27 Co Cobalt 58.933
Transition metal d-block Period 4 Group 9

Cobalt

Co · Element 27 · Cobalt group

The blue in medieval stained glass and Ming porcelain, and half of the magnets that hold hard drives together.

STATE AT 20°C Solid
ATOMIC MASS 58.933 u
ELECTRON CONFIGURATION [Ar] 3d⁷ 4s²

Structure

The cobalt atom

Not a diagram of dots on rings — a Monte-Carlo sample of the actual probability density |ψ|² for each occupied subshell. Drag to rotate. Blue and violet mark opposite signs of the wavefunction, which is what makes bonding possible.

Orbital cloud

Measured values

Property sheet

Every bar shows where cobalt sits among all 118 elements for that property.

Physical

Density 8.9 g/cm³ 56%
Melting point 1768 K 73%
Boiling point 3200 K 66%
Specific heat 0.421 J/g·K
Thermal conductivity 100 W/m·K 83%

Atomic

Atomic radius 125 pm 17%
Covalent radius 126 pm
Van der Waals radius 192 pm

Electronic

Electronegativity 1.88 60%
Ionisation energy 760.3 kJ/mol 63%
Electron affinity 60.8 kJ/mol 64%

Occurrence

Abundance in crust 25 mg/kg 75%

Identity

SymbolCo
Atomic number27
Atomic mass58.9332 u
CategoryTransition metal
Blockd
Crystal structurehexagonal close-packed
Oxidation states-1, 0, +1, +2, +3, +4, +5
Discovered1735
Discovered byGeorg Brandt

Sources: IUPAC 2021 standard atomic weights · CRC Handbook of Chemistry and Physics · NIST. Values marked ~ are predicted rather than measured.

Size, to scale

How big is a cobalt atom?

Radius 125 pm — that is 0.125 nm, so about 4000 million of them side by side would span a millimetre.

Thermal range

Solid, liquid, gas — and when

Cobalt is liquid over a 1432 K window, from 1768 K to 3200 K.

Where it sits

Position in the table

Cobalt sits in period 4, group 9. Everything in group 9 shares the same outer-electron count, which is why they behave so similarly.

OTHER TRANSITION METALS

All transition metals

The story

What cobalt is, and how we found it

Cobalt is the magnetic superhero powering the digital revolution. This lustrous, silver-gray transition metal is absolutely essential for rechargeable batteries, permanent magnets, and jet engines. Named after "kobold," mischievous underground spirits from German folklore, cobalt has gone from being a nuisance for medieval miners to one of the most strategically important elements in the modern world. Discovered in 1735 by Swedish chemist Georg Brandt, cobalt was the first metal discovered since ancient times. For centuries, miners knew about mysterious blue ores that were difficult to smelt and often contained arsenic, making them sick. They blamed these problems on underground spirits called kobolds, never realizing they were dealing with a completely new element that would eventually power smartphones and electric cars. What makes cobalt absolutely extraordinary is its unique combination of magnetic and chemical properties. It's one of only three ferromagnetic elements (along with iron and nickel) that can be permanently magnetized. This makes it essential for creating the world's strongest permanent magnets when alloyed with rare earth elements - magnets so powerful they can lift cars and are used in wind turbines and electric vehicle motors. But cobalt's most important modern role is in rechargeable batteries. Lithium cobalt oxide cathodes in lithium-ion batteries can store enormous amounts of energy while being charged and discharged thousands of times. Your smartphone, laptop, and electric car all depend on cobalt to store and release energy efficiently. As the world transitions to renewable energy and electric vehicles, demand for cobalt has skyrocketed. Here's something concerning: about 70% of the world's cobalt comes from the Democratic Republic of Congo, often from mines with poor working conditions. This has led to intensive research into cobalt-free battery technologies and ethical sourcing initiatives.

The discovery of cobalt

The Swedish Smelter Discovery

Georg Brandt (1694-1768), a Swedish chemist and mineralogist, discovered cobalt around 1735 while investigating blue-colored ores from copper mines near Sala, Sweden. Local miners called these troublesome ores "kobold" (German for goblin) because they contained no copper despite their appearance and produced toxic arsenic fumes when roasted.

Systematic Investigation

Brandt's systematic analysis revealed that the blue color came from a previously unknown metal rather than bismuth or other known elements. His careful chemical procedures isolated cobalt compounds and demonstrated their distinct properties, establishing cobalt as the first metal discovered through scientific investigation rather than ancient metallurgical practices.

Industrial Development

Commercial cobalt production began with cobalt blue pigment manufacturing in the 18th century, prized for its stability and intense color. Modern cobalt metallurgy developed during World War I when Germany's Krupp steelworks discovered cobalt's superalloy properties, leading to strategic military applications.

Applications

What cobalt is used for

Cobalt: The Superalloy Enabler

Cobalt transforms turbine engines from impossible dreams to aerospace reality through its exceptional high-temperature strength and corrosion resistance. This strategic metal enables jet engines, medical implants, and rechargeable batteries that power our modern technological world.

Superalloy Applications

Cobalt-based superalloys maintain strength at temperatures exceeding 1000°C, enabling jet engine turbine blades and combustion chambers to operate under extreme conditions. Stellite alloys containing 50-65% cobalt provide exceptional wear resistance for cutting tools, valve seats, and industrial equipment. Gas turbine engines in commercial aircraft rely on cobalt superalloys for critical rotating components where failure could be catastrophic.

Rechargeable Battery Technology

Lithium cobalt oxide (LiCoO₂) cathodes power most smartphones, laptops, and consumer electronics through cobalt's ability to reversibly intercalate lithium ions. Electric vehicle batteries increasingly use nickel-cobalt-manganese (NCM) and nickel-cobalt-aluminum (NCA) cathodes that balance energy density, safety, and cost while reducing cobalt content due to supply constraints.

Medical Implant Materials

Cobalt-chromium alloys create artificial hip and knee joints with exceptional biocompatibility and wear resistance. These implants last 20-30 years in the human body while maintaining structural integrity under constant mechanical stress. Dental applications utilize cobalt alloys for partial dentures and orthodontic appliances requiring strength and corrosion resistance.

Magnetic Materials

Alnico magnets containing aluminum, nickel, and cobalt provide high-temperature magnetic stability for speakers, sensors, and industrial applications. Samarium-cobalt magnets operate reliably at temperatures up to 350°C, making them essential for aerospace and automotive applications where neodymium magnets would fail.

Cobalt: Critical Technology Material

  • Consumer Electronics
    • Smartphone and laptop batteries (iPhone, Samsung, Dell)
    • Tablet and wearable device batteries
    • Digital camera and portable device batteries
    • Power tool battery packs
  • Electric Vehicles
    • Electric car battery cathodes (Tesla, GM, Ford)
    • Hybrid vehicle battery systems
    • Electric bus and truck batteries
    • Electric scooter and bike batteries
  • Aerospace Industry
    • Jet engine turbine blades and components
    • Rocket engine nozzles and chambers
    • Aircraft structural components
    • Satellite and spacecraft components
  • Medical Applications
    • Artificial hip and knee replacement joints
    • Dental implants and orthodontic devices
    • Surgical instruments and equipment
    • Radiation therapy equipment
  • Industrial Equipment
    • Cutting tools and wear-resistant components
    • High-temperature furnace components
    • Chemical processing equipment
    • Oil refinery catalyst systems

Where it comes from

Natural occurrence

25 mg/kg of Earth's crust · more abundant than 75% of elements

Cobalt: Stellar and Terrestrial Rarity

Cobalt forms through neutron capture processes in massive stars and during supernova nucleosynthesis events. The primary cobalt isotope, cobalt-59, represents the endpoint of iron peak nucleosynthesis, formed when nuclear binding energy reaches its maximum efficiency in stellar cores.

Terrestrial Scarcity

Earth's crust contains only 30 parts per million cobalt, making it relatively rare compared to other transition metals. Most terrestrial cobalt occurs as a byproduct in nickel and copper ores rather than forming independent cobalt minerals, contributing to supply chain concentration and geopolitical concerns.

Primary Cobalt Sources

Democratic Republic of Congo produces 70% of global cobalt from copper-cobalt sedimentary deposits in the Katanga Province. These deposits formed through weathering and oxidation of sulfide ores, creating cobalt-rich laterites and oxidized zones. Carrollite (CuCo₂S₄) and cobaltite (CoAsS) represent primary cobalt minerals, though most production comes from mixed sulfide ores.

Ocean Floor Resources

Manganese nodules on deep ocean floors contain significant cobalt concentrations (0.2-0.3%), representing potential future resources as terrestrial supplies become constrained. These nodules form through extremely slow precipitation processes over millions of years in oxygen-rich deep waters.

Recycling Importance

Cobalt's strategic importance and supply concentration drive extensive recycling efforts. Battery recycling recovers cobalt from spent lithium-ion batteries, while superalloy recycling recycles cobalt from aerospace components, achieving recovery rates exceeding 95% in sophisticated facilities.

Handling

Safety

Cobalt Safety: Respiratory and Skin Concerns

Cobalt compounds can cause serious health effects including hard metal lung disease and allergic contact dermatitis. Occupational exposure requires comprehensive safety measures due to cobalt's potential carcinogenicity and respiratory sensitization.

Health Effects

Cobalt dust inhalation causes pulmonary fibrosis and "hard metal lung disease" in workers exposed to cobalt-tungsten carbide dusts. Skin sensitization leads to cobalt allergies affecting 1-3% of the population, causing dermatitis from jewelry, clothing fasteners, and occupational exposure.

Exposure Limits

  • OSHA PEL: 0.1 mg/m³ (8-hour TWA) for cobalt metal, dust, and fume
  • NIOSH REL: 0.05 mg/m³ (10-hour TWA); potential carcinogen designation
  • ACGIH TLV: 0.02 mg/m³ (8-hour TWA) for cobalt and inorganic compounds

Safety Measures

Respiratory protection, local exhaust ventilation, and skin protection prevent cobalt exposure. Medical surveillance including pulmonary function testing and allergy screening helps detect early health effects in exposed workers.

Quick answers

Cobalt: common questions

What is Cobalt?

Cobalt (symbol Co) is element 27 on the periodic table, a transition metal in period 4, group 9. The blue in medieval stained glass and Ming porcelain, and half of the magnets that hold hard drives together. At room temperature it is a solid.

What is the electron configuration of Cobalt?

Cobalt's ground-state electron configuration is [Ar] 3d⁷ 4s², giving 4 occupied shells holding 2, 8, 15, 2 electrons respectively.

What are the melting and boiling points of Cobalt?

Cobalt melts at 1768 K (1494.9 °C) and boils at 3200 K (2926.9 °C).

What is the atomic mass of Cobalt?

The standard atomic weight of Cobalt is 58.933 u. That is a weighted average across its naturally occurring isotopes, which is why it is rarely a whole number.

How dense is Cobalt?

Cobalt has a density of 8.9 g/cm³. Water is 1.0 g/cm³, so a block of cobalt is about 8.9× heavier.

What is the electronegativity of Cobalt?

Cobalt has a Pauling electronegativity of 1.88. The scale runs from 0.70 (francium, the least greedy for electrons) to 3.98 (fluorine, the most). Values in this middle band tend to form covalent rather than strongly ionic bonds.

Who discovered Cobalt, and when?

Cobalt was discovered in 1735 by Georg Brandt. It is named after german kobold, "goblin" — miners blamed it for bad ore.

How common is Cobalt on Earth?

Cobalt makes up about 25 mg/kg of the Earth's crust — uncommon, but not rare.