58
Ce
Cerium

Cerium

Element 58 • Lanthanide
Atomic Mass 140.116000
Electron Config Unknown
Group/Period ?/6

Physical Properties

MEASURED
Atomic Mass
140.116000 u
Melting Point
1068.00 °C
Boiling Point
3716.00 °C
Ionization Energy
5.54 kJ/mol

Special Properties

CLASSIFIED
STABLE Generally safe to handle with standard precautions

Applications

CATALOGUED

Advanced Industrial Applications

Cerium is the most abundant rare earth element and the workhorse of the lanthanide series. Its unique ability to easily switch between Ce³⁺ and Ce⁴⁺ oxidation states makes it invaluable in countless applications.

Automotive Revolution

Catalytic converters in every modern car contain Cerium oxide (ceria), which helps convert

toxic carbon monoxide and nitrogen oxides into harmless gases.
Cerium's oxygen storage capacity makes it a crucial component in reducing vehicle emissions by up to 95%.

Glass & Ceramics Industry

Cerium dioxide is the universal glass polishing compound. From smartphone screens to telescope mirrors, Cerium oxide provides the finest polish achievable. It's also used to:

  • Decolorize glass by neutralizing iron impurities
  • UV protection in sunglasses and windows
  • Self-cleaning glass coatings for buildings
  • Optical fiber manufacturing for telecommunications

Pyrotechnics & Lighting

The brilliant white light in carbon arc lamps comes from Cerium carbide. Movie theaters, searchlights, and studio lighting all rely on Cerium for intense, sun-like illumination.

Nuclear Technology

Cerium's neutron absorption properties make it valuable in:

  • Nuclear fuel processing
  • Reactor control systems
  • Radiation shielding materials
  • Nuclear waste treatment

Chemical Processing

As a powerful oxygen storage material, Cerium oxide is used in:

  • Water-gas shift reactions for hydrogen production
  • Three-way catalysts in automotive applications
  • Fuel cell technologies
  • Chemical synthesis processes

Common Uses

INDEXED

Everyday Applications

Electronics & Displays

  • Smartphone screen polishing (every major manufacturer)
  • Computer monitor glass polishing
  • TV screen manufacturing
  • LED phosphor materials
  • Optical fiber production

Automotive Industry

  • Catalytic converters (emissions control)
  • Glass polishing for windshields
  • Fuel additives for cleaner combustion
  • Diesel engine particulate filters

Household Items

  • Self-cleaning oven coatings
  • UV-blocking window glass
  • Gas mantles for camping lanterns
  • Ceramic cookware glazes

Medical & Dental

  • Dental porcelain colorants
  • Medical device polishing
  • Radiation therapy equipment
  • Surgical instrument coatings

Tools & Manufacturing

  • Precision optics polishing
  • Glass cutting tools
  • Welding electrode coatings
  • High-temperature ceramics

Market Impact

The global demand for Cerium is approximately 60,000 tons annually, making it the most commercially important rare earth element. Glass polishing alone accounts for over 40% of Cerium consumption worldwide.

Natural Occurrence

SURVEYED

Natural Distribution

Cerium is the most abundant rare earth element and the 25th most abundant element in Earth's crust - more common than copper, lead, or zinc!

Abundance Statistics

  • Earth's Crust: 68 parts per million (ppm)
  • Ranking: 25th most abundant element
  • Ocean Water: 1.5 × 10⁻⁶ ppm
  • Relative Abundance: Makes up 50% of all rare earth elements

Primary Mineral Sources

Bastnäsite

Chemical formula: (Ce,La,Pr,Nd)CO₃F
Ce content: 45-50%
Major deposits: Mountain Pass (California), Bayan Obo (China)

Monazite

Chemical formula: (Ce,La,Nd,Th)PO₄
Ce content: 40-50%
Major deposits: India, Australia, Brazil, Malaysia

Allanite

Chemical formula: (Ce,Ca,Y)₂(Al,Fe)₃(SiO₄)₃(OH)
Ce content: 5-20%
Location: Pegmatites worldwide

Global Production Centers

  • China: 85% of world production (Inner Mongolia, Sichuan)
  • United States: Mountain Pass mine (Molycorp operation)
  • India: Beach sand mining in Kerala and Tamil Nadu
  • Australia: Mount Weld project (Lynas Corporation)
  • Brazil: Araxa and Catalao complexes
  • Russia: Kola Peninsula deposits

Geological Formation

Cerium concentrates in alkaline igneous complexes and carbonatites formed from deep mantle sources. The element substitutes for calcium in many minerals due to similar ionic radius, leading to its widespread distribution in igneous and metamorphic rocks.

Secondary Sources

  • Electronic waste recycling (phosphors, magnets)
  • Catalyst recycling from automotive industry
  • Glass polishing waste recovery
  • Mining tailings reprocessing

Discovery

ARCHIVED
1803

The Discovery Chronicles

1803 - The German Discovery

Martin Heinrich Klaproth, a German chemist famous for discovering uranium and zirconium, was the first to identify cerium. Working independently, he isolated cerium oxide from a mineral sample sent from Sweden.

1803 - The Swedish Discovery

Simultaneously, Swedish chemists Jöns Jakob Berzelius and Wilhelm Hisinger also discovered cerium while analyzing the same mineral - later named cerite in honor of the dwarf planet Ceres.

Astronomical Connection

The element was named after Ceres, the dwarf planet discovered just two years earlier in 1801 by Giuseppe Piazzi. This made cerium the first element named after an astronomical object!

The Race for Discovery

The simultaneous discovery of cerium by German and Swedish chemists created one of chemistry's first priority disputes. However, both parties graciously shared credit, establishing a precedent for international scientific cooperation.

"The new earth possesses properties so distinct that it cannot be confounded with any hitherto known."

— Berzelius and Hisinger, 1803

Early Research Challenges

Early researchers struggled with cerium's multiple oxidation states. The element appeared to change properties unpredictably, leading to confusion about whether multiple elements were present. It wasn't until the development of modern separation techniques that cerium's true nature was understood.

Key Breakthrough

The breakthrough came when scientists realized that cerium could exist as both Ce³⁺ and Ce⁴⁺ ions, unlike other rare earth elements. This unique property, initially a source of confusion, became cerium's greatest asset in modern applications.

Scientific Legacy

Cerium's discovery opened the door to understanding the entire rare earth series. The analytical techniques developed to study cerium laid the groundwork for separating and characterizing all 15 lanthanide elements.

Safety Information

CRITICAL

Safety Information

Low to Moderate Hazard Level

Cerium metal and most compounds are considered relatively safe with appropriate handling. However, some Cerium compounds require special pre

cautions.

Fire and Explosion Hazards

warning">

Cerium Metal: Pyrophoric when finely divided - can ignite spontaneously in air!

  • Store under inert atmosphere (argon or nitrogen)
  • Avoid grinding or creating fine particles
  • Class D fire extinguisher required (dry sand or special powder)
  • Never use water on Cerium fires - can cause violent reactions

Respiratory Considerations

  • Cerium Dust: Can cause respiratory irritation
  • Inhalation Risk: Potential pneumoconiosis with chronic exposure
  • Protection: Use NIOSH-approved respirators when handling powders

Contact Hazards

  • Eye Contact: Cerium compounds can cause severe irritation
  • Skin Contact: Generally non-irritating, but prolonged contact should be avoided
  • PPE: Safety glasses and nitrile gloves recommended

Emergency Procedures

Metal Fire

Use class D fire extinguisher. Evacuate area and call fire department. Do not use water!

Inhalation

Move to fresh air immediately. If breathing problems persist, seek medical attention.

Eye Contact

Flush with water for 15 minutes while holding eyelids open. Seek medical attention.

Skin Contact

Wash with soap and water. Remove contaminated clothing.

Storage and Handling

  • Metal: Store under inert gas in sealed containers
  • Compounds: Cool, dry storage away from acids
  • Separation: Keep away from strong oxidizers and water
  • Labeling: Clearly mark all containers with contents and hazards

Special Considerations

Cerium Nitrate: Strong oxidizer - can cause fires when in contact with organic materials. Requires special storage and handling procedures.

Knowledge Database

Essential information about Cerium (Ce)

Cerium is unique due to its atomic number of 58 and belongs to the Lanthanide category. With an atomic mass of 140.116000, it exhibits distinctive properties that make it valuable for various applications.

Cerium has several important physical properties:

Melting Point: 1068.00 K (795°C)

Boiling Point: 3716.00 K (3443°C)

State at Room Temperature: solid

Atomic Radius: 182 pm

Cerium has various important applications in modern technology and industry:

Advanced Industrial Applications

Cerium is the most abundant rare earth element and the workhorse of the lanthanide series. Its unique ability to easily switch between Ce³⁺ and Ce⁴⁺ oxidation states makes it invaluable in countless applications.

Automotive Revolution

Catalytic converters in every modern car contain Cerium oxide (ceria), which helps convert

toxic carbon monoxide and nitrogen oxides into harmless gases.
Cerium's oxygen storage capacity makes it a crucial component in reducing vehicle emissions by up to 95%.

Glass & Ceramics Industry

Cerium dioxide is the universal glass polishing compound. From smartphone screens to telescope mirrors, Cerium oxide provides the finest polish achievable. It's also used to:

  • Decolorize glass by neutralizing iron impurities
  • UV protection in sunglasses and windows
  • Self-cleaning glass coatings for buildings
  • Optical fiber manufacturing for telecommunications

Pyrotechnics & Lighting

The brilliant white light in carbon arc lamps comes from Cerium carbide. Movie theaters, searchlights, and studio lighting all rely on Cerium for intense, sun-like illumination.

Nuclear Technology

Cerium's neutron absorption properties make it valuable in:

  • Nuclear fuel processing
  • Reactor control systems
  • Radiation shielding materials
  • Nuclear waste treatment

Chemical Processing

As a powerful oxygen storage material, Cerium oxide is used in:

  • Water-gas shift reactions for hydrogen production
  • Three-way catalysts in automotive applications
  • Fuel cell technologies
  • Chemical synthesis processes
1803

The Discovery Chronicles

1803 - The German Discovery

Martin Heinrich Klaproth, a German chemist famous for discovering uranium and zirconium, was the first to identify cerium. Working independently, he isolated cerium oxide from a mineral sample sent from Sweden.

1803 - The Swedish Discovery

Simultaneously, Swedish chemists Jöns Jakob Berzelius and Wilhelm Hisinger also discovered cerium while analyzing the same mineral - later named cerite in honor of the dwarf planet Ceres.

Astronomical Connection

The element was named after Ceres, the dwarf planet discovered just two years earlier in 1801 by Giuseppe Piazzi. This made cerium the first element named after an astronomical object!

The Race for Discovery

The simultaneous discovery of cerium by German and Swedish chemists created one of chemistry's first priority disputes. However, both parties graciously shared credit, establishing a precedent for international scientific cooperation.

"The new earth possesses properties so distinct that it cannot be confounded with any hitherto known."

— Berzelius and Hisinger, 1803

Early Research Challenges

Early researchers struggled with cerium's multiple oxidation states. The element appeared to change properties unpredictably, leading to confusion about whether multiple elements were present. It wasn't until the development of modern separation techniques that cerium's true nature was understood.

Key Breakthrough

The breakthrough came when scientists realized that cerium could exist as both Ce³⁺ and Ce⁴⁺ ions, unlike other rare earth elements. This unique property, initially a source of confusion, became cerium's greatest asset in modern applications.

Scientific Legacy

Cerium's discovery opened the door to understanding the entire rare earth series. The analytical techniques developed to study cerium laid the groundwork for separating and characterizing all 15 lanthanide elements.

Discovered by: <div class="content-section"> <h3><i class="fas fa-user-graduate"></i> The Discovery Chronicles</h3> <div class="discovery-timeline"> <div class="timeline-item"> <h4><i class="fas fa-calendar-alt"></i> 1803 - The German Discovery</h4> <p><strong>Martin Heinrich Klaproth</strong>, a German chemist famous for discovering uranium and zirconium, was the first to identify cerium. Working independently, he isolated cerium oxide from a mineral sample sent from Sweden.</p> </div> <div class="timeline-item"> <h4><i class="fas fa-calendar-alt"></i> 1803 - The Swedish Discovery</h4> <p>Simultaneously, Swedish chemists <strong>Jöns Jakob Berzelius</strong> and <strong>Wilhelm Hisinger</strong> also discovered cerium while analyzing the same mineral - later named cerite in honor of the dwarf planet Ceres.</p> </div> <div class="timeline-item"> <h4><i class="fas fa-star"></i> Astronomical Connection</h4> <p>The element was named after <strong>Ceres</strong>, the dwarf planet discovered just two years earlier in 1801 by Giuseppe Piazzi. This made cerium the first element named after an astronomical object!</p> </div> </div> <div class="historical-context"> <h4><i class="fas fa-book-open"></i> The Race for Discovery</h4> <p>The simultaneous discovery of cerium by German and Swedish chemists created one of chemistry's first priority disputes. However, both parties graciously shared credit, establishing a precedent for international scientific cooperation.</p> <blockquote class="historical-quote"> <p>"The new earth possesses properties so distinct that it cannot be confounded with any hitherto known."</p> <footer>— Berzelius and Hisinger, 1803</footer> </blockquote> </div> <h4><i class="fas fa-microscope"></i> Early Research Challenges</h4> <p>Early researchers struggled with cerium's multiple oxidation states. The element appeared to change properties unpredictably, leading to confusion about whether multiple elements were present. It wasn't until the development of modern separation techniques that cerium's true nature was understood.</p> <div class="breakthrough-box"> <h4><i class="fas fa-lightbulb"></i> Key Breakthrough</h4> <p>The breakthrough came when scientists realized that cerium could exist as both Ce³⁺ and Ce⁴⁺ ions, unlike other rare earth elements. This unique property, initially a source of confusion, became cerium's greatest asset in modern applications.</p> </div> <h4><i class="fas fa-medal"></i> Scientific Legacy</h4> <p>Cerium's discovery opened the door to understanding the entire rare earth series. The analytical techniques developed to study cerium laid the groundwork for separating and characterizing all 15 lanthanide elements.</p> </div>

Year of Discovery: 1803

Natural Distribution

Cerium is the most abundant rare earth element and the 25th most abundant element in Earth's crust - more common than copper, lead, or zinc!

Abundance Statistics

  • Earth's Crust: 68 parts per million (ppm)
  • Ranking: 25th most abundant element
  • Ocean Water: 1.5 × 10⁻⁶ ppm
  • Relative Abundance: Makes up 50% of all rare earth elements

Primary Mineral Sources

Bastnäsite

Chemical formula: (Ce,La,Pr,Nd)CO₃F
Ce content: 45-50%
Major deposits: Mountain Pass (California), Bayan Obo (China)

Monazite

Chemical formula: (Ce,La,Nd,Th)PO₄
Ce content: 40-50%
Major deposits: India, Australia, Brazil, Malaysia

Allanite

Chemical formula: (Ce,Ca,Y)₂(Al,Fe)₃(SiO₄)₃(OH)
Ce content: 5-20%
Location: Pegmatites worldwide

Global Production Centers

  • China: 85% of world production (Inner Mongolia, Sichuan)
  • United States: Mountain Pass mine (Molycorp operation)
  • India: Beach sand mining in Kerala and Tamil Nadu
  • Australia: Mount Weld project (Lynas Corporation)
  • Brazil: Araxa and Catalao complexes
  • Russia: Kola Peninsula deposits

Geological Formation

Cerium concentrates in alkaline igneous complexes and carbonatites formed from deep mantle sources. The element substitutes for calcium in many minerals due to similar ionic radius, leading to its widespread distribution in igneous and metamorphic rocks.

Secondary Sources

  • Electronic waste recycling (phosphors, magnets)
  • Catalyst recycling from automotive industry
  • Glass polishing waste recovery
  • Mining tailings reprocessing

General Safety: Cerium should be handled with standard laboratory safety precautions including protective equipment and proper ventilation.

Safety Information

Low to Moderate Hazard Level

Cerium metal and most compounds are considered relatively safe with appropriate handling. However, some Cerium compounds require special pre

cautions.

Fire and Explosion Hazards

warning">

Cerium Metal: Pyrophoric when finely divided - can ignite spontaneously in air!

  • Store under inert atmosphere (argon or nitrogen)
  • Avoid grinding or creating fine particles
  • Class D fire extinguisher required (dry sand or special powder)
  • Never use water on Cerium fires - can cause violent reactions

Respiratory Considerations

  • Cerium Dust: Can cause respiratory irritation
  • Inhalation Risk: Potential pneumoconiosis with chronic exposure
  • Protection: Use NIOSH-approved respirators when handling powders

Contact Hazards

  • Eye Contact: Cerium compounds can cause severe irritation
  • Skin Contact: Generally non-irritating, but prolonged contact should be avoided
  • PPE: Safety glasses and nitrile gloves recommended

Emergency Procedures

Metal Fire

Use class D fire extinguisher. Evacuate area and call fire department. Do not use water!

Inhalation

Move to fresh air immediately. If breathing problems persist, seek medical attention.

Eye Contact

Flush with water for 15 minutes while holding eyelids open. Seek medical attention.

Skin Contact

Wash with soap and water. Remove contaminated clothing.

Storage and Handling

  • Metal: Store under inert gas in sealed containers
  • Compounds: Cool, dry storage away from acids
  • Separation: Keep away from strong oxidizers and water
  • Labeling: Clearly mark all containers with contents and hazards

Special Considerations

Cerium Nitrate: Strong oxidizer - can cause fires when in contact with organic materials. Requires special storage and handling procedures.

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