35
Br
Bromine

Bromine

Element 35 • Halogen
Atomic Mass 79.904000
Electron Config Unknown
Group/Period 17/4

Overview

ANALYZED
Bromine is the only liquid non-metal at room temperature and one of the most reactive elements on Earth! This dark reddish-brown liquid with its choking, penetrating odor is both fascinating and
dangerous.
The name comes from the Greek word "bromos" meaning stench, which perfectly describes its powerful, unpleasant smell that can be detected at extremely low concentrations. Discovered in 1826 by French chemist Antoine-Jérôme Balard while studying seaweed ash from the Mediterranean coast, Bromine was initially dismissed by other chemists who thought it was just a chlorine-iodine compound. Balard had to prove repeatedly that he had discovered a new element. Interestingly, German chemist Carl Jacob Löwig had isolated Bromine independently around the same time from mineral water, but Balard published first. What makes Bromine absolutely unique is its physical state - it's one of only two elements that are liquid at room temperature (mercury being the other). Bromine easily evaporates to form
toxic orange-brown vapors that are denser than air, creating dramatic demonstrations in chemistry classes.
Its reactivity is intense - it readily attacks organic materials, metals, and even reacts with water. Bromine has played crucial roles in photography, medicine, and industry. Silver bromide was essential for photographic film because it darkens when exposed to light. Bromide compounds were once widely used as sedatives (hence the phrase "taking a bromide" meaning something boring or calming). Today, Bromine compounds are essential flame retardants, protecting everything from furniture to electronics from fire. Here's something remarkable: Bromine is concentrated in seawater and salt lakes, with the Dead Sea containing the highest natural concentrations. Israel extracts vast amounts of Bromine from the Dead Sea, making it a major global producer of this valuable element.

Physical Properties

MEASURED
Atomic Mass
79.904000 u
Melting Point
265.80 °C
Boiling Point
332.00 °C
Ionization Energy
11.81 kJ/mol

Special Properties

CLASSIFIED
STABLE Generally safe to handle with standard precautions

Applications

CATALOGUED

Bromine: The Flame Retardant

Bromine's exceptional effectiveness as a flame retardant has saved countless lives by preventing fires in electronics, textiles, and transportation, while its chemical reactivity enables diverse applications from photography to oil drilling.

Flame Retardant Technology

Brominated flame retardants interrupt combustion chain reactions at the gas phase, providing superior fire protection compared to other halogen systems. Electronics applications include computer circuit boards, television casings, and automotive components where fire safety is critical for consumer protection and regulatory compliance.

Oil and Gas Production

Drilling fluids use Bromine compounds to increase density and control formation pressures in deep oil wells. Completion fluids containing cesium bromide or zinc bromide enable safe well completion in high-pressure, high-temperature environments where conventional fluids would fail.

Water Treatment

Bromine disinfection provides effective biocide action in swimming pools, spas, and cooling towers with better pH stability than chlorine systems. Industrial water treatment uses Bromine-based biocides to control microbial growth in recirculating systems and prevent biofilm formation.

Common Uses

INDEXED

Bromine: Safety and Industry

  • Fire Safety
    • Electronic device flame retardants (computers, TVs)
    • Automotive interior flame retardants
    • Textile and upholstery treatments
    • Building insulation fire protection
  • Water Treatment
    • Swimming pool and spa disinfection
    • Cooling tower biocide systems
    • Industrial water treatment
    • Municipal water disinfection systems
  • Oil & Gas Industry
    • Deep well drilling fluids
    • Well completion and workover fluids
    • Formation damage prevention
    • Pressure control systems
  • Chemical Manufacturing
    • Pharmaceutical intermediate production
    • Specialty chemical synthesis
    • Agricultural chemical manufacturing
    • Dye and pigment production

Natural Occurrence

SURVEYED

Bromine: Ocean Treasure

Bromine concentrates in seawater through evaporation and geological processes, with the Dead Sea containing the world's highest Bromine concentrations at 4,000-5,000 ppm. Most commercial Bromine extraction utilizes seawater or underground brines rather than solid mineral sources.

Brine Production

Seawater processing recovers Bromine through chlorine oxidation followed by steam distillation, while underground brine wells in Arkansas and Israel provide concentrated Bromine sources. The Smackover Formation in Arkansas contains brines with Bromine concentrations exceeding 4,000 ppm.

Discovery

ARCHIVED
1826

The Red Vapor Discovery

Antoine-Jérôme Balard discovered bromine in 1826 while studying seaweed ash from Mediterranean salt marshes. The distinctive red-brown vapor and pungent odor led Balard to identify this new halogen element, which he named from the Greek "bromos" meaning stench.

Safety Information

CRITICAL

Bromine Safety: Highly Corrosive

Bromine liquid and vapor are extremely corrosive and

toxic, requiring comprehensive safety measures for handling and storage.
Emergency response procedures are critical due to Bromine's potential for severe chemical burns and respiratory damage.

Exposure Limits

  • OSHA PEL: 0.1 ppm (8-hour TWA)
  • NIOSH REL: 0.1 ppm (10-hour TWA); 0.3 ppm (15-minute ceiling)
  • Emergency exposure: Immediately
    dangerous to life and health at 3 ppm

Safety Measures

Full-face respirators, acid-resistant clothing, and emergency shower/eyewash stations are mandatory for Bromine handling.

Vapor detection systems and emergency ventilation prevent
dangerous accumulations in work areas.

Knowledge Database

Essential information about Bromine (Br)

Bromine is unique due to its atomic number of 35 and belongs to the Halogen category. With an atomic mass of 79.904000, it exhibits distinctive properties that make it valuable for various applications.

Bromine has several important physical properties:

Melting Point: 265.80 K (-7°C)

Boiling Point: 332.00 K (59°C)

State at Room Temperature: liquid

Atomic Radius: 120 pm

Bromine has various important applications in modern technology and industry:

Bromine: The Flame Retardant

Bromine's exceptional effectiveness as a flame retardant has saved countless lives by preventing fires in electronics, textiles, and transportation, while its chemical reactivity enables diverse applications from photography to oil drilling.

Flame Retardant Technology

Brominated flame retardants interrupt combustion chain reactions at the gas phase, providing superior fire protection compared to other halogen systems. Electronics applications include computer circuit boards, television casings, and automotive components where fire safety is critical for consumer protection and regulatory compliance.

Oil and Gas Production

Drilling fluids use Bromine compounds to increase density and control formation pressures in deep oil wells. Completion fluids containing cesium bromide or zinc bromide enable safe well completion in high-pressure, high-temperature environments where conventional fluids would fail.

Water Treatment

Bromine disinfection provides effective biocide action in swimming pools, spas, and cooling towers with better pH stability than chlorine systems. Industrial water treatment uses Bromine-based biocides to control microbial growth in recirculating systems and prevent biofilm formation.

1826

The Red Vapor Discovery

Antoine-Jérôme Balard discovered bromine in 1826 while studying seaweed ash from Mediterranean salt marshes. The distinctive red-brown vapor and pungent odor led Balard to identify this new halogen element, which he named from the Greek "bromos" meaning stench.

Discovered by: <div class="discovery-content"> <h3>The Red Vapor Discovery</h3> <p><strong>Antoine-Jérôme Balard</strong> discovered bromine in 1826 while studying seaweed ash from Mediterranean salt marshes. The distinctive red-brown vapor and pungent odor led Balard to identify this new halogen element, which he named from the Greek "bromos" meaning stench.</p> </div>

Year of Discovery: 1826

Bromine: Ocean Treasure

Bromine concentrates in seawater through evaporation and geological processes, with the Dead Sea containing the world's highest Bromine concentrations at 4,000-5,000 ppm. Most commercial Bromine extraction utilizes seawater or underground brines rather than solid mineral sources.

Brine Production

Seawater processing recovers Bromine through chlorine oxidation followed by steam distillation, while underground brine wells in Arkansas and Israel provide concentrated Bromine sources. The Smackover Formation in Arkansas contains brines with Bromine concentrations exceeding 4,000 ppm.

General Safety: Bromine should be handled with standard laboratory safety precautions including protective equipment and proper ventilation.

Bromine Safety: Highly Corrosive

Bromine liquid and vapor are extremely corrosive and

toxic, requiring comprehensive safety measures for handling and storage.
Emergency response procedures are critical due to Bromine's potential for severe chemical burns and respiratory damage.

Exposure Limits

  • OSHA PEL: 0.1 ppm (8-hour TWA)
  • NIOSH REL: 0.1 ppm (10-hour TWA); 0.3 ppm (15-minute ceiling)
  • Emergency exposure: Immediately
    dangerous to life and health at 3 ppm

Safety Measures

Full-face respirators, acid-resistant clothing, and emergency shower/eyewash stations are mandatory for Bromine handling.

Vapor detection systems and emergency ventilation prevent
dangerous accumulations in work areas.

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