ELECTRON CONFIGURATION [He] 2s² 2p⁴

Structure

The oxygen atom

Not a diagram of dots on rings — a Monte-Carlo sample of the actual probability density |ψ|² for each occupied subshell. Drag to rotate. Blue and violet mark opposite signs of the wavefunction, which is what makes bonding possible.

Orbital cloud

Measured values

Property sheet

Every bar shows where oxygen sits among all 118 elements for that property.

Physical

Density 0.001 g/cm³ 3%
Melting point 54.4 K 4%
Boiling point 90.2 K 6%
Specific heat 0.918 J/g·K
Thermal conductivity 0.03 W/m·K 6%

Atomic

Atomic radius 60 pm 3%
Covalent radius 66 pm
Van der Waals radius 152 pm

Electronic

Electronegativity 3.44 99%
Ionisation energy 1314.1 kJ/mol 95%
Electron affinity 140.9 kJ/mol 86%

Occurrence

Abundance in crust 461000 mg/kg 100%

Identity

SymbolO
Atomic number8
Atomic mass15.999 u
CategoryNonmetal
Blockp
Crystal structurecubic
Oxidation states-2, -1, 0, +1, +2
Discovered1774
Discovered byJoseph Priestley and Carl Wilhelm Scheele

Sources: IUPAC 2021 standard atomic weights · CRC Handbook of Chemistry and Physics · NIST. Values marked ~ are predicted rather than measured.

Size, to scale

How big is an oxygen atom?

Radius 60 pm — that is 0.06 nm, so about 8333 million of them side by side would span a millimetre.

Thermal range

Solid, liquid, gas — and when

Oxygen is liquid over a 36 K window, from 54 K to 90 K.

Where it sits

Position in the table

Oxygen sits in period 2, group 16. Everything in group 16 shares the same outer-electron count, which is why they behave so similarly.

OTHER NONMETALS

All nonmetals

The story

What oxygen is, and how we found it

The Breath of Life

Oxygen is the third most abundant element in the universe and the most abundant element in Earth's crust, comprising about 21% of our atmosphere and nearly 50% of the planet's mass. This highly reactive, colorless, and odorless gas is absolutely essential for most life forms on Earth through the process of cellular respiration.

Discovered independently by Carl Wilhelm Scheele and Joseph Priestley in the 1770s, oxygen revolutionized our understanding of combustion and respiration. Its name, derived from the Greek words "oxys" (acid) and "genes" (producer), reflects Antoine Lavoisier's mistaken belief that all acids contained oxygen.

Fun Fact: The oxygen we breathe today was largely produced by ancient cyanobacteria through photosynthesis over billions of years, fundamentally changing Earth's atmosphere and enabling complex life to evolve.

Oxygen exists in several allotropes, with dioxygen (O₂) being the form we breathe, and ozone (O₃) forming the protective layer in our stratosphere. In industry, oxygen supports combustion processes, steel production, and serves as an oxidizing agent in countless chemical reactions.

From the water we drink (H₂O) to the minerals in Earth's crust, oxygen forms compounds with virtually every other element, making it fundamental to chemistry, biology, and geology. Its unique electronic configuration gives oxygen its characteristic reactivity and ability to form double bonds, crucial for organic chemistry and life processes.

Applications

What oxygen is used for

Industrial Applications and Manufacturing

Steel and Metal Production

The largest industrial use of oxygen is in steel manufacturing, where it dramatically improves efficiency and quality:

  • Basic Oxygen Furnace (BOF) - Pure oxygen is blown through molten iron to remove carbon, producing high-quality steel in 30-40 minutes instead of hours
  • Electric Arc Furnace (EAF) - Oxygen injection increases melting rates and improves energy efficiency in recycling steel scrap
  • Cutting and welding - Oxy-acetylene and oxy-fuel torches reach temperatures over 3,500°C for precise metal cutting
  • Copper smelting - Oxygen enrichment reduces fuel consumption and increases production rates
  • Aluminum production - Oxygen helps remove impurities during aluminum refining processes

Chemical Manufacturing and Processing

Oxygen serves as a critical oxidizing agent in numerous industrial processes:

  • Ethylene oxide production - Direct oxidation of ethylene produces this key chemical intermediate for antifreeze and plastics
  • Vinyl chloride synthesis - Oxygen-based processes create the precursor for PVC plastic production
  • Propylene oxide manufacturing - Essential for producing polyurethane foams and propylene glycol
  • Titanium dioxide production - Oxygen helps create the white pigment used in paints, plastics, and paper
  • Hydrogen peroxide synthesis - Anthraquinone process uses oxygen to produce this versatile oxidizing agent

Pulp and Paper Industry

Oxygen revolutionized paper manufacturing through environmentally friendly bleaching:

  • Oxygen delignification - Removes lignin from wood pulp without chlorine compounds
  • Ozone bleaching - Generates bright white paper with minimal environmental impact
  • Hydrogen peroxide bleaching - Oxygen-based bleaching creates high-quality recycled paper
  • Biological treatment - Oxygen enhances bacterial breakdown of organic pollutants in paper mill wastewater

Wastewater Treatment and Environmental Applications

Oxygen-based technologies clean water and reduce pollution:

  • Activated sludge process - Aerobic bacteria use oxygen to break down organic pollutants
  • Ozonation - Ozone (O₃) destroys bacteria, viruses, and organic contaminants
  • Advanced oxidation processes - Hydroxyl radicals generated from oxygen compounds eliminate persistent pollutants
  • Groundwater remediation - Oxygen injection stimulates biodegradation of soil contaminants
  • Aquaculture - Oxygen injection maintains fish health in intensive farming operations

Aerospace and Rocket Propulsion

Liquid oxygen (LOX) is the most widely used rocket oxidizer:

  • Space Shuttle program - LOX and liquid hydrogen powered the main engines
  • SpaceX Falcon rockets - Use RP-1 fuel with liquid oxygen oxidizer
  • Blue Origin - BE-4 engines burn methane with liquid oxygen
  • Life support systems - Oxygen generation and recycling for spacecraft and space stations
  • Hypersonic flight - Scramjet engines use atmospheric oxygen for high-speed propulsion

Glass Manufacturing

Oxygen combustion improves glass production efficiency and quality:

  • Oxy-fuel furnaces - Pure oxygen combustion reaches higher temperatures with less fuel
  • Reduced emissions - Lower NOx production compared to air-fuel combustion
  • Improved glass quality - Higher temperatures enable better melting and homogenization
  • Energy efficiency - 15-50% reduction in fuel consumption compared to conventional furnaces

Medical and Healthcare Applications

Medical Oxygen Therapy

  • Respiratory therapy - Treating pneumonia, COPD, asthma, and COVID-19 patients
  • Emergency medicine - First-line treatment for shock, cardiac arrest, and severe trauma
  • Anesthesia - Carrier gas for inhaled anesthetics during surgery
  • Premature infant care - Carefully controlled oxygen levels in neonatal intensive care units
  • Home oxygen therapy - Portable concentrators for patients with chronic respiratory conditions
  • Hyperbaric oxygen therapy - High-pressure oxygen treatment for carbon monoxide poisoning and wound healing

Everyday Consumer Applications

  • Drinking water treatment - Ozonation purifies municipal water supplies worldwide
  • Swimming pool sanitation - Ozone generators provide chemical-free water disinfection
  • Air purification - Ozone generators eliminate odors in cars, homes, and hotels
  • Food preservation - Modified atmosphere packaging extends shelf life of fresh produce
  • Aquarium maintenance - Oxygen pumps and aerators maintain fish health
  • Wine production - Micro-oxygenation improves wine flavor and aging characteristics

Automotive and Transportation

  • Oxygen sensors - Lambda sensors optimize air-fuel ratios in modern engines
  • Catalytic converters - Use oxygen to reduce harmful emissions from vehicles
  • Emergency oxygen systems - Aircraft passenger oxygen masks for cabin depressurization
  • Automotive welding - Oxy-acetylene welding for vehicle repair and restoration
  • Racing applications - Nitrous oxide (N₂O) systems inject oxygen for engine power enhancement

Sports and Fitness

  • Athletic performance - Oxygen bars and canned oxygen for perceived performance enhancement
  • High-altitude training - Supplemental oxygen for acclimatization to thin air
  • Diving applications - Nitrox (oxygen-enriched air) extends underwater time limits
  • Recovery therapy - Post-exercise oxygen therapy claimed to reduce fatigue
  • Mountain climbing - Supplemental oxygen for extreme altitude expeditions

Beauty and Wellness

  • Oxygen facials - Spa treatments claiming to rejuvenate skin appearance
  • Oxygen therapy centers - Wellness facilities offering concentrated oxygen breathing
  • Hair care products - Hydrogen peroxide for hair bleaching and coloring
  • Teeth whitening - Hydrogen peroxide-based whitening treatments
  • Wound care - Hydrogen peroxide for cleaning minor cuts and scrapes

Art and Crafts

  • Glassblowing - Oxygen torches for shaping and manipulating glass
  • Jewelry making - Oxy-propane torches for soldering precious metals
  • Metal sculpture - Cutting and shaping steel and other metals
  • Pottery glazing - Oxidation atmospheres create specific glaze colors and effects
  • Blacksmithing - Oxygen injection into forges for higher temperatures

Scientific and Educational

  • Laboratory experiments - Studying combustion, oxidation, and cellular respiration
  • School demonstrations - Classic experiments showing oxygen's properties
  • Research applications - Controlled atmosphere chambers for biological studies
  • Analytical chemistry - Combustion analysis for determining organic compound composition
  • Environmental monitoring - Dissolved oxygen measurements in water quality testing

Where it comes from

Natural occurrence

461000 mg/kg of Earth's crust · more abundant than 100% of elements

Universal Abundance and Natural Sources

Cosmic and Stellar Origin

Oxygen is the third most abundant element in the universe, comprising approximately 1% of all atoms. It is primarily formed through stellar nucleosynthesis in massive stars:

  • Alpha process - Silicon burning in stars produces oxygen through fusion reactions
  • Helium burning - Triple-alpha process in red giant stars creates carbon, which fuses with helium to form oxygen
  • Supernova nucleosynthesis - Explosive stellar death disperses oxygen throughout galaxies
  • Stellar winds - Evolved stars continuously enrich interstellar medium with oxygen

The oxygen in our solar system formed approximately 4.6 billion years ago from the gravitational collapse of an oxygen-rich molecular cloud.

Atmospheric Abundance

Earth's atmosphere contains 20.946% oxygen by volume, representing the second most abundant atmospheric gas after nitrogen. This massive reservoir contains approximately 1.2 × 10¹⁵ tons of oxygen gas.

Amazing Fact: Virtually all atmospheric oxygen is biogenic - produced by photosynthetic organisms over billions of years. The Great Oxidation Event 2.4 billion years ago fundamentally changed Earth's atmosphere.

The atmospheric oxygen cycle involves constant exchange between:

  • Photosynthesis - Plants, algae, and cyanobacteria produce ~330 billion tons of O₂ annually
  • Respiration - Living organisms consume oxygen for cellular energy production
  • Combustion - Natural and human-caused fires consume atmospheric oxygen
  • Chemical weathering - Rock oxidation slowly removes oxygen from the atmosphere

Crustal and Lithospheric Abundance

Oxygen dominates Earth's crust, comprising approximately 46.1% by weight - making it the most abundant element in the solid Earth. Major oxygen-bearing minerals include:

Silicate Minerals (95% of crust)

  • Quartz (SiO₂) - Pure silicon dioxide, abundant in sandstone and granite
  • Feldspar group - Potassium, sodium, and calcium aluminosilicates
  • Pyroxene and amphibole - Iron, magnesium, and calcium silicates
  • Olivine ((Mg,Fe)₂SiO₄) - Dominant in Earth's upper mantle
  • Clay minerals - Hydrated aluminum and magnesium silicates

Oxide Minerals

  • Hematite (Fe₂O₃) - Primary iron ore mineral
  • Magnetite (Fe₃O₄) - Magnetic iron oxide
  • Corundum (Al₂O₃) - Aluminum oxide (sapphire and ruby)
  • Rutile (TiO₂) - Titanium dioxide
  • Cuprite (Cu₂O) - Copper oxide ore

Carbonate Minerals

  • Calcite (CaCO₃) - Primary component of limestone and marble
  • Dolomite (CaMg(CO₃)₂) - Calcium magnesium carbonate
  • Siderite (FeCO₃) - Iron carbonate

Hydrospheric Distribution

Water (H₂O) contains 88.8% oxygen by mass, making Earth's hydrosphere a massive oxygen reservoir:

  • Oceans - 1.37 billion km³ containing ~1.2 × 10¹⁶ tons of oxygen
  • Ice caps and glaciers - 24.4 million km³ of frozen water
  • Groundwater - 23.4 million km³ in aquifers worldwide
  • Lakes and rivers - 178,000 km³ of fresh surface water
  • Atmospheric water vapor - 12,900 km³ in constant circulation

Dissolved Oxygen in Natural Waters

Aquatic ecosystems depend on dissolved oxygen (DO) levels:

  • Cold freshwater - Up to 14.6 mg/L at 0°C (ice-cold mountain streams)
  • Temperate lakes - 8-12 mg/L seasonal variation due to temperature
  • Tropical waters - 6-8 mg/L in warm surface waters
  • Seawater - 6-8 mg/L, varying with temperature and salinity
  • Deep ocean - 2-6 mg/L in oxygen minimum zones

Biological Oxygen Production

Photosynthetic organisms are a leading source of Earth's oxygen:

  • Marine phytoplankton - Produce 50-85% of Earth's oxygen
  • Tropical rainforests - Amazon rainforest produces ~20% of atmospheric oxygen
  • Boreal forests - Northern coniferous forests contribute significantly
  • Grasslands and crops - Agricultural areas and prairies
  • Cyanobacteria - Blue-green algae in both marine and freshwater environments

Extraterrestrial Oxygen

Oxygen occurs throughout the solar system and universe:

  • Mars atmosphere - 0.13% oxygen, mostly from CO₂ photodissociation
  • Europa's atmosphere - Thin oxygen atmosphere from water ice radiolysis
  • Comets - Water ice contains frozen oxygen
  • Meteorites - Oxide minerals provide clues about early solar system
  • Exoplanet atmospheres - Oxygen signatures sought as potential biosignatures

Handling

Safety

Safety Information and Handling Precautions

EXTREME FIRE HAZARD: Oxygen greatly accelerates combustion and can cause explosive fires with oils, greases, and organic materials. Oxygen-enriched atmospheres make normally non-flammable materials burn violently.

Fire and Explosion Hazards

Oxygen's role in combustion creates severe safety risks:

  • Combustion acceleration - Materials burn 3-5 times faster in pure oxygen
  • Lowered ignition temperatures - Many materials ignite at much lower temperatures
  • Explosive potential - Oil and grease can explode on contact with high-pressure oxygen
  • Clothing fires - Synthetic fabrics become extremely flammable in oxygen-rich environments
  • Hot surfaces - Cigarettes, sparks, and hot metal can trigger violent combustion

High-Pressure Oxygen Hazards

DANGER: High-pressure oxygen systems can cause explosive decompression, severe burns, and death. Never use oxygen with oil or grease-contaminated equipment.

Compressed oxygen safety measures:

  • Cylinder handling - Secure upright, protect valves, use proper regulators
  • Pressure testing - Never exceed rated pressures, inspect equipment regularly
  • Clean systems - Oxygen-clean components free of oil, grease, and hydrocarbons
  • Compatible materials - Use only oxygen-compatible seals, lubricants, and components
  • Slow opening - Open valves slowly to prevent adiabatic heating

Medical Oxygen Safety

Healthcare oxygen administration requires careful monitoring:

  • Oxygen toxicity - High concentrations (>60%) for extended periods can damage lungs
  • Retinopathy of prematurity - Excessive oxygen can cause blindness in premature infants
  • Absorption atelectasis - 100% oxygen can cause lung collapse
  • Fire hazards - No smoking or open flames near oxygen therapy equipment
  • Proper dosing - Physician-prescribed flow rates and concentrations only

Occupational Exposure Limits

OSHA and regulatory standards for workplace oxygen:

  • Safe oxygen range - 19.5% to 23.5% in workplace atmospheres
  • Oxygen deficiency - Below 19.5% requires supplied air or evacuation
  • Oxygen enrichment - Above 23.5% creates fire and explosion hazards
  • Confined spaces - Continuous monitoring required in tanks, vessels, and enclosed areas
  • Hot work permits - Special precautions for welding and cutting in oxygen-enriched areas

Cryogenic Oxygen Hazards

Liquid oxygen (LOX) at -183°C presents additional dangers:

  • Severe frostbite - Instant tissue damage on skin contact
  • Vapor expansion - One liter of LOX expands to 860 liters of gas
  • Container pressure - Closed containers can explode from pressure buildup
  • Organic material reaction - LOX can detonate with organic materials
  • PPE requirements - Insulated gloves, safety glasses, and protective clothing

First Aid and Emergency Response

Emergency procedures for oxygen incidents:

  • Oxygen fire - Shut off oxygen source, evacuate area, call fire department
  • Oxygen toxicity - Reduce oxygen concentration, provide fresh air, seek medical attention
  • Cryogenic burns - Warm affected area gradually with lukewarm water
  • Eye contact with LOX - Flush with lukewarm water for 15 minutes
  • System leaks - Ventilate area, eliminate ignition sources, repair when safe

Environmental and Disposal Considerations

Environmental impact and waste management:

  • Atmospheric release - Oxygen can be safely vented to atmosphere
  • Water discharge - Dissolved oxygen beneficial to aquatic environments
  • Container disposal - Empty cylinders must be properly marked and recycled
  • Equipment decontamination - Proper cleaning procedures for oxygen service equipment
  • Spill response - LOX spills require evacuation and fire prevention measures

Transportation Safety

DOT regulations for oxygen transport:

  • Hazard classification - Class 2.2 (non-flammable gas) with oxidizer properties
  • Shipping requirements - Proper labeling, packaging, and documentation required
  • Vehicle restrictions - Limitations on tunnel passage and residential areas
  • Emergency response - CHEMTREC contact information for transportation incidents
  • Driver training - Special certification required for oxygen transport

Quick answers

Oxygen: common questions

What is Oxygen?

Oxygen (symbol O) is element 8 on the periodic table, a nonmetal in period 2, group 16. The element that rusts iron, burns fuel and keeps you alive — and the most abundant element in the Earth's crust. At room temperature it is a gas.

What is the electron configuration of Oxygen?

Oxygen's ground-state electron configuration is [He] 2s² 2p⁴, giving 2 occupied shells holding 2, 6 electrons respectively. Its outer shell holds 6 electrons, which is what sets its bonding behaviour.

What are the melting and boiling points of Oxygen?

Oxygen melts at 54.4 K (-218.8 °C) and boils at 90.2 K (-182.9 °C).

What is the atomic mass of Oxygen?

The standard atomic weight of Oxygen is 15.999 u. That is a weighted average across its naturally occurring isotopes, which is why it is rarely a whole number.

How dense is Oxygen?

Oxygen is a gas at room temperature; its density is about 1.4 g/L at 0 °C and 1 atm — roughly heavier than air.

What is the electronegativity of Oxygen?

Oxygen has a Pauling electronegativity of 3.44. The scale runs from 0.70 (francium, the least greedy for electrons) to 3.98 (fluorine, the most). A value this high means it tends to pull electrons away from almost anything it bonds with.

Who discovered Oxygen, and when?

Oxygen was discovered in 1774 by Joseph Priestley and Carl Wilhelm Scheele. It is named after greek oxys + genes, "acid-former".

How common is Oxygen on Earth?

Oxygen makes up about 46.1% of the Earth's crust — one of the most abundant elements there is.