The story
What tungsten is, and how we found it
Tungsten (W) is element 74, a hard, dense, gray-white transition metal in group 6 of the periodic table. It has the highest melting point of any metal, 3,422 °C (3,695 K), and boils at 5,555 °C (5,828 K). Its density, 19.25 g/cm³, is close to that of gold. The symbol W comes from wolfram, the element's name in German and several other languages.
Atomic structure and isotopes
A tungsten atom has 74 electrons in six shells, arranged 2, 8, 18, 32, 12, 2, with the configuration [Xe] 4f¹⁴ 5d⁴ 6s². Its most common oxidation state is +6, as in tungsten trioxide (WO₃) and the tungstate ion.
Natural tungsten is a mix of five isotopes: tungsten-180, 182, 183, 184 and 186. Tungsten-184 is the most common, at about 31%. Tungsten-180 is weakly radioactive: its alpha decay has been observed, with a half-life of about 1.8 × 10¹⁸ years, so natural tungsten is effectively stable.
The discovery of tungsten
Scheele and tungstic acid (1781)
In 1781 the Swedish chemist Carl Wilhelm Scheele showed that the mineral then called tungsten (Swedish for "heavy stone", now named scheelite) contained a new acid, which he named tungstic acid. Torbern Bergman suggested that a new metal could be obtained from it, but neither man isolated it.
The Elhuyar brothers isolate the metal (1783)
In 1783 the Spanish brothers Juan José and Fausto Elhuyar, working at the Royal Seminary of Bergara in the Basque Country, found the same acid in the mineral wolframite and reduced it with charcoal, obtaining the metal for the first time. This is the discovery year shown on this page.
Two names
The Elhuyar brothers called the metal wolfram, after wolframite, and that name is still used in German and several other languages. English and French adopted tungsten. IUPAC uses the name tungsten with the symbol W, from wolfram.
Ductile tungsten (1906 to 1910)
Tungsten is brittle at room temperature, so the first tungsten lamp filaments were pressed from powder and fragile. Between 1906 and 1910 William Coolidge at General Electric developed a powder metallurgy process to make ductile tungsten wire, which became the standard filament of incandescent lamps.