25
Mn
Manganese

Manganese

Element 25 • Transition Metal
Atomic Mass 54.938045
Electron Config Unknown
Group/Period 7/4

Overview

ANALYZED
Manganese is the unsung hero of steelmaking and the secret ingredient that makes your smartphone battery work! This hard, brittle, silvery-gray metal is absolutely essential for modern civilization - virtually all steel contains Manganese, and without it, our infrastructure would literally crumble. Despite being the 12th most abundant element on Earth, Manganese often goes unnoticed even though it's in everything from the steel beams in skyscrapers to the batteries in electric cars. Discovered in 1774 by Swedish chemist Johan Gottlieb Gahn, Manganese was initially confused with magnesium and iron due to their similar properties. The name comes from the Latin "magnes" meaning magnet, though pure Manganese is actually only weakly magnetic. What makes this element absolutely crucial is its ability to remove sulfur and oxygen impurities from steel, acting like a molecular cleanup crew during the steelmaking process. Here's something mind-blowing: Manganese exists in more oxidation states than almost any other element, ranging from -3 to +7! This incredible versatility makes it useful in everything from purple glass (Mn³⁺) to powerful oxidizing agents like potassium permanganate (Mn⁷⁺) that can disinfect water and treat wounds. Manganese plays a vital role in biology too. It's an essential trace element for all living things, helping plants perform photosynthesis and enabling humans to process carbohydrates and fats. Manganese-containing enzymes are crucial for bone formation, wound healing, and antioxidant protection. Deficiency can cause skeletal abnormalities and reproductive problems. The ocean floor is literally covered with trillions of tons of Manganese nodules - potato-sized rocks containing Manganese, iron, nickel, and copper that grew over millions of years. These nodules could be the future of deep-sea mining, though the environmental implications are still being studied.

Physical Properties

MEASURED
Atomic Mass
54.938045 u
Melting Point
1519.00 °C
Boiling Point
2334.00 °C
Ionization Energy
7.43 kJ/mol

Special Properties

CLASSIFIED
STABLE Generally safe to handle with standard precautions

Applications

CATALOGUED

Manganese: The Steel Purifier

Manganese serves as steel's essential partner, removing harmful sulfur and oxygen while strengthening iron alloys that build our modern world. This versatile element enables everything from railroad tracks to aluminum beverage cans through its unique metallurgical and chemical properties.

Steel Production Essential

Ferromanganese containing 75-80% Manganese serves as steel's primary deoxidizer and desulfurizer, removing impurities that would otherwise cause brittleness and hot cracking. Every ton of steel requires 6-9 kg of Manganese, making steel production the largest consumer of Manganese globally. Manganese steel containing 11-14% Manganese exhibits extraordinary work-hardening properties, ideal for mining equipment, railroad crossings, and military armor where impact resistance is critical.

Aluminum Alloy Applications

3000-series aluminum alloys containing 0.8-1.5% Manganese provide excellent corrosion resistance and formability for beverage cans, automotive body panels, and architectural applications. Manganese prevents grain growth during aluminum processing, maintaining strength and preventing orange-peel surface defects during forming operations.

Battery Technology

Alkaline batteries utilize Manganese dioxide (MnO₂) cathodes that provide reliable 1.5V output through Manganese's ability to accept electrons during discharge. Lithium-ion batteries increasingly use Manganese-based cathodes (LiMn₂O₄) for improved safety and thermal stability in electric vehicle applications, with Manganese helping prevent thermal runaway conditions.

Chemical Catalysis

Potassium permanganate (KMnO₄) serves as a powerful oxidizing agent for water treatment, removing iron, Manganese, and organic contaminants from municipal water supplies. Manganese dioxide catalyzes hydrogen peroxide decomposition in industrial processes and serves as an oxidation catalyst in organic chemical synthesis.

Common Uses

INDEXED

Manganese: Building Modern Life

  • Steel & Construction
    • All steel production (deoxidizer and strengthener)
    • Railroad tracks and heavy construction equipment
    • Mining equipment and crushing machinery
    • Military armor and ballistic protection
  • Aluminum Products
    • Beverage cans (Coca-Cola, Pepsi, beer cans)
    • Automotive body panels and trim
    • Building facades and roofing systems
    • Marine applications and boat hulls
  • Batteries & Electronics
    • Alkaline batteries (AA, AAA, D-cell)
    • Electric vehicle battery cathodes
    • Rechargeable battery systems
    • Electronic device power sources
  • Chemical Industry
    • Water treatment and purification systems
    • Industrial oxidation processes
    • Laboratory analytical reagents
    • Specialty chemical manufacturing
  • Agriculture & Health
    • Animal feed supplements (essential nutrient)
    • Fertilizers and soil conditioners
    • Nutritional supplements
    • Medical imaging contrast agents

Natural Occurrence

SURVEYED

Manganese: Abundant and Essential

Manganese forms through oxygen burning processes in massive stars and neutron capture reactions during stellar evolution. Its cosmic abundance reflects Manganese's nuclear stability and formation through multiple nucleosynthesis pathways in both regular stellar fusion and

explosive supernova events.

Terrestrial Abundance

Earth's crust contains approximately 1,050 parts per million Manganese, making it the 12th most abundant element. This high concentration enables widespread Manganese occurrence in rocks, soils, and water systems, supporting both geological processes and biological functions.

Major Manganese Deposits

Sedimentary Manganese deposits formed through chemical precipitation in ancient oceans account for 80% of global reserves. The Kalahari Manganese field in South Africa contains the world's largest high-grade deposits, formed through hydrothermal and sedimentary processes. Australia's Pilbara region hosts significant Manganese resources in banded iron formations.

Ocean Floor Resources

Manganese nodules covering vast areas of deep ocean floors represent enormous potential resources, containing 24-30% Manganese along with nickel, copper, and cobalt. These potato-sized concretions form through extremely slow precipitation processes over millions of years, though deep-sea mining remains technologically and environmentally challenging.

Biological Cycling

Manganese participates actively in Earth's biogeochemical cycles as an essential element for photosynthesis and enzyme function in all living organisms. Soil Manganese availability affects plant growth and agricultural productivity, while marine Manganese cycling influences ocean chemistry and productivity.

Discovery

ARCHIVED
1774

Swedish Discovery

Johan Gottlieb Gahn isolated metallic manganese in 1774 through carbon reduction of manganese dioxide, though the element was recognized earlier by Carl Wilhelm Scheele and others. Gahn's systematic approach established manganese as a distinct element rather than a form of iron or other known metals.

Industrial Development

Commercial manganese production began with ferromanganese smelting in the 1840s, revolutionizing steel production. The development of electric arc furnaces in the early 1900s enabled efficient manganese alloy production, supporting the steel industry's rapid expansion during industrialization.

Safety Information

CRITICAL

Manganese Safety: Neurological Concerns

Manganese

toxicity primarily affects the central nervous system, causing manganism - a Parkinson's-like condition from chronic inhalation exposure.
While Manganese is essential for health, occupational exposure requires careful monitoring and control.

Health Effects

Chronic Manganese exposure causes irreversible neurological damage including tremors, muscle rigidity, and psychiatric symptoms. Ferromanganese production and welding operations present the highest exposure risks through inhalation of Manganese-containing dusts and fumes.

Exposure Limits

  • OSHA PEL: 5 mg/m³ ceiling for Manganese compounds
  • NIOSH REL: 1 mg/m³ (10-hour TWA) for Manganese dust and compounds
  • ACGIH TLV: 0.02 mg/m³ (respirable fraction) for Manganese and inorganic compounds

Safety Measures

Respiratory protection, local exhaust ventilation, and biological monitoring through blood and urine Manganese levels help prevent neurological damage. Early detection and exposure reduction can prevent progression of manganism symptoms.

Knowledge Database

Essential information about Manganese (Mn)

Manganese is unique due to its atomic number of 25 and belongs to the Transition Metal category. With an atomic mass of 54.938045, it exhibits distinctive properties that make it valuable for various applications.

Manganese has several important physical properties:

Melting Point: 1519.00 K (1246°C)

Boiling Point: 2334.00 K (2061°C)

State at Room Temperature: solid

Atomic Radius: 127 pm

Manganese has various important applications in modern technology and industry:

Manganese: The Steel Purifier

Manganese serves as steel's essential partner, removing harmful sulfur and oxygen while strengthening iron alloys that build our modern world. This versatile element enables everything from railroad tracks to aluminum beverage cans through its unique metallurgical and chemical properties.

Steel Production Essential

Ferromanganese containing 75-80% Manganese serves as steel's primary deoxidizer and desulfurizer, removing impurities that would otherwise cause brittleness and hot cracking. Every ton of steel requires 6-9 kg of Manganese, making steel production the largest consumer of Manganese globally. Manganese steel containing 11-14% Manganese exhibits extraordinary work-hardening properties, ideal for mining equipment, railroad crossings, and military armor where impact resistance is critical.

Aluminum Alloy Applications

3000-series aluminum alloys containing 0.8-1.5% Manganese provide excellent corrosion resistance and formability for beverage cans, automotive body panels, and architectural applications. Manganese prevents grain growth during aluminum processing, maintaining strength and preventing orange-peel surface defects during forming operations.

Battery Technology

Alkaline batteries utilize Manganese dioxide (MnO₂) cathodes that provide reliable 1.5V output through Manganese's ability to accept electrons during discharge. Lithium-ion batteries increasingly use Manganese-based cathodes (LiMn₂O₄) for improved safety and thermal stability in electric vehicle applications, with Manganese helping prevent thermal runaway conditions.

Chemical Catalysis

Potassium permanganate (KMnO₄) serves as a powerful oxidizing agent for water treatment, removing iron, Manganese, and organic contaminants from municipal water supplies. Manganese dioxide catalyzes hydrogen peroxide decomposition in industrial processes and serves as an oxidation catalyst in organic chemical synthesis.

1774

Swedish Discovery

Johan Gottlieb Gahn isolated metallic manganese in 1774 through carbon reduction of manganese dioxide, though the element was recognized earlier by Carl Wilhelm Scheele and others. Gahn's systematic approach established manganese as a distinct element rather than a form of iron or other known metals.

Industrial Development

Commercial manganese production began with ferromanganese smelting in the 1840s, revolutionizing steel production. The development of electric arc furnaces in the early 1900s enabled efficient manganese alloy production, supporting the steel industry's rapid expansion during industrialization.

Discovered by: <div class="discovery-content"> <h3>Swedish Discovery</h3> <p><strong>Johan Gottlieb Gahn</strong> isolated metallic manganese in 1774 through carbon reduction of manganese dioxide, though the element was recognized earlier by <strong>Carl Wilhelm Scheele</strong> and others. Gahn's systematic approach established manganese as a distinct element rather than a form of iron or other known metals.</p> <h4>Industrial Development</h4> <p>Commercial manganese production began with <strong>ferromanganese smelting</strong> in the 1840s, revolutionizing steel production. The development of electric arc furnaces in the early 1900s enabled efficient manganese alloy production, supporting the steel industry's rapid expansion during industrialization.</p> </div>

Year of Discovery: 1774

Manganese: Abundant and Essential

Manganese forms through oxygen burning processes in massive stars and neutron capture reactions during stellar evolution. Its cosmic abundance reflects Manganese's nuclear stability and formation through multiple nucleosynthesis pathways in both regular stellar fusion and

explosive supernova events.

Terrestrial Abundance

Earth's crust contains approximately 1,050 parts per million Manganese, making it the 12th most abundant element. This high concentration enables widespread Manganese occurrence in rocks, soils, and water systems, supporting both geological processes and biological functions.

Major Manganese Deposits

Sedimentary Manganese deposits formed through chemical precipitation in ancient oceans account for 80% of global reserves. The Kalahari Manganese field in South Africa contains the world's largest high-grade deposits, formed through hydrothermal and sedimentary processes. Australia's Pilbara region hosts significant Manganese resources in banded iron formations.

Ocean Floor Resources

Manganese nodules covering vast areas of deep ocean floors represent enormous potential resources, containing 24-30% Manganese along with nickel, copper, and cobalt. These potato-sized concretions form through extremely slow precipitation processes over millions of years, though deep-sea mining remains technologically and environmentally challenging.

Biological Cycling

Manganese participates actively in Earth's biogeochemical cycles as an essential element for photosynthesis and enzyme function in all living organisms. Soil Manganese availability affects plant growth and agricultural productivity, while marine Manganese cycling influences ocean chemistry and productivity.

General Safety: Manganese should be handled with standard laboratory safety precautions including protective equipment and proper ventilation.

Manganese Safety: Neurological Concerns

Manganese

toxicity primarily affects the central nervous system, causing manganism - a Parkinson's-like condition from chronic inhalation exposure.
While Manganese is essential for health, occupational exposure requires careful monitoring and control.

Health Effects

Chronic Manganese exposure causes irreversible neurological damage including tremors, muscle rigidity, and psychiatric symptoms. Ferromanganese production and welding operations present the highest exposure risks through inhalation of Manganese-containing dusts and fumes.

Exposure Limits

  • OSHA PEL: 5 mg/m³ ceiling for Manganese compounds
  • NIOSH REL: 1 mg/m³ (10-hour TWA) for Manganese dust and compounds
  • ACGIH TLV: 0.02 mg/m³ (respirable fraction) for Manganese and inorganic compounds

Safety Measures

Respiratory protection, local exhaust ventilation, and biological monitoring through blood and urine Manganese levels help prevent neurological damage. Early detection and exposure reduction can prevent progression of manganism symptoms.

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