62
Sm
Samarium

Samarium

Element 62 • Lanthanide
Atomic Mass 150.360000
Electron Config Unknown
Group/Period ?/6

Physical Properties

MEASURED
Atomic Mass
150.360000 u
Melting Point
1345.00 °C
Boiling Point
2067.00 °C
Ionization Energy
5.58 kJ/mol

Special Properties

CLASSIFIED
STABLE Generally safe to handle with standard precautions

Applications

CATALOGUED

🧲 Magnetic Technology Revolution

Samarium stands as one of the most strategically important rare earth elements, driving innovations in high-performance magnets, nuclear technology, and advanced materials science. Its unique magnetic and neutron-absorbing properties make it indispensable for modern technology.

Super-Strong Permanent Magnets

Samarium-cobalt (SmCo) magnets represent the pinnacle of permanent magnet technology, maintaining magnetic strength at temperatures up to 350°C where neodymium magnets fail. These magnets power precision motors in satellites, military guidance systems, and high-end audio equipment.

Nuclear Reactor Control

Samarium-149 possesses the highest thermal neutron absorption cross-section of any stable nucleus, making it crucial for nuclear reactor control rods. This isotope naturally accumulates in reactor cores as a fission product, requiring careful management in reactor physics calculations.

Advanced Cancer Treatment

Samarium-153 serves as a radiopharmaceutical for treating bone cancer metastases. The isotope's targeted accumulation in bone tissue and controlled beta emission provides precise therapeutic radiation while minimizing damage to healthy organs.

Precision Optics and Lasers

Samarium-doped glasses create specialized optical components for infrared applications, including night vision systems, laser range finders, and fiber optic communications. The element's sharp absorption lines enable precise wavelength filtering.

Catalytic Processes

Samarium catalysts facilitate carbon-carbon bond formation in organic synthesis, particularly in pharmaceutical manufacturing. Samarium diiodide (SmI₂) enables unique reduction reactions impossible with conventional catalysts.

Innovation Driver: Samarium-cobalt magnets enable the miniaturization of high-performance motors, making possible everything from precision robotics to ultra-efficient wind turbines.

Common Uses

INDEXED

⚙️ Everyday Technology Applications

Electric Vehicle Motors

High-performance electric vehicles utilize Samarium-cobalt magnets in their drive motors due to exceptional temperature stability and power density. These magnets maintain efficiency during rapid acceleration and high-speed operation.

Aerospace Applications

Commercial and military aircraft rely on Samarium-cobalt magnets in actuators, sensors, and navigation equipment. The magnets' resistance to demagnetization at altitude and temperature extremes ensures reliable operation in aerospace environments.

Medical Devices

MRI machines incorporate Samarium compounds in contrast agents for enhanced imaging of specific tissues. Samarium's magnetic properties improve image resolution and diagnostic accuracy for certain medical conditions.

Audio Equipment

High-end speakers and headphones feature Samarium-cobalt magnets in their drivers, producing superior sound quality with minimal distortion. Audiophiles prize these components for their exceptional magnetic stability and acoustic performance.

Industrial Motors

Manufacturing equipment uses Samarium-based permanent magnet motors for precision positioning, high-speed machining, and automated assembly systems. These motors offer exceptional efficiency and controllability.

Consumer Electronics

Smartphones, tablets, and laptops contain micro-motors with Samarium magnets for camera autofocus, haptic feedback, and cooling fans. The miniaturization enabled by these powerful magnets allows for thinner, more efficient devices.

Natural Occurrence

SURVEYED

🌍 Global Rare Earth Deposits

Primary Mineral Sources

Samarium occurs primarily in monazite and bastnäsite deposits, typically comprising 1-8% of rare earth element content. The largest economically viable deposits are located in China (Bayan Obo), the United States (Mountain Pass, California), and Australia (Mount Weld).

Geological Formation

Samarium concentrates in alkaline igneous rocks and associated pegmatites through magmatic differentiation processes. Carbonatite complexes, formed by carbon dioxide-rich magmas, contain the highest Samarium concentrations due to preferential fractionation during crystallization.

Geographic Distribution

Significant Samarium resources exist in:

  • China: Inner Mongolia deposits (60% of global production)
  • United States: California and Alaska rare earth mines
  • Australia: Western Australian laterite deposits
  • India: Monazite beach sands along Kerala coast
  • Brazil: Minas Gerais state mineral complexes

Extraction Challenges

Samarium separation requires complex multi-stage processes involving ion exchange, solvent extraction, and fractional crystallization. The similarity of lanthanide chemical properties makes purification energy-intensive and technically demanding.

Environmental Considerations

Rare earth mining often involves radioactive thorium and uranium co-extraction, requiring specialized waste management. Environmental protection measures include groundwater monitoring, tailings pond management, and air quality control systems.

Supply Chain Security

Global Samarium supply concentration in few countries creates strategic materials concerns for technology-dependent nations. Recycling programs and alternative source development are increasingly important for supply security.

📊 Crustal Abundance: Samarium occurs at approximately 6 parts per million in Earth's crust, making it more abundant than tin but rarer than copper.

Discovery

ARCHIVED
1879

🔬 French Scientific Triumph

Paul-Émile Lecoq de Boisbaudran (1879)

French chemist Paul-Émile Lecoq de Boisbaudran discovered samarium while investigating the mineral samarskite from North Carolina. Using his pioneering spectroscopic techniques, he detected new spectral lines that couldn't be attributed to known elements.

Spectroscopic Detection

Boisbaudran employed flame spectroscopy to analyze rare earth concentrates, observing characteristic orange-red emission lines at wavelengths never before recorded. His meticulous observations and systematic approach established samarium as the first rare earth element discovered through spectroscopic analysis.

Naming Origins

The element was named after samarskite mineral, which itself honored Russian mining engineer Colonel Vasili Samarsky-Bykhovets. This made samarium the first element named after a living person, though indirectly through the mineral name.

Isolation Challenges

Pure samarium metal wasn't isolated until 1901 by Eugène-Anatole Demarçay, who used electrochemical reduction of samarium chloride. The 22-year gap between discovery and isolation demonstrates the technical challenges of rare earth element purification.

Industrial Development

Commercial samarium production began in the 1960s with the development of ion exchange separation techniques. The discovery of samarium-cobalt magnets by Albert Daane and Kenneth Strnat in 1966 transformed samarium from a laboratory curiosity into a strategically important material.

Scientific Impact

Samarium's discovery contributed to:

  • Rare earth chemistry understanding
  • Spectroscopic technique development
  • Periodic table completion
  • Lanthanide series characterization
🏆 Scientific Legacy: Boisbaudran's discovery methods established spectroscopy as the primary tool for identifying new elements, revolutionizing analytical chemistry.

Safety Information

CRITICAL

⚠️ Moderate Hazard Handling

Physical Hazards

Samarium metal presents fire risks when finely divided, igniting spontaneously in air above 150°C. Metal chips and powder require storage under inert atmosphere to prevent oxidation and potential combustion.

Chemical Reactivity

Samarium reacts slowly with water and acids, producing hydrogen gas and heat. Avoid contact with strong oxidizing agents, which can cause vigorous reactions. Samarium compounds may cause skin and eye irritation upon direct contact.

Personal Protection

  • Safety glasses and face shield for powder handling
  • Chemical-resistant gloves (nitrile or neoprene)
  • Laboratory coat and closed-toe shoes
  • Dust mask or respirator when generating particles

Safe Handling Practices

Work in well-ventilated areas or fume hoods when handling Samarium compounds. Use grounding straps and anti-static procedures when working with powders. Keep incompatible materials separated and clearly labeled.

Storage Requirements

Store Samarium metal under mineral oil or inert gas to prevent oxidation. Compounds should be kept in tightly sealed containers in cool, dry locations away from acids and oxidizers. Maintain temperature below 25°C for optimal stability.

Emergency Procedures

Fire incidents: Use dry sand, sodium chloride, or Class D fire extinguishers. Never use water on Samarium metal fires. Chemical spills: Neutralize with mild acid, absorb with inert material, and dispose according to regulations.

Low
Toxicity: Samarium has relatively low acute toxicity but should be handled with standard laboratory safety precautions to prevent accumulation exposure.

Knowledge Database

Essential information about Samarium (Sm)

Samarium is unique due to its atomic number of 62 and belongs to the Lanthanide category. With an atomic mass of 150.360000, it exhibits distinctive properties that make it valuable for various applications.

Samarium has several important physical properties:

Melting Point: 1345.00 K (1072°C)

Boiling Point: 2067.00 K (1794°C)

State at Room Temperature: solid

Atomic Radius: 180 pm

Samarium has various important applications in modern technology and industry:

🧲 Magnetic Technology Revolution

Samarium stands as one of the most strategically important rare earth elements, driving innovations in high-performance magnets, nuclear technology, and advanced materials science. Its unique magnetic and neutron-absorbing properties make it indispensable for modern technology.

Super-Strong Permanent Magnets

Samarium-cobalt (SmCo) magnets represent the pinnacle of permanent magnet technology, maintaining magnetic strength at temperatures up to 350°C where neodymium magnets fail. These magnets power precision motors in satellites, military guidance systems, and high-end audio equipment.

Nuclear Reactor Control

Samarium-149 possesses the highest thermal neutron absorption cross-section of any stable nucleus, making it crucial for nuclear reactor control rods. This isotope naturally accumulates in reactor cores as a fission product, requiring careful management in reactor physics calculations.

Advanced Cancer Treatment

Samarium-153 serves as a radiopharmaceutical for treating bone cancer metastases. The isotope's targeted accumulation in bone tissue and controlled beta emission provides precise therapeutic radiation while minimizing damage to healthy organs.

Precision Optics and Lasers

Samarium-doped glasses create specialized optical components for infrared applications, including night vision systems, laser range finders, and fiber optic communications. The element's sharp absorption lines enable precise wavelength filtering.

Catalytic Processes

Samarium catalysts facilitate carbon-carbon bond formation in organic synthesis, particularly in pharmaceutical manufacturing. Samarium diiodide (SmI₂) enables unique reduction reactions impossible with conventional catalysts.

Innovation Driver: Samarium-cobalt magnets enable the miniaturization of high-performance motors, making possible everything from precision robotics to ultra-efficient wind turbines.
1879

🔬 French Scientific Triumph

Paul-Émile Lecoq de Boisbaudran (1879)

French chemist Paul-Émile Lecoq de Boisbaudran discovered samarium while investigating the mineral samarskite from North Carolina. Using his pioneering spectroscopic techniques, he detected new spectral lines that couldn't be attributed to known elements.

Spectroscopic Detection

Boisbaudran employed flame spectroscopy to analyze rare earth concentrates, observing characteristic orange-red emission lines at wavelengths never before recorded. His meticulous observations and systematic approach established samarium as the first rare earth element discovered through spectroscopic analysis.

Naming Origins

The element was named after samarskite mineral, which itself honored Russian mining engineer Colonel Vasili Samarsky-Bykhovets. This made samarium the first element named after a living person, though indirectly through the mineral name.

Isolation Challenges

Pure samarium metal wasn't isolated until 1901 by Eugène-Anatole Demarçay, who used electrochemical reduction of samarium chloride. The 22-year gap between discovery and isolation demonstrates the technical challenges of rare earth element purification.

Industrial Development

Commercial samarium production began in the 1960s with the development of ion exchange separation techniques. The discovery of samarium-cobalt magnets by Albert Daane and Kenneth Strnat in 1966 transformed samarium from a laboratory curiosity into a strategically important material.

Scientific Impact

Samarium's discovery contributed to:

  • Rare earth chemistry understanding
  • Spectroscopic technique development
  • Periodic table completion
  • Lanthanide series characterization
🏆 Scientific Legacy: Boisbaudran's discovery methods established spectroscopy as the primary tool for identifying new elements, revolutionizing analytical chemistry.

Discovered by: <div class="discovery-story"> <h3>🔬 French Scientific Triumph</h3> <h4>Paul-Émile Lecoq de Boisbaudran (1879)</h4> <p>French chemist <strong>Paul-Émile Lecoq de Boisbaudran</strong> discovered samarium while investigating the mineral samarskite from North Carolina. Using his pioneering spectroscopic techniques, he detected new spectral lines that couldn't be attributed to known elements.</p> <h4>Spectroscopic Detection</h4> <p>Boisbaudran employed <em>flame spectroscopy</em> to analyze rare earth concentrates, observing characteristic orange-red emission lines at wavelengths never before recorded. His meticulous observations and systematic approach established samarium as the first rare earth element discovered through spectroscopic analysis.</p> <h4>Naming Origins</h4> <p>The element was named after <strong>samarskite mineral</strong>, which itself honored Russian mining engineer Colonel Vasili Samarsky-Bykhovets. This made samarium the first element named after a living person, though indirectly through the mineral name.</p> <h4>Isolation Challenges</h4> <p>Pure samarium metal wasn't isolated until <em>1901 by Eugène-Anatole Demarçay</em>, who used electrochemical reduction of samarium chloride. The 22-year gap between discovery and isolation demonstrates the technical challenges of rare earth element purification.</p> <h4>Industrial Development</h4> <p>Commercial samarium production began in the <strong>1960s</strong> with the development of ion exchange separation techniques. The discovery of samarium-cobalt magnets by Albert Daane and Kenneth Strnat in 1966 transformed samarium from a laboratory curiosity into a strategically important material.</p> <h4>Scientific Impact</h4> <p>Samarium's discovery contributed to:</p> <ul> <li><strong>Rare earth chemistry</strong> understanding</li> <li><em>Spectroscopic technique</em> development</li> <li><strong>Periodic table</strong> completion</li> <li>Lanthanide series characterization</li> </ul> <div class="legacy-note">🏆 <strong>Scientific Legacy:</strong> Boisbaudran's discovery methods established spectroscopy as the primary tool for identifying new elements, revolutionizing analytical chemistry.</div> </div>

Year of Discovery: 1879

🌍 Global Rare Earth Deposits

Primary Mineral Sources

Samarium occurs primarily in monazite and bastnäsite deposits, typically comprising 1-8% of rare earth element content. The largest economically viable deposits are located in China (Bayan Obo), the United States (Mountain Pass, California), and Australia (Mount Weld).

Geological Formation

Samarium concentrates in alkaline igneous rocks and associated pegmatites through magmatic differentiation processes. Carbonatite complexes, formed by carbon dioxide-rich magmas, contain the highest Samarium concentrations due to preferential fractionation during crystallization.

Geographic Distribution

Significant Samarium resources exist in:

  • China: Inner Mongolia deposits (60% of global production)
  • United States: California and Alaska rare earth mines
  • Australia: Western Australian laterite deposits
  • India: Monazite beach sands along Kerala coast
  • Brazil: Minas Gerais state mineral complexes

Extraction Challenges

Samarium separation requires complex multi-stage processes involving ion exchange, solvent extraction, and fractional crystallization. The similarity of lanthanide chemical properties makes purification energy-intensive and technically demanding.

Environmental Considerations

Rare earth mining often involves radioactive thorium and uranium co-extraction, requiring specialized waste management. Environmental protection measures include groundwater monitoring, tailings pond management, and air quality control systems.

Supply Chain Security

Global Samarium supply concentration in few countries creates strategic materials concerns for technology-dependent nations. Recycling programs and alternative source development are increasingly important for supply security.

📊 Crustal Abundance: Samarium occurs at approximately 6 parts per million in Earth's crust, making it more abundant than tin but rarer than copper.

General Safety: Samarium should be handled with standard laboratory safety precautions including protective equipment and proper ventilation.

⚠️ Moderate Hazard Handling

Physical Hazards

Samarium metal presents fire risks when finely divided, igniting spontaneously in air above 150°C. Metal chips and powder require storage under inert atmosphere to prevent oxidation and potential combustion.

Chemical Reactivity

Samarium reacts slowly with water and acids, producing hydrogen gas and heat. Avoid contact with strong oxidizing agents, which can cause vigorous reactions. Samarium compounds may cause skin and eye irritation upon direct contact.

Personal Protection

  • Safety glasses and face shield for powder handling
  • Chemical-resistant gloves (nitrile or neoprene)
  • Laboratory coat and closed-toe shoes
  • Dust mask or respirator when generating particles

Safe Handling Practices

Work in well-ventilated areas or fume hoods when handling Samarium compounds. Use grounding straps and anti-static procedures when working with powders. Keep incompatible materials separated and clearly labeled.

Storage Requirements

Store Samarium metal under mineral oil or inert gas to prevent oxidation. Compounds should be kept in tightly sealed containers in cool, dry locations away from acids and oxidizers. Maintain temperature below 25°C for optimal stability.

Emergency Procedures

Fire incidents: Use dry sand, sodium chloride, or Class D fire extinguishers. Never use water on Samarium metal fires. Chemical spills: Neutralize with mild acid, absorb with inert material, and dispose according to regulations.

Low
Toxicity: Samarium has relatively low acute toxicity but should be handled with standard laboratory safety precautions to prevent accumulation exposure.
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