68 Er Erbium 167.259
Lanthanide f-block Period 6

Erbium

Er · Element 68

The rare earth that keeps the internet running: erbium amplifies light inside fibre-optic cable.

STATE AT 20°C Solid
ATOMIC MASS 167.259 u
ELECTRON CONFIGURATION [Xe] 4f¹² 6s²

Structure

The erbium atom

Not a diagram of dots on rings — a Monte-Carlo sample of the actual probability density |ψ|² for each occupied subshell. Drag to rotate. Blue and violet mark opposite signs of the wavefunction, which is what makes bonding possible.

Orbital cloud

Measured values

Property sheet

Every bar shows where erbium sits among all 118 elements for that property.

Physical

Density 9.066 g/cm³ 59%
Melting point 1802 K 75%
Boiling point 3141 K 64%
Specific heat 0.168 J/g·K
Thermal conductivity 16.2 W/m·K 46%

Atomic

Atomic radius 175 pm 58%
Covalent radius 190 pm
Van der Waals radius 235 pm

Electronic

Electronegativity 1.24 25%
Ionisation energy 589.5 kJ/mol 28%
Electron affinity 48.2 kJ/mol 31%

Occurrence

Abundance in crust 3.5 mg/kg 64%

Identity

SymbolEr
Atomic number68
Atomic mass167.259 u
CategoryLanthanide
Blockf
Crystal structurehexagonal close-packed
Oxidation states+3
Discovered1843
Discovered byCarl Gustav Mosander

Sources: IUPAC 2021 standard atomic weights · CRC Handbook of Chemistry and Physics · NIST. Values marked ~ are predicted rather than measured.

Size, to scale

How big is an erbium atom?

Radius 175 pm — that is 0.175 nm, so about 2857 million of them side by side would span a millimetre.

Thermal range

Solid, liquid, gas — and when

Erbium is liquid over a 1339 K window, from 1802 K to 3141 K.

Where it sits

Position in the table

Erbium sits in the lanthanide series, printed below the main grid.

OTHER LANTHANIDES

All lanthanides

The story

What erbium is, and how we found it

The rare earth that keeps the internet running: erbium amplifies light inside fibre-optic cable.

The discovery of erbium

🔬 Swedish Chemical Mastery

Discovered by: Carl Gustaf Mosander in Stockholm, Sweden (1843)

Named after: Ytterby, Sweden - the famous quarry that provided four element names

🧪 The Systematic Separation

Erbium's discovery represents Carl Gustaf Mosander's masterful systematic approach to rare earth element separation. Working at the Karolinska Institute in Stockholm, Mosander had already discovered lanthanum and didymium when he turned his attention to the mineral gadolinite from Ytterby quarry in 1843.

Mosander suspected that the "yttria" fraction from gadolinite contained multiple unknown elements. Using his refined fractional crystallization techniques, he began the painstaking process of separating the mixed oxides. The work required exceptional patience - each crystallization cycle took weeks to complete, and hundreds of cycles were needed for meaningful separation.

⚗️ The Great Separation

Through systematic fractional crystallization of yttrium compounds, Mosander identified three distinct components: yttria (white), erbia (rose-colored), and terbia (yellow). His original assignment of colors to erbia and terbia was later reversed by other chemists, but his fundamental separation work remained valid.

Mosander named his rose-colored fraction "erbia" after Ytterby, continuing the tradition of honoring the remarkable Swedish locality that had already provided yttrium. Little did he know that this same mineral deposit would eventually yield four different element names.

🔬 Verification Challenges

Mosander's erbium discovery faced significant skepticism from contemporary chemists who doubted whether such subtle chemical differences could truly represent distinct elements. The chemical properties of erbium were so similar to other rare earths that many scientists questioned its elemental status.

Definitive proof of erbium's elemental nature came from spectroscopic analysis in the 1860s, when characteristic absorption lines provided unambiguous evidence of a unique element.

🏆 Ytterby's Legacy

The small Swedish quarry at Ytterby holds the unique distinction of providing names for four elements: yttrium, ytterbium, terbium, and erbium. No other location on Earth has contributed more element names, making Ytterby a pilgrimage destination for chemistry enthusiasts worldwide.

🔬 Modern Vindication

Mosander's careful 19th-century separation work laid the foundation for understanding lanthanide chemistry. His "erbia" - once considered merely a chemical curiosity - now enables global telecommunications infrastructure worth trillions of dollars. The element that Mosander painstakingly separated grain by grain now carries the world's internet traffic at the speed of light.

Pure metallic erbium wasn't isolated until 1934, nearly a century after Mosander's discovery, demonstrating the extraordinary technical challenges he overcame using only 19th-century analytical techniques.

Applications

What erbium is used for

The Internet's Backbone Element

Erbium has quietly become the unsung hero of global telecommunications, enabling the internet to function at the speed and capacity we depend on today. This remarkable rare earth element powers the fiber optic networks that carry virtually all international data, making it literally central for modern digital civilization.

🌐 Fiber Optic Communication Revolution

Erbium-doped fiber amplifiers (EDFAs) are the technological miracle that makes long-distance fiber optic communication possible. When excited by pump lasers, erbium ions amplify optical signals at the critical 1.55-micrometer wavelength where optical fibers have minimal signal loss. Without erbium amplifiers, your Netflix stream, video calls, and internet browsing would be impossible over distances greater than 40 kilometers.

Every transoceanic internet cable, every long-distance phone call, and virtually all high-speed internet traffic passes through erbium-doped amplifiers. These devices can amplify optical signals by factors of 1000 or more while maintaining perfect signal quality, enabling data transmission across continents at the speed of light.

🎯 Military & Defense Laser Systems

Erbium:glass lasers serve critical roles in military rangefinding and target designation systems. These eye-safe lasers operate at wavelengths that don't damage human vision, making them ideal for battlefield applications where both precision and safety are paramount. Advanced military systems use erbium lasers for missile guidance, terrain mapping, and covert communication systems.

🏥 Medical Laser Applications

Erbium:YAG lasers have revolutionized cosmetic and medical procedures, particularly in dermatology and dentistry. Operating at 2.94 micrometers, these lasers are perfectly absorbed by water in human tissue, enabling incredibly precise ablation with minimal thermal damage. Erbium lasers can remove wrinkles, scars, and damaged skin layer by layer with unprecedented control.

👓 Advanced Optical Materials

Erbium compounds enable sophisticated optical glass applications including specialized lenses, filters, and optical components. Erbium-doped glass can selectively absorb or emit specific wavelengths, creating custom optical filters for photography, astronomy, and scientific instrumentation.

💎 High-Performance Glass Coloring

Erbium creates beautiful pink coloration in glass and crystals, prized for decorative applications and optical filters. The characteristic erbium pink color results from specific electronic transitions that also enable its laser and amplification properties.

🔬 Scientific Research Applications

Erbium's unique optical properties make it invaluable for spectroscopy, quantum optics research, and advanced photonics applications. Researchers use erbium-based systems to study quantum mechanics, develop new laser technologies, and explore fundamental physics phenomena.

🌟 Connecting the Digital World

  • 🌍 Internet Infrastructure: Fiber optic amplifiers in undersea cables and long-distance networks
  • 📞 Telecommunications: Signal boosters in phone networks and data transmission systems
  • 🎖️ Military Equipment: Laser rangefinders, targeting systems, and secure communications
  • 💆 Medical/Cosmetic: Laser skin treatments, wrinkle removal, and dental procedures
  • 👓 Specialty Glass: Optical filters, safety glasses, and decorative glass coloring
  • 📡 Satellite Systems: Communication satellites and space-based laser systems

📈 Critical Infrastructure Material

Erbium demand is directly tied to global internet growth and fiber optic network expansion. With internet traffic doubling every 2-3 years, erbium has become a strategic material for national communications infrastructure.

💰 Market Dynamics

The global erbium market is valued at over $200 million annually, driven primarily by telecommunications infrastructure investment. 5G network deployment is creating new demand for erbium-based optical components.

🔬 Innovation Drivers

Emerging applications include quantum communication systems, advanced medical imaging, and next-generation computing technologies. Erbium's role in quantum internet development could make it even more strategically important.

🏭 Manufacturing Locations

Major erbium-doped fiber amplifier manufacturing occurs in Japan, South Korea, and China, making global supply chains dependent on Asian production capabilities. This concentration creates strategic vulnerabilities for global communications infrastructure.

Where it comes from

Natural occurrence

3.5 mg/kg of Earth's crust · more abundant than 64% of elements

🌍 Moderately Rare Global Distribution

Erbium occurs in Earth's crust at approximately 3.5 parts per million, making it roughly as abundant as tin and more common than most other heavy rare earth elements. Despite this relative abundance, economically viable erbium deposits remain geographically concentrated and technically challenging to process.

🏔️ Primary Mineral Sources

  • Xenotime: Yttrium phosphate mineral containing 5-25% erbium oxide
  • Monazite: Thorium-cerium phosphate with 2-8% heavy rare earth content
  • Bastnäsite: Rare earth carbonate fluoride in carbonatite deposits
  • Ion-adsorption clays: Weathered granite deposits enriched in heavy REEs

🌏 Major Global Sources

China (80% of global production): Bayan Obo mine in Inner Mongolia produces erbium as a byproduct of iron ore mining. Southern China's ion-adsorption clay deposits in Jiangxi and Guangdong provinces provide additional heavy rare earth sources with enhanced erbium content.

Australia: Mount Weld rare earth deposit contains significant erbium reserves within its bastnäsite ore body. Lynas Corporation processes this material to produce mixed rare earth concentrates.

Malaysia: Lynas Advanced Materials Plant processes Australian ore to produce separated rare earth oxides, including high-purity erbium oxide for telecommunications applications.

United States: Mountain Pass mine in California contains erbium-bearing bastnäsite, though current operations focus primarily on light rare earth production.

⚒️ Processing & Separation

Erbium separation requires sophisticated hydrometallurgical processes due to the chemical similarity of adjacent lanthanides. Solvent extraction using phosphonic acid extractants can selectively separate erbium from other heavy rare earths. Complete purification to telecommunications-grade purity (99.99%) requires dozens of extraction stages.

🌊 Alternative Sources

Seawater contains dissolved erbium at concentrations of 0.87 parts per billion. While extraction is not economical, advancing technology may eventually make marine sources viable for erbium recovery.

♻️ Recycling Opportunities

End-of-life fiber optic equipment and laser systems represent growing sources of recyclable erbium. Specialized processing can recover high-purity erbium from telecommunications equipment, though current recycling rates remain minimal due to collection challenges.

🔬 Quality Requirements

Telecommunications applications require ultra-high-purity erbium with minimal optical impurities. Iron, copper, and transition metal contamination must be reduced to parts-per-million levels to prevent optical absorption losses in fiber amplifiers.

Handling

Safety

⚠️ Telecommunications & Laboratory Safety

🟢 Low Hazard Classification

Erbium and its compounds present minimal toxicity risks under normal handling conditions. Standard laboratory safety procedures are adequate for most erbium applications, with special attention to laser safety in telecommunications systems.

🥽 Basic Protective Equipment

  • Eye Protection: Safety glasses for general handling, specialized laser goggles for optical systems
  • Hand Protection: Nitrile gloves for direct contact with compounds
  • Respiratory Protection: Dust mask when handling powdered materials
  • Clothing: Standard laboratory attire and closed-toe shoes

⚗️ Specific Precautions

Laser Safety: Erbium:glass and erbium:YAG lasers require Class 4 laser safety protocols. While erbium lasers are "eye-safe" compared to other wavelengths, they can still cause thermal injury at high power levels.

Optical Fiber Safety: Erbium-doped fiber systems can carry significant optical power. Never look directly into fiber ends or use optical instruments to examine active fibers.

🏥 Medical Application Standards

Medical-grade erbium lasers require additional safety measures including controlled access, warning signs, and specialized training for operators. Patient safety protocols must address both laser and chemical exposure risks.

🚨 Emergency Procedures

  • Eye Contact: Flush with clean water for 15 minutes, seek medical evaluation
  • Skin Contact: Wash with soap and water, remove contaminated clothing
  • Inhalation: Move to fresh air, monitor for respiratory irritation
  • Laser Exposure: Discontinue exposure immediately, seek medical attention if injury suspected

🗄️ Storage Guidelines

Store erbium compounds in tightly sealed containers in cool, dry conditions. Erbium-doped fibers and optical components require protection from mechanical damage and contamination. Maintain controlled temperature and humidity for precision optical devices.

♻️ Disposal Considerations

Erbium-containing waste should be segregated for potential recycling, particularly from high-value telecommunications equipment. Optical fibers and laser components may contain other hazardous materials requiring specialized disposal procedures.

📊 Workplace Monitoring

Recommended exposure limit: 5 mg/m³ as 8-hour time-weighted average for erbium compounds. Air monitoring recommended in manufacturing environments, particularly during powder handling operations.

Quick answers

Erbium: common questions

What is Erbium?

Erbium (symbol Er) is element 68 on the periodic table, a lanthanide in period 6. The rare earth that keeps the internet running: erbium amplifies light inside fibre-optic cable. At room temperature it is a solid.

What is the electron configuration of Erbium?

Erbium's ground-state electron configuration is [Xe] 4f¹² 6s², giving 6 occupied shells holding 2, 8, 18, 30, 8, 2 electrons respectively.

What are the melting and boiling points of Erbium?

Erbium melts at 1802 K (1528.9 °C) and boils at 3141 K (2867.9 °C).

What is the atomic mass of Erbium?

The standard atomic weight of Erbium is 167.259 u. That is a weighted average across its naturally occurring isotopes, which is why it is rarely a whole number.

How dense is Erbium?

Erbium has a density of 9.066 g/cm³. Water is 1.0 g/cm³, so a block of erbium is about 9.1× heavier.

What is the electronegativity of Erbium?

Erbium has a Pauling electronegativity of 1.24. The scale runs from 0.70 (francium, the least greedy for electrons) to 3.98 (fluorine, the most). Values in this middle band tend to form covalent rather than strongly ionic bonds.

Who discovered Erbium, and when?

Erbium was discovered in 1843 by Carl Gustav Mosander. It is named after ytterby, Sweden.

How common is Erbium on Earth?

Erbium makes up about 3.5 mg/kg of the Earth's crust — uncommon, but not rare.