104 Rf Rutherfordium 267*
Transition metal d-block Period 7 Group 4 Radioactive Synthetic

Rutherfordium

Rf · Element 104 · Transition metal

The first transactinide — and chemically a heavier cousin of hafnium, not an actinide at all.

State at 20°C Solid~
Atomic mass 267 u
Electron configuration[Rn] 5f¹⁴ 6d² 7s²

Structure

The rutherfordium atom

Not a diagram of dots on rings — a Monte-Carlo sample of the actual probability density |ψ|² for each occupied subshell. Drag to rotate. Blue and violet mark opposite signs of the wavefunction, which is what makes bonding possible.

Orbital cloud

Measured values

Property sheet

Every bar shows where rutherfordium sits among all 118 elements for that property.

Physical

Density 23.2 g/cm³~ 93%
Melting point 2400 K~ 90%
Boiling point 5800 K~ 98%
Specific heat —
Thermal conductivity —

Atomic

Atomic radius 247 pm~ 85%
Covalent radius 157 pm~
Van der Waals radius 247 pm~

Electronic

Electronegativity —
Ionisation energy 578.9 kJ/mol~ 23%
Electron affinity —

Occurrence

Abundance in crust 0 mg/kg 0%

Identity

SymbolRf
Atomic number104
Atomic mass267 u
CategoryTransition metal
Blockd
Crystal structureunknown
Oxidation states+4
Discovered1964
Discovered byJINR Dubna & Berkeley

Sources: IUPAC 2021 standard atomic weights · CRC Handbook of Chemistry and Physics · NIST. Values marked ~ are predicted rather than measured.

Same element, different neutrons

Isotopes of rutherfordium

All rutherfordium atoms have the same number of protons, 104, and differ only in their number of neutrons: those variants are its isotopes. None of them is stable. The longest-lived known isotope, Rf-267, has 163 neutrons and a half-life of ~1.3 hr.

Long-lived and well-known isotopes of rutherfordium
ISOTOPE Neutrons Natural Abundance Half-life Decay Mode
Rf-257 153 — 4.4 sec α (79.3%), ε (19.4%), SF (1.3%)
Rf-261 157 — 68 sec α
Rf-263 159 — 10 min α
Rf-265 161 — ~1.0 min SF
Rf-267 longest-lived 163 — ~1.3 hr SF, α

Here the classroom shortcut, rounded atomic mass (267) minus atomic number, gives the same answer: 163.

Decay modes

α
alpha decay
ε
electron capture
SF
spontaneous fission

~ marks a half-life whose published uncertainty is larger than the value itself.

Data: IAEA Nuclear Data Section, LiveChart of Nuclides, ground-state evaluations, retrieved October 10, 2026. Abundance is the share of atoms in the natural element; a dash means the isotope has no standard natural abundance.

Size, to scale

How big is a rutherfordium atom?

Radius 247 pm — that is 0.247 nm, so about 2.02 million of them side by side would span a millimetre.

Thermal range

Solid, liquid, gas — and when

Rutherfordium is liquid over a 3400 K window, from 2400 K to 5800 K.

Where it sits

Position in the table

Rutherfordium sits in period 7, group 4. Everything in group 4 shares the same outer-electron count, which is why they behave so similarly.

Other transition metals

All transition metals

The story

What rutherfordium is, and how we found it

The first transactinide — and chemically a heavier cousin of hafnium, not an actinide at all.

The discovery of rutherfordium

International Discovery Race (1964-1969)

Rutherfordium's discovery became a major Cold War scientific competition between Soviet scientists at Dubna and American researchers at Berkeley. Both teams claimed priority, leading to a naming controversy that lasted decades until IUPAC resolution in 1997.

Soviet Union Initial Claims

In 1964, Georgy Flerov's team at the Joint Institute for Nuclear Research in Dubna reported creating element 104 by bombarding plutonium-242 with neon-22 ions. They proposed the name "kurchatovium" after Igor Kurchatov, father of the Soviet atomic bomb program.

Berkeley Laboratory Counter-Claims

In 1969, Albert Ghiorso's team at Berkeley Lab reported independent synthesis of element 104 by bombarding californium-249 with carbon-12 and carbon-13 ions. They proposed "rutherfordium" honoring New Zealand physicist Ernest Rutherford, father of nuclear physics.

IUPAC Resolution (1997)

The International Union of Pure and Applied Chemistry resolved the controversy in 1997, officially recognizing both teams' contributions but adopting "rutherfordium" as the standard name. This decision balanced scientific achievement with international diplomacy.

Modern Confirmation

Recent advances in detection technology have confirmed rutherfordium's properties and enabled discovery of new isotopes, including the 2025 discovery of rutherfordium-252 with high precision, validating theoretical predictions about superheavy nuclear behavior.

Applications

What rutherfordium is used for

Superheavy Element Gateway Research

Rutherfordium serves as the first true superheavy element beyond the actinide series, providing crucial insights into how matter behaves under very high nuclear charge conditions. Scientists use rutherfordium to validate theoretical predictions about electron configurations and chemical properties in the superheavy region.

Nuclear Stability Studies

Research teams employ rutherfordium to investigate nuclear shell effects and fission barriers that govern superheavy element stability. Rutherfordium-252, first reported in 2025 with a ground state that fissions in about 60 nanoseconds, provides critical data for understanding the "island of stability" predictions.

Relativistic Chemistry Investigation

Rutherfordium enables pioneering studies of relativistic effects in chemistry, where electron velocities reach significant fractions of light speed due to very high nuclear charge. These studies validate quantum mechanical calculations for superheavy atoms and predict chemical behavior of undiscovered elements.

Advanced Synthesis Technique Development

Scientists use rutherfordium research to develop and refine hot fusion reaction methods for creating superheavy elements. These techniques involve bombarding actinide targets with medium-mass ions, establishing pathways for synthesizing even heavier elements.

Nuclear Astrophysics Applications

Rutherfordium studies contribute to understanding r-process nucleosynthesis in neutron star mergers and supernovae, which are thought to make nuclei of mass 260 or more that split almost at once; no rutherfordium has ever been found in nature. This research helps explain heavy element abundance patterns in the universe.

Research Institution Applications

Rutherfordium applications are exclusively limited to world-leading nuclear research facilities including GSI in Germany, RIKEN in Japan, Berkeley Lab in the USA, and JINR in Russia. These facilities use rutherfordium for advanced superheavy element physics and chemistry research.

Nuclear Structure Analysis

Research teams utilize rutherfordium in precision nuclear measurements including spontaneous fission studies, alpha-decay energy determination, and nuclear lifetime measurements. The recent discovery of rutherfordium-252 provides new data on nuclear stability limits.

Single-Atom Chemistry Experiments

Scientists perform important atom-by-atom chemical studies with rutherfordium, investigating oxidation states, complex formation, and chemical bonding using gas-phase chromatography and extraction techniques at the limits of analytical chemistry.

Detection System Innovation

Rutherfordium research drives development of advanced detection technologies including gas-filled separators, position-sensitive detectors, and sophisticated data acquisition systems that enable identification and study of individual superheavy atoms.

Where it comes from

Natural occurrence

0 mg/kg of Earth's crust · more abundant than 0% of elements

Purely Artificial Element

Rutherfordium is known only from artificial synthesis in particle accelerators and has never been detected naturally on Earth or in cosmic phenomena. This superheavy element has never been found anywhere in nature.

Hot Fusion Synthesis Process

Scientists make rutherfordium directly by bombarding californium-249 with carbon-12 or -13 ions or curium-248 with oxygen ions; its longest-lived isotope, rutherfordium-267, appears at the end of decay chains of flerovium made by bombarding plutonium-242 with calcium-48 ions in a cyclotron. These "hot fusion" reactions require precise energy calibration to overcome strong electrostatic repulsion.

Ultrashort Nuclear Lifetime

The most stable rutherfordium isotope, 267Rf, has a half-life of only 1.3 hours, while most isotopes decay within seconds or minutes. The recently discovered 252Rf fissions in about 60 nanoseconds from its ground state, and an excited isomeric state survives about 13 microseconds, demonstrating the instability of superheavy nuclei.

Atom-by-Atom Production

Global rutherfordium production is measured in individual atoms per experiment, with successful synthesis runs producing perhaps 1-10 atoms per hour. Worldwide annual production totals fewer than thousands of atoms across all research facilities combined.

Cosmic Absence

Unlike elements formed through stellar nucleosynthesis or cosmic ray interactions, no rutherfordium survives in nature, and whether the r-process briefly makes it in neutron star mergers is still an open question. It represents a high point of artificial element creation.

Handling

Safety

Rutherfordium is radioactive. It has no stable isotope — every nucleus decays. Handling requires appropriate shielding and licensing.

Radiation Hazard

Rutherfordium is radioactive, but it is made only a few atoms at a time in heavy-ion accelerators. Its isotopes decay by spontaneous fission, alpha emission and electron capture; the longest-lived, rutherfordium-267, has a half-life of about 1.3 hours. No weighable amount of rutherfordium has ever existed, so the atoms themselves cannot deliver a meaningful radiation dose to anyone.

Where the Real Hazards Are

The hazards in this research come from the experiment, not the element: the accelerator beam, radioactive targets and activated equipment, and the waste these produce. They are controlled by shielding and remote handling, and the waste is managed as radioactive waste under national radiation protection rules.

Worker Protection

Staff follow the standard occupational radiation rules: annual dose limits, personal dose monitoring and keeping doses as low as reasonably achievable. Workers under 18 face much lower dose limits than adults: one tenth of the adult limits under US Nuclear Regulatory Commission rules (10 CFR 20.1207), and 1 mSv a year at US Department of Energy laboratories (10 CFR 835.207). A worker who declares a pregnancy is limited to 5 mSv to the fetus over the whole pregnancy (10 CFR 20.1208 and 835.206).

Quick answers

Rutherfordium: common questions

What is rutherfordium?

Rutherfordium (symbol Rf) is element 104 on the periodic table, a transition metal in period 7, group 4. The first transactinide — and chemically a heavier cousin of hafnium, not an actinide at all. At room temperature it is expected to be a solid, and it is radioactive.

What is the electron configuration of rutherfordium?

Rutherfordium's ground-state electron configuration is [Rn] 5f¹⁴ 6d² 7s², giving 7 occupied shells with the distribution 2, 8, 18, 32, 32, 10, 2.

What are the melting and boiling points of rutherfordium?

No sample of rutherfordium has ever been condensed, so both figures are calculated rather than measured: it is predicted to melt at 2400 K (2126.9 °C) and boil at 5800 K (5526.9 °C). That puts it among the most refractory elements — it stays solid at temperatures that vaporise most metals.

What is the atomic mass of rutherfordium?

Rutherfordium has no stable isotope, so it has no standard atomic weight. The figure quoted, 267, is the mass number of its longest-lived known isotope.

How many neutrons does rutherfordium have?

Rutherfordium has no stable isotope. Its longest-lived known isotope, Rf-267, has 163 neutrons (mass number 267 minus atomic number 104) and a half-life of ~1.3 hr. The classroom shortcut, rounded atomic mass (267) minus atomic number, gives the same 163.

How dense is rutherfordium?

Rutherfordium is predicted to have a density of about 23.2 g/cm³, though no sample large enough to weigh has ever been made. Water is 1.0 g/cm³ for comparison.

Who discovered rutherfordium, and when?

Rutherfordium was discovered in 1964 by JINR Dubna & Berkeley. Origin of the name: Ernest Rutherford.

How common is rutherfordium on Earth?

Rutherfordium does not occur naturally on Earth in any meaningful quantity — it is made in a reactor or an accelerator.

Is rutherfordium radioactive?

Yes. Rutherfordium has no stable isotope — every one of its nuclei decays. It does not occur in usable quantities in nature and must be synthesised.