88 Ra Radium 226*
Alkaline earth metal s-block Period 7 Group 2 Radioactive

Radium

Ra · Element 88 · Alkaline earth metals

The element that glowed in the dark on watch dials, and killed the women who painted them.

STATE AT 20°C Solid
ATOMIC MASS 226 u
ELECTRON CONFIGURATION [Rn] 7s²

Structure

The radium atom

Not a diagram of dots on rings — a Monte-Carlo sample of the actual probability density |ψ|² for each occupied subshell. Drag to rotate. Blue and violet mark opposite signs of the wavefunction, which is what makes bonding possible.

Orbital cloud

Measured values

Property sheet

Every bar shows where radium sits among all 118 elements for that property.

Physical

Density 5.5 g/cm³ 32%
Melting point 1233 K 55%
Boiling point 2010 K 43%
Specific heat 0.094 J/g·K
Thermal conductivity 15 W/m·K 44%

Atomic

Atomic radius 221 pm 77%
Covalent radius 221 pm
Van der Waals radius 283 pm

Electronic

Electronegativity 0.9 5%
Ionisation energy 509.4 kJ/mol 6%
Electron affinity 9.6 kJ/mol 15%

Occurrence

Abundance in crust 9.00e-7 mg/kg 28%

Identity

SymbolRa
Atomic number88
Atomic mass226 u
CategoryAlkaline earth metal
Blocks
Crystal structurebody-centered cubic
Oxidation states+2
Discovered1898
Discovered byMarie & Pierre Curie

Sources: IUPAC 2021 standard atomic weights · CRC Handbook of Chemistry and Physics · NIST. Values marked ~ are predicted rather than measured.

Size, to scale

How big is a radium atom?

Radius 221 pm — that is 0.221 nm, so about 2262 million of them side by side would span a millimetre.

Thermal range

Solid, liquid, gas — and when

Radium is liquid over a 777 K window, from 1233 K to 2010 K.

Where it sits

Position in the table

Radium sits in period 7, group 2. Everything in group 2 shares the same outer-electron count, which is why they behave so similarly.

OTHER ALKALINE EARTH METALS

All alkaline earth metals

The story

What radium is, and how we found it

The element that glowed in the dark on watch dials, and killed the women who painted them.

The discovery of radium

Marie and Pierre Curie (1898)

Radium was discovered in 1898 by Marie and Pierre Curie in Paris, along with polonium, while investigating the mysterious radioactivity of pitchblende ore. Marie Curie noticed that pitchblende was more radioactive than pure uranium, suggesting the presence of unknown elements. Through painstaking chemical separation processes, the Curies isolated fractions containing intense radioactivity, eventually identifying two new elements they named polonium and radium.

Heroic Isolation Efforts

The Curies processed literally tons of pitchblende residue in a converted shed, using primitive equipment and no safety protection. Marie Curie spent four years refining radium, finally isolating one-tenth of a gram of pure radium chloride in 1902. The work required processing over 8 tons of pitchblende to obtain this tiny sample, demonstrating radiums extreme rarity and the incredible dedication required for its discovery.

significant Properties

The Curies discovered that radium glowed in the dark, emitted heat continuously, and caused surrounding materials to become radioactive. These unprecedented properties revolutionized understanding of atomic structure and energy. Pierre Curie famously carried a vial of radium in his pocket, noting the burns it caused on his skin, unwittingly demonstrating both its power and danger.

Nobel Prize Recognition

The discovery of radium earned Marie and Pierre Curie the 1903 Nobel Prize in Physics (shared with Henri Becquerel for radioactivity research) and Marie Curie a second Nobel Prize in Chemistry in 1911 for isolating pure radium and determining its atomic weight. Marie Curie became the first person to win Nobel Prizes in two different scientific fields, largely based on her radium research.

Applications

What radium is used for

Medical Radiotherapy

Radium-226 historically played a crucial role in cancer treatment through brachytherapy (internal radiation therapy). From the 1900s through the 1970s, radium needles and applicators were inserted directly into tumors or body cavities to deliver high-dose radiation to cancer cells. While largely replaced by safer isotopes like cesium-137 and iridium-192, radium established the foundations of modern radiation oncology and saved countless lives when few other cancer treatments existed.

Scientific Research and Calibration

Radium serves as a primary standard for radioactivity measurements and instrument calibration. The original definition of the curie (unit of radioactivity) was based on the decay rate of one gram of radium-226. Today, precisely measured radium sources help calibrate radiation detection equipment, validate measurement techniques, and provide reference standards for national laboratories worldwide. Radium also contributes to nuclear physics research studying alpha decay processes.

Industrial Applications (Historical)

Before its health risks were fully understood, radium had numerous industrial applications. Self-luminous paint containing radium was used on watch dials, instrument panels, and aircraft gauges from 1917 to the 1960s. These applications provided reliable illumination without external power sources, crucial for military and aviation applications during both World Wars. Radium was also used in lightning rods and as an additive in certain specialty steels.

Educational and Training

Sealed radium sources continue to serve important educational roles in training radiation safety professionals, health physicists, and nuclear engineers. These controlled sources help students understand radiation detection principles, shielding calculations, and contamination control procedures. Modern educational applications use minimal amounts in secure devices designed to prevent exposure while providing valuable learning experiences.

Largely Discontinued Due to Health Risks

Most historical uses of radium have been discontinued due to severe health and environmental risks. Consumer products containing radium, including luminous paints, health tonics, and cosmetics, were banned in most countries by the 1970s. The tragic stories of radium dial painters who developed "radium jaw" and other fatal illnesses led to strict regulations and the development of modern radiation protection standards.

Limited Specialized Applications

Today, radium use is restricted to highly controlled applications including certain medical research, instrument calibration, and nuclear physics experiments. Ra-223 (Xofigo) represents a modern medical application - an FDA-approved radiopharmaceutical for treating bone metastases in prostate cancer patients. This alpha-emitting isotope targets bone tissue specifically, delivering radiation directly to cancer sites while minimizing whole-body exposure.

Research and Standards

National laboratories and research institutions maintain radium sources for calibrating radiation measurement equipment and studying nuclear decay processes. These applications require strict licensing, specialized facilities, and comprehensive safety protocols. Such uses are essential for maintaining the accuracy of radiation measurements used in medicine, nuclear power, and environmental monitoring.

Environmental Monitoring

Radium isotopes serve as natural tracers for studying groundwater movement, ocean circulation, and sediment transport. Scientists measure radium concentrations to track water masses, estimate groundwater discharge rates, and understand biogeochemical processes in aquatic systems. These applications help manage water resources and monitor environmental changes without requiring artificial radium addition.

Where it comes from

Natural occurrence

9.00e-7 mg/kg of Earth's crust · more abundant than 28% of elements

Uranium Decay Product

Radium occurs naturally as an intermediate product in the uranium-238 decay chain, forming when radon-222 decays. With a half-life of 1,600 years, radium-226 accumulates in uranium-bearing ores and rocks, reaching equilibrium concentrations determined by the balance between formation and decay. Significant radium deposits occur in uranium-rich areas including the Colorado Plateau, Athabasca Basin in Canada, and various locations in Australia, Kazakhstan, and Africa.

Groundwater Contamination

Radium dissolves readily in groundwater, particularly in areas with uranium-bearing bedrock or sediments. High radium concentrations in drinking water supplies affect thousands of communities worldwide, especially those using deep wells in glacial aquifers or areas with phosphate deposits. The EPA sets maximum contaminant levels for combined radium-226 and radium-228 at 5 pCi/L in public water supplies.

NORM and Industrial Sources

Naturally Occurring Radioactive Materials (NORM) containing radium accumulate in oil and gas production equipment, phosphate mining operations, and coal ash. Radium concentrates in brine and scale deposits in oil field pipes and tanks, creating significant disposal challenges for the petroleum industry. Phosphate fertilizers often contain elevated radium levels, contributing to agricultural radiation exposure.

Building Materials and Indoor Air

Certain building materials, including concrete made with phosphate slag or fly ash, can contain elevated radium levels. Radium in building materials contributes to indoor radon concentrations as Ra-226 decays to produce radon gas. Some natural stones used in construction, particularly granite varieties, may contain significant radium concentrations that require monitoring and potential mitigation.

Handling

Safety

Radium is radioactive. It has no stable isotope — every nucleus decays. Handling requires appropriate shielding and licensing.

Severe Health Hazards

Radium is extremely dangerous due to its intense radioactivity and biological behavior. When ingested or inhaled, radium accumulates in bones, where it continues emitting alpha radiation for decades. This internal exposure causes bone cancer, leukemia, and severe anemia. The tragic deaths of radium dial painters in the early 1900s, who developed "radium jaw" and bone cancers from licking radium-painted brushes, led to modern radiation protection standards.

Strict Handling Protocols

All radium work requires specialized facilities with appropriate containment, ventilation, and monitoring systems. Personnel must wear full protective equipment including respirators to prevent inhalation of radium dust or radon gas produced by decay. Radium sources must be stored in secure, shielded containers and handled only with remote tools. Regular bioassay monitoring is required for anyone potentially exposed to radium.

Environmental and Public Health

Radium contamination of drinking water supplies poses ongoing public health challenges. Communities with elevated radium levels require water treatment systems or alternative supplies. Former radium processing sites, including watch dial painting facilities and medical supply manufacturers, remain contaminated decades after closure, requiring expensive cleanup efforts and long-term monitoring.

Emergency Response

Radium spills or accidents require immediate evacuation and specialized cleanup procedures. Contaminated areas may remain hazardous for thousands of years due to radiums 1,600-year half-life. Emergency responders must be trained in radiation detection and have appropriate equipment to assess contamination levels. Medical treatment for radium exposure focuses on preventing absorption and accelerating elimination from the body using chelation therapy.

Quick answers

Radium: common questions

What is Radium?

Radium (symbol Ra) is element 88 on the periodic table, a alkaline earth metal in period 7, group 2. The element that glowed in the dark on watch dials, and killed the women who painted them. At room temperature it is a solid, and it is radioactive.

What is the electron configuration of Radium?

Radium's ground-state electron configuration is [Rn] 7s², giving 7 occupied shells holding 2, 8, 18, 32, 18, 8, 2 electrons respectively.

What are the melting and boiling points of Radium?

Radium melts at 1233 K (959.9 °C) and boils at 2010 K (1736.9 °C).

What is the atomic mass of Radium?

Radium has no stable isotope, so it has no standard atomic weight. The figure quoted, 226, is the mass number of its longest-lived known isotope.

How dense is Radium?

Radium has a density of 5.5 g/cm³. Water is 1.0 g/cm³, so a block of radium is about 5.5× heavier.

What is the electronegativity of Radium?

Radium has a Pauling electronegativity of 0.9. The scale runs from 0.70 (francium, the least greedy for electrons) to 3.98 (fluorine, the most). A value this low means it readily gives its outer electrons away, forming positive ions.

Who discovered Radium, and when?

Radium was discovered in 1898 by Marie & Pierre Curie. It is named after latin radius, "ray".

How common is Radium on Earth?

Radium makes up about 9.00e-7 mg/kg of the Earth's crust — genuinely rare, which is why it is expensive.

Is Radium radioactive?

Yes. Radium has no stable isotope — every one of its nuclei decays. Trace amounts occur naturally as decay products of heavier elements.