30 Zn Zinc 65.38
Transition metal d-block Period 4 Group 12

Zinc

Zn · Element 30 · Zinc group

The sacrificial metal: zinc corrodes so that the steel it coats does not.

STATE AT 20°C Solid
ATOMIC MASS 65.38 u
ELECTRON CONFIGURATION [Ar] 3d¹⁰ 4s²

Structure

The zinc atom

Not a diagram of dots on rings — a Monte-Carlo sample of the actual probability density |ψ|² for each occupied subshell. Drag to rotate. Blue and violet mark opposite signs of the wavefunction, which is what makes bonding possible.

Orbital cloud

Measured values

Property sheet

Every bar shows where zinc sits among all 118 elements for that property.

Physical

Density 7.134 g/cm³ 43%
Melting point 692.9 K 35%
Boiling point 1180 K 29%
Specific heat 0.388 J/g·K
Thermal conductivity 116 W/m·K 86%

Atomic

Atomic radius 134 pm 21%
Covalent radius 122 pm
Van der Waals radius 139 pm

Electronic

Electronegativity 1.65 54%
Ionisation energy 906 kJ/mol 82%
Electron affinity 0 kJ/mol 0%

Occurrence

Abundance in crust 70 mg/kg 80%

Identity

SymbolZn
Atomic number30
Atomic mass65.38 u
CategoryTransition metal
Blockd
Crystal structurehexagonal close-packed
Oxidation states-2, +1, +2
Discovered1746
Discovered byAndreas Marggraf

Sources: IUPAC 2021 standard atomic weights · CRC Handbook of Chemistry and Physics · NIST. Values marked ~ are predicted rather than measured.

Size, to scale

How big is a zinc atom?

Radius 134 pm — that is 0.134 nm, so about 3731 million of them side by side would span a millimetre.

Thermal range

Solid, liquid, gas — and when

Zinc is liquid over a 487 K window, from 693 K to 1180 K.

Where it sits

Position in the table

Zinc sits in period 4, group 12. Everything in group 12 shares the same outer-electron count, which is why they behave so similarly.

OTHER TRANSITION METALS

All transition metals

The story

What zinc is, and how we found it

Bluish-white metal. Essential nutrient and protects steel from rust.

The discovery of zinc

The Ancient Metal with a Modern Name

Zinc's discovery story spans millennia, bridging ancient metallurgy and modern chemistry. Unlike elements discovered in laboratory flasks, zinc emerged from the practical needs of craftsmen and the curiosity of alchemists.

Ancient Beginnings

Archaeological evidence from the Indus Valley civilization (2500 BCE) reveals zinc-containing brass artifacts, suggesting early knowledge of zinc-bearing ores. However, these ancient metallurgists unknowingly produced zinc through cementation processes - heating copper with zinc-rich calamine (zinc carbonate) in crucibles, creating brass without ever isolating pure zinc.

Roman brass production flourished around 20 BCE, with workshops in modern-day Belgium and Germany perfecting techniques that would influence European metallurgy for centuries. The Romans called their zinc-bearing ore "cadmia," recognizing its value but never understanding its true nature.

Asian Mastery

While Europeans struggled with zinc's volatility, Indian metallurgists achieved pure zinc production by the 12th century. In Rajasthan's Zawar mines, they developed significant retort distillation techniques, heating zinc ores in sealed clay vessels and condensing the vapor in bamboo pipes cooled with water - a process 500 years ahead of European methods.

European Recognition

The German physician and alchemist Andreas Libavius first described metallic zinc in European literature in 1597, calling it "Indian tin." However, systematic study awaited Andreas Sigismund Marggraf (1709-1782), a Berlin apothecary's son who became one of chemistry's pioneers.

In 1746, Marggraf conducted the definitive experiments that established zinc as a distinct element. Working in his private laboratory, he carefully heated calamine with charcoal in sealed retorts, collecting the silvery condensate that formed. His meticulous documentation proved zinc was not merely an impure form of tin or lead, as previously believed.

Industrial Revolution

The real breakthrough came with William Champion's 1738 patent for large-scale zinc smelting in Bristol, England. Champion's process used massive retorts capable of producing 200 pounds of zinc daily, launching the industrial zinc age and enabling the galvanization revolution that would transform 19th-century construction.

Applications

What zinc is used for

Industrial Applications: The Corrosion Fighter

Zinc stands as one of industry's most versatile defenders, with its primary superpower being galvanization - the process that saves billions of dollars in infrastructure damage annually. When steel is hot-dip galvanized, it's immersed in molten zinc at 450°C, creating a metallurgical bond that forms multiple zinc-iron alloy layers. This process protects everything from highway guardrails to the Eiffel Tower's recent renovation.

Galvanization Technologies

Modern galvanization employs several cutting-edge techniques. Continuous galvanizing lines can process steel coils at speeds up to 600 meters per minute, applying zinc coatings as thin as 7 microns yet providing decades of protection. Electrogalvanizing uses zinc sulfate solutions and precise current control to deposit ultra-smooth coatings for automotive body panels, ensuring your car's pristine finish.

Die-Casting Revolution

Zinc die-casting creates the intricate components hiding in plain sight around you. The process injects molten zinc alloys (typically Zamak 3, 5, or 7) into precision steel molds under pressures exceeding 1,000 psi. This produces everything from your laptop's hinges and smartphone frames to automotive transmission cases and decorative hardware with tolerances measured in thousandths of an inch.

Battery Technology

In alkaline batteries, zinc powder serves as the anode in a potassium hydroxide electrolyte, delivering the reliable 1.5V that powers countless devices. Advanced zinc-air batteries for hearing aids achieve energy densities rivaling lithium systems by using atmospheric oxygen as the cathode, making them incredibly lightweight and long-lasting.

Chemical Manufacturing

Zinc oxide production involves either the French process (vaporizing metallic zinc at 950°C) or the American process (burning zinc vapor in controlled atmospheres). The resulting zinc oxide serves as a crucial catalyst in methanol synthesis and as a key ingredient in rubber vulcanization, where it acts as an activator for sulfur cross-linking that gives tires their durability.

Everyday Zinc: Hidden in Plain Sight

  • Personal Care Products
    • Sunscreen (zinc oxide provides broad-spectrum UV protection)
    • Diaper rash cream (Desitin, A+D, Boudreaux's Butt Paste)
    • Anti-dandruff shampoo (Head & Shoulders, Selsun Blue)
    • Deodorants and antiperspirants (antimicrobial properties)
  • Construction Materials
    • Galvanized roofing and siding (lasts 50+ years)
    • Chain-link fencing and guardrails
    • HVAC ductwork and gutters
    • Nails, screws, and fasteners
  • Automotive Industry
    • Body panels and frames (corrosion resistance)
    • Die-cast engine components and transmission parts
    • Brake lines and fuel systems
    • Decorative trim and emblems
  • Electronics & Technology
    • Battery casings and electrodes (Duracell, Energizer)
    • Smartphone and laptop frames
    • TV and monitor bezels
    • Gaming console housings
  • Health & Nutrition
    • Dietary supplements (immune system support)
    • Zinc lozenges for cold treatment (Cold-Eeze, Zicam)
    • Wound healing ointments
    • Zinc-fortified cereals and foods

Where it comes from

Natural occurrence

70 mg/kg of Earth's crust · more abundant than 80% of elements

Zinc's Cosmic Journey

Zinc's story begins in the nuclear furnaces of massive stars, where silicon burning and neutron capture processes forge this essential element during the final moments before stellar collapse. When these stars explode as supernovae, they scatter zinc across the cosmos, eventually incorporating it into new planetary systems like our own.

Terrestrial Abundance

Earth's crust contains approximately 70 parts per million zinc, making it the 24th most abundant element. This concentration resulted from early planetary differentiation processes, where zinc's moderate atomic weight allowed it to remain in the silicate mantle rather than sink into the iron-nickel core.

Primary Zinc Minerals

Sphalerite (ZnS) dominates global zinc production, accounting for 95% of all zinc ore. This cubic crystal system mineral often displays brilliant colors - from honey yellow to deep red - due to iron and cadmium substitutions. Major deposits formed through hydrothermal processes where zinc-rich fluids precipitated in limestone environments.

Smithsonite (ZnCO₃) and hemimorphite (Zn₄Si₂O₇(OH)₂·H₂O) represent important secondary minerals formed through weathering of primary sulfide deposits. These oxidized zones often create spectacular crystal formations prized by mineral collectors.

Global Distribution

The world's largest zinc deposits cluster around ancient tectonic boundaries. Australia's Broken Hill region contains some of Earth's richest zinc-lead-silver ores, formed 1.7 billion years ago. Peru's Antamina mine exploits a massive skarn deposit where limestone met intrusive magma, creating ideal conditions for zinc concentration.

Biological Cycling

Zinc participates in Earth's biogeochemical cycles through weathering, plant uptake, and marine precipitation. Ocean water contains about 0.5 parts per billion zinc, while marine organisms concentrate it in their tissues, eventually returning it to sediments upon death.

Handling

Safety

Zinc Safety: Essential but Balanced

Zinc presents a fascinating paradox - it's simultaneously essential for life and potentially toxic in excess. Understanding this delicate balance is crucial for safe handling and biological health.

Biological Importance vs. Toxicity

The human body requires 8-11 mg of zinc daily for over 300 enzyme functions, immune system operation, and wound healing. However, acute toxicity begins around 225-450 mg, causing nausea, vomiting, and diarrhea. Chronic exposure above 40 mg daily can interfere with copper absorption, leading to anemia and immune dysfunction.

Occupational Exposure Limits

  • OSHA PEL: 5 mg/m³ (8-hour TWA) for zinc oxide fume
  • NIOSH REL: 5 mg/m³ (10-hour TWA) with 10 mg/m³ ceiling
  • ACGIH TLV: 2 mg/m³ respirable fraction, 10 mg/m³ inhalable

Metal Fume Fever

Metal fume fever represents zinc's most significant occupational hazard. Inhaling zinc oxide fumes during welding or smelting causes flu-like symptoms appearing 4-12 hours post-exposure: fever, chills, nausea, and fatigue. While rarely serious, it's completely preventable with proper ventilation and respiratory protection.

Personal Protective Equipment

  • Respiratory: N95 minimum for zinc dust; supplied-air for hot operations
  • Eye Protection: Safety glasses with side shields; goggles for grinding
  • Skin Protection: Nitrile gloves; long sleeves for handling zinc compounds
  • Ventilation: Local exhaust for welding; general ventilation for storage

Emergency Procedures

Inhalation: Remove from exposure immediately; provide fresh air and oxygen if needed. Skin Contact: Flush with water for 15 minutes; remove contaminated clothing. Eye Contact: Irrigate with clean water for 15 minutes; seek medical attention. Ingestion: Do not induce vomiting; provide water and seek immediate medical care for amounts exceeding nutritional doses.

Quick answers

Zinc: common questions

What is Zinc?

Zinc (symbol Zn) is element 30 on the periodic table, a transition metal in period 4, group 12. The sacrificial metal: zinc corrodes so that the steel it coats does not. At room temperature it is a solid.

What is the electron configuration of Zinc?

Zinc's ground-state electron configuration is [Ar] 3d¹⁰ 4s², giving 4 occupied shells holding 2, 8, 18, 2 electrons respectively.

What are the melting and boiling points of Zinc?

Zinc melts at 692.9 K (419.7 °C) and boils at 1180 K (906.9 °C).

What is the atomic mass of Zinc?

The standard atomic weight of Zinc is 65.38 u. That is a weighted average across its naturally occurring isotopes, which is why it is rarely a whole number.

How dense is Zinc?

Zinc has a density of 7.134 g/cm³. Water is 1.0 g/cm³, so a block of zinc is about 7.1× heavier.

What is the electronegativity of Zinc?

Zinc has a Pauling electronegativity of 1.65. The scale runs from 0.70 (francium, the least greedy for electrons) to 3.98 (fluorine, the most). Values in this middle band tend to form covalent rather than strongly ionic bonds.

Who discovered Zinc, and when?

Zinc was discovered in 1746 by Andreas Marggraf. It is named after german Zinke, "prong".

How common is Zinc on Earth?

Zinc makes up about 70 mg/kg of the Earth's crust — uncommon, but not rare.