34
Se
Selenium

Selenium

Element 34 • Nonmetal
Atomic Mass 78.960000
Electron Config Unknown
Group/Period 16/4

Overview

ANALYZED
Selenium is the remarkable metalloid that protects life from oxidative damage while powering modern photocopiers and solar panels! This fascinating element exists in multiple forms with completely different properties - it can be a red powder, a gray metal-like solid, or a black glassy material. Named after the Greek word "selene" meaning moon, Selenium has gone from being considered a
toxic waste product to an essential nutrient and high-tech material.
Discovered in 1817 by Swedish chemist Jöns Jacob Berzelius, Selenium was initially mistaken for tellurium in the residue from sulfuric acid production. Berzelius noticed this residue had a distinctive smell when burned - like radishes - and realized it was a new element. For decades, Selenium was considered purely
toxic with no beneficial uses, earning a reputation as an industrial poison.
What makes Selenium absolutely crucial today is its unique photoelectric properties. When light hits Selenium, it generates electricity (photovoltaic effect) or changes its electrical conductivity (photoconductive effect). This discovery revolutionized technology, leading to photocopiers, light meters, solar cells, and photographic equipment. Before digital cameras, Selenium exposure meters were essential for photography. But here's the remarkable biological twist: Selenium turned out to be an essential trace element for all life! It's a key component of antioxidant enzymes like glutathione peroxidase that protect cells from damage by free radicals. Selenium deficiency can cause heart disease, weakened immunity, and reproductive problems. Brazil nuts are incredibly rich in Selenium - just two nuts provide your entire daily requirement. Selenium also has fascinating optical properties. Different forms of Selenium can be red, gray, or black, and it becomes electrically conductive when exposed to light. This photoconductivity made Selenium crucial for early television cameras and copying machines.

Physical Properties

MEASURED
Atomic Mass
78.960000 u
Melting Point
453.00 °C
Boiling Point
958.00 °C
Ionization Energy
9.75 kJ/mol

Special Properties

CLASSIFIED
STABLE Generally safe to handle with standard precautions

Applications

CATALOGUED

Selenium: The Photoelectric Pioneer

Selenium's unique photoelectric properties revolutionized electronics and continue to enable modern photovoltaic technology, while its biological importance makes it essential for human health and agricultural productivity.

Photovoltaic Applications

Copper indium gallium selenide (CIGS) thin-film solar cells achieve efficiencies exceeding 23% through Selenium's optimal bandgap properties for solar energy conversion. These flexible solar cells enable building-integrated photovoltaics and space applications where traditional silicon panels prove impractical.

Glass Manufacturing

Selenium decolorizing removes green tints from glass caused by iron impurities, creating crystal-clear optical glass for lenses, windows, and laboratory glassware. Ruby glass production uses Selenium to create brilliant red colors prized for decorative and artistic applications.

Electronic Components

Photoconductor drums in laser printers and photocopiers utilize Selenium's photosensitive properties to create latent electrostatic images. Rectifier diodes historically used Selenium's semiconductor properties before silicon dominance, though specialized Selenium rectifiers still serve niche applications.

Common Uses

INDEXED

Selenium: Hidden Essential

  • Solar Energy Systems
    • Thin-film solar panels for residential and commercial use
    • Building-integrated photovoltaic systems
    • Flexible solar cells for curved surfaces
    • Space-grade solar panels for satellites
  • Health & Nutrition
    • Dietary supplements and multivitamins
    • Animal feed supplements (livestock and poultry)
    • Selenium-enriched foods and beverages
    • Agricultural soil amendments
  • Manufacturing & Industry
    • Glass decolorizing and tinting processes
    • Rubber vulcanization and plastic additives
    • Metal alloy production and processing
    • Chemical catalyst applications
  • Electronics & Printing
    • Laser printer and photocopier drums
    • Photographic equipment and processes
    • Electronic rectifiers and switches
    • Light-sensitive devices and sensors

Natural Occurrence

SURVEYED

Selenium: Rare but Widespread

Selenium forms through neutron capture processes in stellar cores, with its abundance reflecting the element's position in the iron peak of nuclear binding energy. Terrestrial Selenium derives from both primordial condensation and later cosmic ray interactions in the upper atmosphere.

Terrestrial Distribution

Earth's crust contains approximately 0.09 parts per million Selenium, making it one of the rarer stable elements. Selenium rarely forms independent minerals, instead occurring as trace substituents in sulfur-bearing minerals and as selenide phases in precious metal deposits.

Industrial Recovery

Most commercial Selenium comes as a byproduct of copper refining, where Selenium concentrates in anode slimes during electrolytic copper purification. These slimes contain 5-25% Selenium, recovered through roasting, acid leaching, and chemical reduction processes.

Biological Concentration

Certain plants, particularly Selenium accumulator species like Astragalus and Stanleya, concentrate Selenium from soils, sometimes reaching

toxic levels.
These "Selenium indicator plants" help locate Selenium-rich geological formations and can cause selenosis in grazing livestock.

Discovery

ARCHIVED
1817

The Tellurium Impurity

Jöns Jakob Berzelius discovered selenium in 1817 while investigating residues from sulfuric acid production. Initially believing he had found tellurium contamination, Berzelius's careful analysis revealed a new element with similar properties but distinct characteristics, which he named selenium from the Greek "selene" meaning moon.

Safety Information

CRITICAL

Selenium Safety: Essential but
Toxic

Selenium exhibits a narrow margin between essential nutrition and toxicity.

While required for human health, excessive Selenium exposure causes selenosis with hair loss, nail brittleness, and neurological symptoms.

Occupational Limits

  • OSHA PEL: 0.2 mg/m³ (8-hour TWA) for Selenium compounds
  • NIOSH REL: 0.2 mg/m³ (10-hour TWA)
  • Hydrogen selenide: 0.05 ppm (extremely
    toxic gas)

Safety Measures

Respiratory protection and local exhaust ventilation prevent Selenium dust and vapor exposure.

Hydrogen selenide gas detection systems are essential in Selenium processing facilities due to its extreme
toxicity.

Knowledge Database

Essential information about Selenium (Se)

Selenium is unique due to its atomic number of 34 and belongs to the Nonmetal category. With an atomic mass of 78.960000, it exhibits distinctive properties that make it valuable for various applications.

Selenium has several important physical properties:

Melting Point: 453.00 K (180°C)

Boiling Point: 958.00 K (685°C)

State at Room Temperature: solid

Atomic Radius: 120 pm

Selenium has various important applications in modern technology and industry:

Selenium: The Photoelectric Pioneer

Selenium's unique photoelectric properties revolutionized electronics and continue to enable modern photovoltaic technology, while its biological importance makes it essential for human health and agricultural productivity.

Photovoltaic Applications

Copper indium gallium selenide (CIGS) thin-film solar cells achieve efficiencies exceeding 23% through Selenium's optimal bandgap properties for solar energy conversion. These flexible solar cells enable building-integrated photovoltaics and space applications where traditional silicon panels prove impractical.

Glass Manufacturing

Selenium decolorizing removes green tints from glass caused by iron impurities, creating crystal-clear optical glass for lenses, windows, and laboratory glassware. Ruby glass production uses Selenium to create brilliant red colors prized for decorative and artistic applications.

Electronic Components

Photoconductor drums in laser printers and photocopiers utilize Selenium's photosensitive properties to create latent electrostatic images. Rectifier diodes historically used Selenium's semiconductor properties before silicon dominance, though specialized Selenium rectifiers still serve niche applications.

1817

The Tellurium Impurity

Jöns Jakob Berzelius discovered selenium in 1817 while investigating residues from sulfuric acid production. Initially believing he had found tellurium contamination, Berzelius's careful analysis revealed a new element with similar properties but distinct characteristics, which he named selenium from the Greek "selene" meaning moon.

Discovered by: <div class="discovery-content"> <h3>The Tellurium Impurity</h3> <p><strong>Jöns Jakob Berzelius</strong> discovered selenium in 1817 while investigating residues from sulfuric acid production. Initially believing he had found tellurium contamination, Berzelius's careful analysis revealed a new element with similar properties but distinct characteristics, which he named selenium from the Greek "selene" meaning moon.</p> </div>

Year of Discovery: 1817

Selenium: Rare but Widespread

Selenium forms through neutron capture processes in stellar cores, with its abundance reflecting the element's position in the iron peak of nuclear binding energy. Terrestrial Selenium derives from both primordial condensation and later cosmic ray interactions in the upper atmosphere.

Terrestrial Distribution

Earth's crust contains approximately 0.09 parts per million Selenium, making it one of the rarer stable elements. Selenium rarely forms independent minerals, instead occurring as trace substituents in sulfur-bearing minerals and as selenide phases in precious metal deposits.

Industrial Recovery

Most commercial Selenium comes as a byproduct of copper refining, where Selenium concentrates in anode slimes during electrolytic copper purification. These slimes contain 5-25% Selenium, recovered through roasting, acid leaching, and chemical reduction processes.

Biological Concentration

Certain plants, particularly Selenium accumulator species like Astragalus and Stanleya, concentrate Selenium from soils, sometimes reaching

toxic levels.
These "Selenium indicator plants" help locate Selenium-rich geological formations and can cause selenosis in grazing livestock.

General Safety: Selenium should be handled with standard laboratory safety precautions including protective equipment and proper ventilation.

Selenium Safety: Essential but
Toxic

Selenium exhibits a narrow margin between essential nutrition and toxicity.

While required for human health, excessive Selenium exposure causes selenosis with hair loss, nail brittleness, and neurological symptoms.

Occupational Limits

  • OSHA PEL: 0.2 mg/m³ (8-hour TWA) for Selenium compounds
  • NIOSH REL: 0.2 mg/m³ (10-hour TWA)
  • Hydrogen selenide: 0.05 ppm (extremely
    toxic gas)

Safety Measures

Respiratory protection and local exhaust ventilation prevent Selenium dust and vapor exposure.

Hydrogen selenide gas detection systems are essential in Selenium processing facilities due to its extreme
toxicity.

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