21
Sc
Scandium

Scandium

Element 21 • Transition Metal
Atomic Mass 44.955912
Electron Config Unknown
Group/Period 3/4

Overview

ANALYZED
Meet Scandium - the ultra-rare "space age" metal that makes airplanes lighter and stronger! This silvery-white transition metal is so rare that only about 15 tons are produced worldwide each year, making it more expensive than gold. Discovered in 1879 by Swedish chemist Lars Fredrik Nilson, Scandium was actually predicted by Mendeleev who called it "eka-boron" before it was found. What makes Scandium absolutely incredible is its ability to create ultra-strong, lightweight alloys. When just 0.1-0.5% Scandium is added to aluminum, the resulting alloy becomes dramatically stronger while staying lightweight - perfect for aerospace applications. The Soviet Union secretly used Scandium-aluminum alloys in their MiG fighter jets, giving them a significant advantage in the Cold War. Scandium has the unique property of being both a transition metal and behaving somewhat like aluminum. It forms only one stable oxidation state (+3) and creates colorless compounds, unlike most transition metals that form colored compounds. This element is also paramagnetic and has one of the highest melting points among the lighter elements at 1,541°C. The name "Scandium" comes from "Scandia," the Latin name for Scandinavia, where it was first discovered in rare minerals. Today, Scandium is found in over 800 mineral species but never in concentrated amounts, making extraction extremely expensive and challenging. Here's something mind-blowing: Scandium is scattered throughout the Earth's crust at about 22 parts per million, making it more abundant than lead or mercury, yet it's incredibly difficult to extract economically. Most Scandium today comes as a byproduct of uranium and tungsten mining, or from rare earth element processing in China and Russia.

Physical Properties

MEASURED
Atomic Mass
44.955912 u
Melting Point
1814.00 °C
Boiling Point
3109.00 °C
Ionization Energy
6.56 kJ/mol

Special Properties

CLASSIFIED
STABLE Generally safe to handle with standard precautions

Applications

CATALOGUED

Scandium: The Aerospace Lightener

Scandium transforms aluminum from ordinary metal to aerospace marvel through precise alloying, creating the lightest high-strength materials available. This rare earth element's unique properties make it indispensable for cutting-edge applications despite its extreme cost and scarcity.

Aluminum-Scandium Alloys

Al-Sc alloys achieve unprecedented strength-to-weight ratios through Scandium's grain refinement effects. Adding just 0.1-0.3% Scandium to aluminum creates Al₃Sc precipitates that prevent grain growth during welding and heat treatment, maintaining strength at elevated temperatures. These alloys enable aerospace components weighing 15-20% less than traditional aluminum parts while providing superior fatigue resistance.

Aerospace Applications

Military aircraft like the MiG-29 and Su-57 utilize Scandium-aluminum components in critical structures, fuel tanks, and landing gear where weight reduction directly translates to improved performance and fuel efficiency. The Russian aerospace industry pioneered large-scale Scandium use, maintaining technological advantages in fighter aircraft design.

Sports Equipment Revolution

High-end baseball bats, bicycle frames, and lacrosse sticks incorporate Scandium alloys for professional and Olympic-level competition. A Scandium-aluminum baseball bat costs $400-800 but provides optimal "sweet spot" characteristics and durability that aluminum alone cannot achieve.

Solid Oxide Fuel Cells

Scandium-stabilized zirconia (ScSZ) electrolytes enable fuel cells operating at lower temperatures (650-750°C vs. 800-1000°C) with higher ionic conductivity. This application could revolutionize distributed power generation and electric vehicle range extenders, though Scandium's cost currently limits commercial deployment.

Common Uses

INDEXED

Scandium: Ultra-High-End Applications

  • Aerospace Industry
    • Military fighter aircraft components (MiG-29, Su-57)
    • Spacecraft structural elements
    • Satellite components requiring extreme light weight
    • Rocket engine components
  • Professional Sports Equipment
    • Olympic-level bicycle frames (Tour de France racing)
    • Professional baseball bats ($400-800 each)
    • High-end lacrosse sticks and hockey sticks
    • Tennis racquet frames for professionals
  • Energy Technology
    • Solid oxide fuel cell electrolytes
    • Advanced battery research applications
    • High-efficiency power generation systems
    • Experimental hydrogen storage systems
  • Lighting Technology
    • High-intensity discharge (HID) lamps
    • Stadium and arena lighting systems
    • Professional photography and film lighting
    • Specialty scientific instrumentation lighting
  • Research & Development
    • Advanced materials research
    • Superconductor research applications
    • High-temperature ceramics development
    • Next-generation alloy development

Natural Occurrence

SURVEYED

Scandium: Cosmically Rare

Scandium's cosmic journey begins in the nuclear cores of massive stars through silicon burning processes and neutron capture reactions. These stellar nucleosynthesis events occur during the final stages of stellar evolution, creating Scandium isotopes that disperse throughout the galaxy during supernova explosions, though in far smaller quantities than more common elements.

Terrestrial Scarcity

Earth's crust contains approximately 22 parts per million Scandium, making it more abundant than silver or mercury yet paradoxically one of the rarest commercially available elements. This paradox stems from Scandium's geochemical behavior - it rarely concentrates into economically viable ore deposits, instead dispersing widely through rock-forming minerals.

Mineral Occurrences

Thortveitite ((Sc,Y)₂Si₂O₇) represents the only known Scandium-rich mineral, containing up to 40% Scandium oxide. However, thortveitite occurs only in small quantities in Norwegian pegmatites and Madagascar deposits, making it insufficient for global Scandium demand.

Most commercial Scandium comes as a byproduct from uranium and titanium processing. The Bayan Obo rare earth deposit in China and certain Australian laterite deposits contain Scandium concentrations of 100-300 ppm, recovered through complex hydrometallurgical processes.

Global Distribution

Russia dominates global Scandium production from processing uranium mill tailings, producing 60-80% of the world's 15-20 tons annual supply. China produces Scandium from rare earth processing, while Australia develops new extraction methods from nickel and cobalt laterite deposits.

Red Mud Recovery

Aluminum production generates millions of tons of red mud waste containing 100-150 ppm Scandium. Research focuses on economical Scandium extraction from this abundant waste stream, potentially revolutionizing Scandium availability and reducing environmental impacts of aluminum processing.

Discovery

ARCHIVED
1879

Predicted by Patterns

Scandium's discovery exemplifies the power of Mendeleev's periodic table predictions, joining gallium and germanium as elements predicted before their actual identification. This rare earth element emerged from systematic spectroscopic analysis and theoretical chemistry.

Mendeleev's "Ekaboron" Prediction

In 1869, Dmitri Mendeleev identified a gap in his periodic table between calcium and titanium, predicting an unknown element he called "ekaboron" (meaning "beyond boron"). His predictions included:

  • Atomic weight: ~44 (actual Sc: 44.96)
  • Density: ~3.5 g/cm³ (actual: 2.99 g/cm³)
  • Forms oxide Eb₂O₃ (correct: Sc₂O₃)
  • Higher atomic weight than calcium

Nilson's Spectroscopic Discovery

Lars Fredrik Nilson (1840-1899), a Swedish chemist at Uppsala University, discovered scandium on October 21, 1879, while analyzing rare earth minerals from Scandinavia. Using the newly developed technique of emission spectroscopy, Nilson detected unknown spectral lines in samples of euxenite and gadolinite.

Nilson's meticulous work involved processing 10 kilograms of euxenite through repeated precipitation and crystallization steps, ultimately isolating 2 grams of scandium oxide (Sc₂O₃) as a white powder with unique spectroscopic properties.

Cleve's Confirmation

Per Teodor Cleve (1840-1905), Nilson's colleague at Uppsala, immediately recognized that Nilson's new element perfectly matched Mendeleev's ekaboron predictions. Cleve's systematic analysis confirmed scandium's atomic weight and chemical properties, providing another stunning validation of periodic law.

The Naming

Nilson named his discovery "scandium" after Scandinavia, honoring the region where the defining mineral samples originated. This naming reflected the strong tradition of honoring geographical origins in element nomenclature.

Isolation Challenges

Pure metallic scandium remained elusive until 1937, when Werner Fischer and colleagues at the Kaiser Wilhelm Institute achieved the first preparation through electrolysis of molten potassium, lithium, and scandium chlorides. The extreme difficulty of scandium metal production continues to limit its applications despite remarkable properties.

Safety Information

CRITICAL

Scandium Safety: Generally Low Risk

Scandium and its compounds exhibit relatively low

toxicity compared to other rare earth elements, though proper handling procedures remain essential due to limited toxicological data and potential respiratory irritation from dust exposure.

Biological Effects

Scandium shows low acute

toxicity with animal studies indicating LD₅₀ values exceeding 4 grams per kilogram for most Scandium compounds.
However, like other rare earth elements, Scandium can accumulate in liver and bone tissues with prolonged exposure. Scandium chloride demonstrates moderate
toxicity requiring careful handling protocols.

Occupational Exposure Guidelines

  • No established OSHA PEL for Scandium compounds
  • Recommended exposure limit: <1 mg/m³ for Scandium compounds (dust)
  • Respiratory protection: N95 minimum for dust; higher protection for fine particles
  • Eye protection: Safety glasses with side shields recommended

Handling Procedures

  • Dust Control: Use local exhaust ventilation when grinding or machining Scandium alloys
  • Personal Protection: Nitrile gloves for handling compounds; dust masks for powder operations
  • Storage: Store in cool, dry areas away from acids and strong oxidizers
  • Waste Disposal: Collect Scandium waste for recycling due to extreme value and scarcity

Fire and Reactivity

Scandium metal poses fire hazards when in powder form, potentially igniting in air or reacting violently with water. Scandium alloys generally exhibit excellent fire resistance, contributing to their aerospace applications where fire safety is paramount.

Emergency Procedures

Inhalation: Move to fresh air; seek medical attention for persistent respiratory irritation. Skin contact: Wash with soap and water; remove contaminated clothing. Eye contact: Flush with clean water for 15 minutes; seek medical attention if irritation persists. Ingestion: Rinse mouth with water; seek medical evaluation for significant amounts.

Knowledge Database

Essential information about Scandium (Sc)

Scandium is unique due to its atomic number of 21 and belongs to the Transition Metal category. With an atomic mass of 44.955912, it exhibits distinctive properties that make it valuable for various applications.

Scandium has several important physical properties:

Melting Point: 1814.00 K (1541°C)

Boiling Point: 3109.00 K (2836°C)

State at Room Temperature: solid

Atomic Radius: 162 pm

Scandium has various important applications in modern technology and industry:

Scandium: The Aerospace Lightener

Scandium transforms aluminum from ordinary metal to aerospace marvel through precise alloying, creating the lightest high-strength materials available. This rare earth element's unique properties make it indispensable for cutting-edge applications despite its extreme cost and scarcity.

Aluminum-Scandium Alloys

Al-Sc alloys achieve unprecedented strength-to-weight ratios through Scandium's grain refinement effects. Adding just 0.1-0.3% Scandium to aluminum creates Al₃Sc precipitates that prevent grain growth during welding and heat treatment, maintaining strength at elevated temperatures. These alloys enable aerospace components weighing 15-20% less than traditional aluminum parts while providing superior fatigue resistance.

Aerospace Applications

Military aircraft like the MiG-29 and Su-57 utilize Scandium-aluminum components in critical structures, fuel tanks, and landing gear where weight reduction directly translates to improved performance and fuel efficiency. The Russian aerospace industry pioneered large-scale Scandium use, maintaining technological advantages in fighter aircraft design.

Sports Equipment Revolution

High-end baseball bats, bicycle frames, and lacrosse sticks incorporate Scandium alloys for professional and Olympic-level competition. A Scandium-aluminum baseball bat costs $400-800 but provides optimal "sweet spot" characteristics and durability that aluminum alone cannot achieve.

Solid Oxide Fuel Cells

Scandium-stabilized zirconia (ScSZ) electrolytes enable fuel cells operating at lower temperatures (650-750°C vs. 800-1000°C) with higher ionic conductivity. This application could revolutionize distributed power generation and electric vehicle range extenders, though Scandium's cost currently limits commercial deployment.

1879

Predicted by Patterns

Scandium's discovery exemplifies the power of Mendeleev's periodic table predictions, joining gallium and germanium as elements predicted before their actual identification. This rare earth element emerged from systematic spectroscopic analysis and theoretical chemistry.

Mendeleev's "Ekaboron" Prediction

In 1869, Dmitri Mendeleev identified a gap in his periodic table between calcium and titanium, predicting an unknown element he called "ekaboron" (meaning "beyond boron"). His predictions included:

  • Atomic weight: ~44 (actual Sc: 44.96)
  • Density: ~3.5 g/cm³ (actual: 2.99 g/cm³)
  • Forms oxide Eb₂O₃ (correct: Sc₂O₃)
  • Higher atomic weight than calcium

Nilson's Spectroscopic Discovery

Lars Fredrik Nilson (1840-1899), a Swedish chemist at Uppsala University, discovered scandium on October 21, 1879, while analyzing rare earth minerals from Scandinavia. Using the newly developed technique of emission spectroscopy, Nilson detected unknown spectral lines in samples of euxenite and gadolinite.

Nilson's meticulous work involved processing 10 kilograms of euxenite through repeated precipitation and crystallization steps, ultimately isolating 2 grams of scandium oxide (Sc₂O₃) as a white powder with unique spectroscopic properties.

Cleve's Confirmation

Per Teodor Cleve (1840-1905), Nilson's colleague at Uppsala, immediately recognized that Nilson's new element perfectly matched Mendeleev's ekaboron predictions. Cleve's systematic analysis confirmed scandium's atomic weight and chemical properties, providing another stunning validation of periodic law.

The Naming

Nilson named his discovery "scandium" after Scandinavia, honoring the region where the defining mineral samples originated. This naming reflected the strong tradition of honoring geographical origins in element nomenclature.

Isolation Challenges

Pure metallic scandium remained elusive until 1937, when Werner Fischer and colleagues at the Kaiser Wilhelm Institute achieved the first preparation through electrolysis of molten potassium, lithium, and scandium chlorides. The extreme difficulty of scandium metal production continues to limit its applications despite remarkable properties.

Discovered by: <div class="discovery-content"> <h3>Predicted by Patterns</h3> <p>Scandium's discovery exemplifies the power of Mendeleev's periodic table predictions, joining gallium and germanium as elements predicted before their actual identification. This rare earth element emerged from systematic spectroscopic analysis and theoretical chemistry.</p> <h4>Mendeleev's "Ekaboron" Prediction</h4> <p>In 1869, <strong>Dmitri Mendeleev</strong> identified a gap in his periodic table between calcium and titanium, predicting an unknown element he called <strong>"ekaboron"</strong> (meaning "beyond boron"). His predictions included:</p> <ul> <li>Atomic weight: ~44 (actual Sc: 44.96)</li> <li>Density: ~3.5 g/cm³ (actual: 2.99 g/cm³)</li> <li>Forms oxide Eb₂O₃ (correct: Sc₂O₃)</li> <li>Higher atomic weight than calcium</li> </ul> <h4>Nilson's Spectroscopic Discovery</h4> <p><strong>Lars Fredrik Nilson</strong> (1840-1899), a Swedish chemist at Uppsala University, discovered scandium on October 21, 1879, while analyzing rare earth minerals from Scandinavia. Using the newly developed technique of <strong>emission spectroscopy</strong>, Nilson detected unknown spectral lines in samples of euxenite and gadolinite.</p> <p>Nilson's meticulous work involved processing 10 kilograms of euxenite through repeated precipitation and crystallization steps, ultimately isolating 2 grams of scandium oxide (Sc₂O₃) as a white powder with unique spectroscopic properties.</p> <h4>Cleve's Confirmation</h4> <p><strong>Per Teodor Cleve</strong> (1840-1905), Nilson's colleague at Uppsala, immediately recognized that Nilson's new element perfectly matched Mendeleev's ekaboron predictions. Cleve's systematic analysis confirmed scandium's atomic weight and chemical properties, providing another stunning validation of periodic law.</p> <h4>The Naming</h4> <p>Nilson named his discovery <strong>"scandium"</strong> after Scandinavia, honoring the region where the defining mineral samples originated. This naming reflected the strong tradition of honoring geographical origins in element nomenclature.</p> <h4>Isolation Challenges</h4> <p>Pure metallic scandium remained elusive until 1937, when <strong>Werner Fischer and colleagues</strong> at the Kaiser Wilhelm Institute achieved the first preparation through electrolysis of molten potassium, lithium, and scandium chlorides. The extreme difficulty of scandium metal production continues to limit its applications despite remarkable properties.</p> </div>

Year of Discovery: 1879

Scandium: Cosmically Rare

Scandium's cosmic journey begins in the nuclear cores of massive stars through silicon burning processes and neutron capture reactions. These stellar nucleosynthesis events occur during the final stages of stellar evolution, creating Scandium isotopes that disperse throughout the galaxy during supernova explosions, though in far smaller quantities than more common elements.

Terrestrial Scarcity

Earth's crust contains approximately 22 parts per million Scandium, making it more abundant than silver or mercury yet paradoxically one of the rarest commercially available elements. This paradox stems from Scandium's geochemical behavior - it rarely concentrates into economically viable ore deposits, instead dispersing widely through rock-forming minerals.

Mineral Occurrences

Thortveitite ((Sc,Y)₂Si₂O₇) represents the only known Scandium-rich mineral, containing up to 40% Scandium oxide. However, thortveitite occurs only in small quantities in Norwegian pegmatites and Madagascar deposits, making it insufficient for global Scandium demand.

Most commercial Scandium comes as a byproduct from uranium and titanium processing. The Bayan Obo rare earth deposit in China and certain Australian laterite deposits contain Scandium concentrations of 100-300 ppm, recovered through complex hydrometallurgical processes.

Global Distribution

Russia dominates global Scandium production from processing uranium mill tailings, producing 60-80% of the world's 15-20 tons annual supply. China produces Scandium from rare earth processing, while Australia develops new extraction methods from nickel and cobalt laterite deposits.

Red Mud Recovery

Aluminum production generates millions of tons of red mud waste containing 100-150 ppm Scandium. Research focuses on economical Scandium extraction from this abundant waste stream, potentially revolutionizing Scandium availability and reducing environmental impacts of aluminum processing.

General Safety: Scandium should be handled with standard laboratory safety precautions including protective equipment and proper ventilation.

Scandium Safety: Generally Low Risk

Scandium and its compounds exhibit relatively low

toxicity compared to other rare earth elements, though proper handling procedures remain essential due to limited toxicological data and potential respiratory irritation from dust exposure.

Biological Effects

Scandium shows low acute

toxicity with animal studies indicating LD₅₀ values exceeding 4 grams per kilogram for most Scandium compounds.
However, like other rare earth elements, Scandium can accumulate in liver and bone tissues with prolonged exposure. Scandium chloride demonstrates moderate
toxicity requiring careful handling protocols.

Occupational Exposure Guidelines

  • No established OSHA PEL for Scandium compounds
  • Recommended exposure limit: <1 mg/m³ for Scandium compounds (dust)
  • Respiratory protection: N95 minimum for dust; higher protection for fine particles
  • Eye protection: Safety glasses with side shields recommended

Handling Procedures

  • Dust Control: Use local exhaust ventilation when grinding or machining Scandium alloys
  • Personal Protection: Nitrile gloves for handling compounds; dust masks for powder operations
  • Storage: Store in cool, dry areas away from acids and strong oxidizers
  • Waste Disposal: Collect Scandium waste for recycling due to extreme value and scarcity

Fire and Reactivity

Scandium metal poses fire hazards when in powder form, potentially igniting in air or reacting violently with water. Scandium alloys generally exhibit excellent fire resistance, contributing to their aerospace applications where fire safety is paramount.

Emergency Procedures

Inhalation: Move to fresh air; seek medical attention for persistent respiratory irritation. Skin contact: Wash with soap and water; remove contaminated clothing. Eye contact: Flush with clean water for 15 minutes; seek medical attention if irritation persists. Ingestion: Rinse mouth with water; seek medical evaluation for significant amounts.

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