49
In
Indium

Indium

Element 49 • Post-transition Metal
Atomic Mass 114.818000
Electron Config Unknown
Group/Period 13/5

Physical Properties

MEASURED
Atomic Mass
114.818000 u
Melting Point
429.75 °C
Boiling Point
2345.00 °C
Ionization Energy
5.79 kJ/mol

Special Properties

CLASSIFIED
STABLE Generally safe to handle with standard precautions

Applications

CATALOGUED

Flat-Panel Displays

Indium tin oxide (ITO) is the transparent conductor that makes modern touchscreens, LCD displays, and OLED screens possible. ITO films are nearly invisible yet electrically conductive, enabling the precise control needed for pixel activation. Every smartphone, tablet, and modern TV relies on Indium for its display functionality.

Semiconductor Technology

Indium compounds like Indium gallium arsenide (InGaAs) and Indium phosphide (InP) are crucial for high-speed electronics and optoelectronics. These materials enable infrared detectors, laser diodes, and high-frequency transistors used in fiber optic communications, satellite systems, and 5G networks.

Photovoltaic Applications

Copper Indium gallium selenide (CIGS) thin-film solar cells achieve high efficiency rates while using less material than traditional silicon panels. Indium's unique properties help create flexible solar cells that can be integrated into building materials, portable devices, and unconventional surfaces.

Low-Temperature Solders

Indium's low melting point (157°C) makes it ideal for specialized soldering applications where heat-sensitive components must be protected. Indium-based solders are used in cryogenic applications, thermal interface materials for computer processors, and sealing ultra-high vacuum systems.

Nuclear Control Systems

Indium's excellent neutron absorption properties make it valuable in nuclear reactors for neutron detection and control rod applications. Indium foils are used to measure neutron flux in reactor monitoring systems, helping ensure safe nuclear power operation.

Infrared Technology

Indium antimonide (InSb) and Indium arsenide (InAs) are essential for infrared detectors used in thermal imaging cameras, night vision equipment, and medical imaging systems. These materials detect heat signatures with exceptional sensitivity, enabling applications from military surveillance to medical diagnostics.

Light-Emitting Devices

Indium gallium nitride (InGaN) enables blue and white LED lighting, revolutionizing energy-efficient illumination. These LEDs are found in everything from flashlights to automotive headlights to large-scale architectural lighting, representing a major advancement in lighting technology.

Research Applications

Pure Indium serves as a temperature standard and is used in specialized research equipment. Its malleability allows it to form perfect seals in high-vacuum systems, while its unique electronic properties make it valuable for studying quantum effects and developing new electronic materials.

Common Uses

INDEXED

Smartphone & Tablet Screens

Every touchscreen device contains Indium tin oxide (ITO) as the transparent conductor layer. When you swipe your phone or tap your tablet, you're interacting with Indium. This invisible layer detects your finger's electrical field while remaining completely transparent to visible light.

Television & Computer Monitors

Modern LCD and OLED displays rely on ITO-coated glass to control individual pixels. Whether watching Netflix, gaming, or working on a computer, Indium enables the precise electrical control that creates the images you see. Higher-end displays often use more Indium for better performance.

LED Lighting

Energy-efficient LED bulbs and strips contain Indium gallium nitride, which produces blue light that phosphors convert to white light. From household lighting to automotive headlights to stadium illumination, Indium helps create the bright, efficient lighting that's replacing traditional bulbs.

Solar Panels

Some thin-film solar panels use CIGS (copper Indium gallium selenide) technology to convert sunlight into electricity. These panels can be flexible and lightweight, making them suitable for unconventional installations like curved surfaces or portable applications.

Automotive Electronics

Modern vehicles contain numerous displays and touchscreen interfaces that rely on Indium. From dashboard displays to entertainment systems to heads-up displays, Indium enables the interactive technology that makes driving safer and more convenient.

Digital Cameras & Imaging

Infrared sensors in digital cameras often use Indium-based materials to detect heat signatures or enable night vision capabilities. Security cameras, thermal imaging devices, and even some smartphone cameras benefit from Indium's unique optical properties.

Gaming Devices

Gaming consoles, handheld devices, and VR headsets all rely on Indium for their displays and touchscreen interfaces. The responsive, high-quality screens that enhance gaming experiences depend on Indium's transparent conducting properties.

Computer Components

High-performance computer processors use Indium-based thermal interface materials to efficiently transfer heat from chips to cooling systems. This helps prevent overheating and maintains optimal performance in demanding computing applications.

Natural Occurrence

SURVEYED

Indium is one of the rarest elements in Earth's crust, occurring at an average concentration of only 0.1 parts per million - making it rarer than silver or mercury. This precious metal is never found in its pure form in nature and rarely forms its own minerals.

Association with Zinc Ores

Indium is almost exclusively recovered as a byproduct of zinc production. The element substitutes for zinc in sulfide minerals, particularly sphalerite (ZnS), where Indium concentrations typically range from 0.001% to 0.1%. Major zinc-producing regions automatically become Indium sources, making Indium supply dependent on zinc market conditions.

Rare Indium Minerals

Only a few rare minerals contain significant Indium concentrations. The most important is indite (FeIn₂S₄), found in hydrothermal deposits. Other rare Indium minerals include roquesite (CuInS₂) and sakuraiite. These minerals are primarily of scientific interest rather than economic importance.

Global Distribution

China dominates Indium production (60% of world supply), primarily from zinc smelting operations. Other significant producers include South Korea, Japan, Canada, and Belgium. The Mount Isa mine in Australia and the Red Dog mine in Alaska are among the world's richest sources of Indium-bearing ores.

Recovery Challenges

Extracting Indium requires sophisticated metallurgical processes due to its extremely low concentrations. The element is recovered from zinc refinery residues through complex solvent extraction and electrowinning processes. Recovery rates are typically low, making Indium expensive and supply-constrained.

Secondary Sources

Recycling of Indium from electronic waste is becoming increasingly important as primary ore grades decline. ITO-coated glass from LCD manufacturing waste and end-of-life electronic devices provides valuable secondary Indium sources. However, recycling processes are complex and not yet widely implemented.

Laboratory Concentrations

Some coal ashes contain elevated Indium concentrations (up to 10 ppm), potentially offering future recovery opportunities. Certain types of volcanic rocks also show Indium enrichment, though not at economically viable levels with current technology.

Cosmic Abundance

Indium is extremely rare in the universe, with an abundance approximately 1/10,000th that of silver. The element forms through slow neutron capture processes in certain types of stars. Meteorites contain trace amounts of Indium, providing insights into early solar system formation processes.

Supply Concerns

Growing demand for touchscreen devices and LED lighting has raised concerns about Indium supply sustainability. The element's scarcity and concentration in few producing countries make it strategically important. Research into Indium alternatives and improved recycling methods is ongoing to address potential future shortages.

Discovery

ARCHIVED
1863

Indium was discovered in 1863 by German chemists Ferdinand Reich and Hieronymus Theodor Richter while searching for thallium in zinc ore samples. Their discovery came through the new technique of spectroscopy, which revealed an unexpected bright blue line that led to an entirely new element.

The Hunt for Thallium (1863)

Ferdinand Reich, a professor at the Freiberg School of Mines in Germany, was investigating zinc ore samples from a local mine, hoping to find thallium - an element that had been discovered just two years earlier. Reich was partially colorblind, so he enlisted the help of his colleague Hieronymus Richter to perform the crucial spectroscopic observations.

The Mysterious Blue Line

When Richter examined the spectroscopic flame of the zinc ore extract, instead of the expected green line of thallium, he observed a brilliant indigo-blue line at wavelength 451 nanometers. This spectral line didn't match any known element, indicating the presence of something entirely new. The intense blue color would later give the element its name.

Chemical Isolation

Reich and Richter worked methodically to isolate the unknown element from their zinc ore samples. They used precipitation reactions and careful chemical separations to concentrate the new substance. The process was challenging because indium was present in extremely small quantities - less than 0.01% of the ore sample.

First Pure Sample (1864)

After months of painstaking work, the duo successfully isolated a small amount of metallic indium in 1864. The metal was silvery-white, soft enough to mark paper like lead, and had a relatively low melting point. They named it "indium" from the Latin "indicum," meaning indigo, after the distinctive blue spectral line that led to its discovery.

Determining Properties

Early research revealed indium's unusual properties: it was extremely malleable, had a low melting point (157°C), and made a distinctive "tin cry" when bent. Chemists found it formed stable compounds and had an atomic weight of about 115, placing it between cadmium and tin in the periodic table.

The Curiosity Element

For nearly a century after its discovery, indium remained primarily a laboratory curiosity with no significant applications. Its rarity and the difficulty of extraction meant it was mainly studied by researchers interested in its unusual properties. Few could have predicted its future importance in technology.

The Electronics Revolution (1940s-present)

Indium's importance exploded with the development of semiconductor technology. The discovery that indium tin oxide (ITO) could be both transparent and electrically conductive revolutionized display technology. From the first experimental transistors to modern touchscreens, indium became essential to the digital age.

Modern Indispensability

Today, indium is critical to modern life in ways Reich and Richter never could have imagined. Every smartphone, tablet, and flat-screen TV depends on indium for its display. The element that was once a laboratory curiosity is now essential to global technology infrastructure, demonstrating how scientific discoveries can transform from academic interest to technological necessity.

Scientific Impact

The discovery of indium demonstrated the power of spectroscopy as a tool for finding new elements. This technique would lead to the discovery of several other elements in the following decades. The story also illustrates how collaborative scientific work - with Reich and Richter combining their different expertise - can lead to breakthrough discoveries.

Safety Information

CRITICAL

Generally Low
Toxicity

Pure metallic Indium has relatively low toxicity compared to other heavy metals.

However, some Indium compounds can be more
hazardous, and proper safety precautions should always be followed when handling Indium materials.

Skin & Eye Contact

Mild irritant: Direct contact with Indium metal is generally safe, but Indium compounds may cause skin and eye irritation. Wear gloves and safety glasses when handling Indium materials. Wash thoroughly after contact and seek medical attention if irritation persists.

Inhalation Concerns

Respiratory protection needed: Indium dust and fumes should not be inhaled. Some studies suggest potential lung damage from chronic exposure to Indium compounds, particularly Indium tin oxide (ITO). Use appropriate ventilation and respiratory protection when working with Indium materials.

Occupational Exposure

Electronics industry concerns: Workers in ITO sputtering operations and semiconductor manufacturing may face higher exposure risks. Regular health monitoring and strict exposure controls are recommended. Some cases of pulmonary alveolar proteinosis have been reported in workers exposed to Indium compounds.

Chemical Reactivity

Relatively stable: Metallic Indium is chemically stable under normal conditions. However, Indium compounds may react with acids or oxidizing agents. Store Indium materials in dry conditions to prevent oxidation and formation of potentially more

hazardous compounds.

Fire & Heat Hazards

Low melting point considerations: Indium melts at only 157°C (314°F), so it can liquify at moderate temperatures. Indium dust may be combustible. Avoid heating Indium materials without proper ventilation, as vapors may be harmful.

Environmental Impact

Responsible disposal: While Indium has lower environmental

toxicity than many heavy metals, proper disposal and recycling are important due to its rarity and economic value.
Electronic waste containing Indium should be processed through appropriate recycling facilities.

Emergency Procedures

Standard protocols: For skin contact, wash with soap and water. For eye contact, flush with clean water for 15 minutes. If Indium dust is inhaled, move to fresh air and seek medical attention if breathing difficulties occur. No specific antidotes are required for Indium exposure.

Knowledge Database

Essential information about Indium (In)

Indium is unique due to its atomic number of 49 and belongs to the Post-transition Metal category. With an atomic mass of 114.818000, it exhibits distinctive properties that make it valuable for various applications.

Indium has several important physical properties:

Melting Point: 429.75 K (157°C)

Boiling Point: 2345.00 K (2072°C)

State at Room Temperature: solid

Atomic Radius: 167 pm

Indium has various important applications in modern technology and industry:

Flat-Panel Displays

Indium tin oxide (ITO) is the transparent conductor that makes modern touchscreens, LCD displays, and OLED screens possible. ITO films are nearly invisible yet electrically conductive, enabling the precise control needed for pixel activation. Every smartphone, tablet, and modern TV relies on Indium for its display functionality.

Semiconductor Technology

Indium compounds like Indium gallium arsenide (InGaAs) and Indium phosphide (InP) are crucial for high-speed electronics and optoelectronics. These materials enable infrared detectors, laser diodes, and high-frequency transistors used in fiber optic communications, satellite systems, and 5G networks.

Photovoltaic Applications

Copper Indium gallium selenide (CIGS) thin-film solar cells achieve high efficiency rates while using less material than traditional silicon panels. Indium's unique properties help create flexible solar cells that can be integrated into building materials, portable devices, and unconventional surfaces.

Low-Temperature Solders

Indium's low melting point (157°C) makes it ideal for specialized soldering applications where heat-sensitive components must be protected. Indium-based solders are used in cryogenic applications, thermal interface materials for computer processors, and sealing ultra-high vacuum systems.

Nuclear Control Systems

Indium's excellent neutron absorption properties make it valuable in nuclear reactors for neutron detection and control rod applications. Indium foils are used to measure neutron flux in reactor monitoring systems, helping ensure safe nuclear power operation.

Infrared Technology

Indium antimonide (InSb) and Indium arsenide (InAs) are essential for infrared detectors used in thermal imaging cameras, night vision equipment, and medical imaging systems. These materials detect heat signatures with exceptional sensitivity, enabling applications from military surveillance to medical diagnostics.

Light-Emitting Devices

Indium gallium nitride (InGaN) enables blue and white LED lighting, revolutionizing energy-efficient illumination. These LEDs are found in everything from flashlights to automotive headlights to large-scale architectural lighting, representing a major advancement in lighting technology.

Research Applications

Pure Indium serves as a temperature standard and is used in specialized research equipment. Its malleability allows it to form perfect seals in high-vacuum systems, while its unique electronic properties make it valuable for studying quantum effects and developing new electronic materials.

1863

Indium was discovered in 1863 by German chemists Ferdinand Reich and Hieronymus Theodor Richter while searching for thallium in zinc ore samples. Their discovery came through the new technique of spectroscopy, which revealed an unexpected bright blue line that led to an entirely new element.

The Hunt for Thallium (1863)

Ferdinand Reich, a professor at the Freiberg School of Mines in Germany, was investigating zinc ore samples from a local mine, hoping to find thallium - an element that had been discovered just two years earlier. Reich was partially colorblind, so he enlisted the help of his colleague Hieronymus Richter to perform the crucial spectroscopic observations.

The Mysterious Blue Line

When Richter examined the spectroscopic flame of the zinc ore extract, instead of the expected green line of thallium, he observed a brilliant indigo-blue line at wavelength 451 nanometers. This spectral line didn't match any known element, indicating the presence of something entirely new. The intense blue color would later give the element its name.

Chemical Isolation

Reich and Richter worked methodically to isolate the unknown element from their zinc ore samples. They used precipitation reactions and careful chemical separations to concentrate the new substance. The process was challenging because indium was present in extremely small quantities - less than 0.01% of the ore sample.

First Pure Sample (1864)

After months of painstaking work, the duo successfully isolated a small amount of metallic indium in 1864. The metal was silvery-white, soft enough to mark paper like lead, and had a relatively low melting point. They named it "indium" from the Latin "indicum," meaning indigo, after the distinctive blue spectral line that led to its discovery.

Determining Properties

Early research revealed indium's unusual properties: it was extremely malleable, had a low melting point (157°C), and made a distinctive "tin cry" when bent. Chemists found it formed stable compounds and had an atomic weight of about 115, placing it between cadmium and tin in the periodic table.

The Curiosity Element

For nearly a century after its discovery, indium remained primarily a laboratory curiosity with no significant applications. Its rarity and the difficulty of extraction meant it was mainly studied by researchers interested in its unusual properties. Few could have predicted its future importance in technology.

The Electronics Revolution (1940s-present)

Indium's importance exploded with the development of semiconductor technology. The discovery that indium tin oxide (ITO) could be both transparent and electrically conductive revolutionized display technology. From the first experimental transistors to modern touchscreens, indium became essential to the digital age.

Modern Indispensability

Today, indium is critical to modern life in ways Reich and Richter never could have imagined. Every smartphone, tablet, and flat-screen TV depends on indium for its display. The element that was once a laboratory curiosity is now essential to global technology infrastructure, demonstrating how scientific discoveries can transform from academic interest to technological necessity.

Scientific Impact

The discovery of indium demonstrated the power of spectroscopy as a tool for finding new elements. This technique would lead to the discovery of several other elements in the following decades. The story also illustrates how collaborative scientific work - with Reich and Richter combining their different expertise - can lead to breakthrough discoveries.

Discovered by: <div class="discovery-story"> <div class="story-intro"> <p class="lead">Indium was discovered in 1863 by German chemists Ferdinand Reich and Hieronymus Theodor Richter while searching for thallium in zinc ore samples. Their discovery came through the new technique of spectroscopy, which revealed an unexpected bright blue line that led to an entirely new element.</p> </div> <div class="historical-timeline"> <div class="time-period"> <h3><i class="fas fa-search"></i> The Hunt for Thallium (1863)</h3> <p>Ferdinand Reich, a professor at the Freiberg School of Mines in Germany, was investigating zinc ore samples from a local mine, hoping to find thallium - an element that had been discovered just two years earlier. Reich was partially colorblind, so he enlisted the help of his colleague Hieronymus Richter to perform the crucial spectroscopic observations.</p> </div> <div class="time-period"> <h3><i class="fas fa-rainbow"></i> The Mysterious Blue Line</h3> <p>When Richter examined the spectroscopic flame of the zinc ore extract, instead of the expected green line of thallium, he observed a brilliant indigo-blue line at wavelength 451 nanometers. This spectral line didn't match any known element, indicating the presence of something entirely new. The intense blue color would later give the element its name.</p> </div> <div class="time-period"> <h3><i class="fas fa-flask"></i> Chemical Isolation</h3> <p>Reich and Richter worked methodically to isolate the unknown element from their zinc ore samples. They used precipitation reactions and careful chemical separations to concentrate the new substance. The process was challenging because indium was present in extremely small quantities - less than 0.01% of the ore sample.</p> </div> <div class="time-period"> <h3><i class="fas fa-atom"></i> First Pure Sample (1864)</h3> <p>After months of painstaking work, the duo successfully isolated a small amount of metallic indium in 1864. The metal was silvery-white, soft enough to mark paper like lead, and had a relatively low melting point. They named it "indium" from the Latin "indicum," meaning indigo, after the distinctive blue spectral line that led to its discovery.</p> </div> <div class="time-period"> <h3><i class="fas fa-balance-scale"></i> Determining Properties</h3> <p>Early research revealed indium's unusual properties: it was extremely malleable, had a low melting point (157°C), and made a distinctive "tin cry" when bent. Chemists found it formed stable compounds and had an atomic weight of about 115, placing it between cadmium and tin in the periodic table.</p> </div> <div class="time-period"> <h3><i class="fas fa-question"></i> The Curiosity Element</h3> <p>For nearly a century after its discovery, indium remained primarily a laboratory curiosity with no significant applications. Its rarity and the difficulty of extraction meant it was mainly studied by researchers interested in its unusual properties. Few could have predicted its future importance in technology.</p> </div> <div class="time-period"> <h3><i class="fas fa-tv"></i> The Electronics Revolution (1940s-present)</h3> <p>Indium's importance exploded with the development of semiconductor technology. The discovery that indium tin oxide (ITO) could be both transparent and electrically conductive revolutionized display technology. From the first experimental transistors to modern touchscreens, indium became essential to the digital age.</p> </div> <div class="time-period"> <h3><i class="fas fa-mobile-alt"></i> Modern Indispensability</h3> <p>Today, indium is critical to modern life in ways Reich and Richter never could have imagined. Every smartphone, tablet, and flat-screen TV depends on indium for its display. The element that was once a laboratory curiosity is now essential to global technology infrastructure, demonstrating how scientific discoveries can transform from academic interest to technological necessity.</p> </div> </div> <div class="discovery-significance"> <h3><i class="fas fa-lightbulb"></i> Scientific Impact</h3> <p>The discovery of indium demonstrated the power of spectroscopy as a tool for finding new elements. This technique would lead to the discovery of several other elements in the following decades. The story also illustrates how collaborative scientific work - with Reich and Richter combining their different expertise - can lead to breakthrough discoveries.</p> </div> </div>

Year of Discovery: 1863

Indium is one of the rarest elements in Earth's crust, occurring at an average concentration of only 0.1 parts per million - making it rarer than silver or mercury. This precious metal is never found in its pure form in nature and rarely forms its own minerals.

Association with Zinc Ores

Indium is almost exclusively recovered as a byproduct of zinc production. The element substitutes for zinc in sulfide minerals, particularly sphalerite (ZnS), where Indium concentrations typically range from 0.001% to 0.1%. Major zinc-producing regions automatically become Indium sources, making Indium supply dependent on zinc market conditions.

Rare Indium Minerals

Only a few rare minerals contain significant Indium concentrations. The most important is indite (FeIn₂S₄), found in hydrothermal deposits. Other rare Indium minerals include roquesite (CuInS₂) and sakuraiite. These minerals are primarily of scientific interest rather than economic importance.

Global Distribution

China dominates Indium production (60% of world supply), primarily from zinc smelting operations. Other significant producers include South Korea, Japan, Canada, and Belgium. The Mount Isa mine in Australia and the Red Dog mine in Alaska are among the world's richest sources of Indium-bearing ores.

Recovery Challenges

Extracting Indium requires sophisticated metallurgical processes due to its extremely low concentrations. The element is recovered from zinc refinery residues through complex solvent extraction and electrowinning processes. Recovery rates are typically low, making Indium expensive and supply-constrained.

Secondary Sources

Recycling of Indium from electronic waste is becoming increasingly important as primary ore grades decline. ITO-coated glass from LCD manufacturing waste and end-of-life electronic devices provides valuable secondary Indium sources. However, recycling processes are complex and not yet widely implemented.

Laboratory Concentrations

Some coal ashes contain elevated Indium concentrations (up to 10 ppm), potentially offering future recovery opportunities. Certain types of volcanic rocks also show Indium enrichment, though not at economically viable levels with current technology.

Cosmic Abundance

Indium is extremely rare in the universe, with an abundance approximately 1/10,000th that of silver. The element forms through slow neutron capture processes in certain types of stars. Meteorites contain trace amounts of Indium, providing insights into early solar system formation processes.

Supply Concerns

Growing demand for touchscreen devices and LED lighting has raised concerns about Indium supply sustainability. The element's scarcity and concentration in few producing countries make it strategically important. Research into Indium alternatives and improved recycling methods is ongoing to address potential future shortages.

General Safety: Indium should be handled with standard laboratory safety precautions including protective equipment and proper ventilation.

Generally Low
Toxicity

Pure metallic Indium has relatively low toxicity compared to other heavy metals.

However, some Indium compounds can be more
hazardous, and proper safety precautions should always be followed when handling Indium materials.

Skin & Eye Contact

Mild irritant: Direct contact with Indium metal is generally safe, but Indium compounds may cause skin and eye irritation. Wear gloves and safety glasses when handling Indium materials. Wash thoroughly after contact and seek medical attention if irritation persists.

Inhalation Concerns

Respiratory protection needed: Indium dust and fumes should not be inhaled. Some studies suggest potential lung damage from chronic exposure to Indium compounds, particularly Indium tin oxide (ITO). Use appropriate ventilation and respiratory protection when working with Indium materials.

Occupational Exposure

Electronics industry concerns: Workers in ITO sputtering operations and semiconductor manufacturing may face higher exposure risks. Regular health monitoring and strict exposure controls are recommended. Some cases of pulmonary alveolar proteinosis have been reported in workers exposed to Indium compounds.

Chemical Reactivity

Relatively stable: Metallic Indium is chemically stable under normal conditions. However, Indium compounds may react with acids or oxidizing agents. Store Indium materials in dry conditions to prevent oxidation and formation of potentially more

hazardous compounds.

Fire & Heat Hazards

Low melting point considerations: Indium melts at only 157°C (314°F), so it can liquify at moderate temperatures. Indium dust may be combustible. Avoid heating Indium materials without proper ventilation, as vapors may be harmful.

Environmental Impact

Responsible disposal: While Indium has lower environmental

toxicity than many heavy metals, proper disposal and recycling are important due to its rarity and economic value.
Electronic waste containing Indium should be processed through appropriate recycling facilities.

Emergency Procedures

Standard protocols: For skin contact, wash with soap and water. For eye contact, flush with clean water for 15 minutes. If Indium dust is inhaled, move to fresh air and seek medical attention if breathing difficulties occur. No specific antidotes are required for Indium exposure.

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