97 Bk Berkelium 247*
Actinide f-block Period 7 Radioactive Synthetic

Berkelium

Bk · Element 97 · Actinide

Made in milligram quantities and used mainly as a target for creating even heavier elements.

State at 20°C Solid
Atomic mass 247 u
Electron configuration[Rn] 5f⁹ 7s²

Structure

The berkelium atom

Not a diagram of dots on rings — a Monte-Carlo sample of the actual probability density |ψ|² for each occupied subshell. Drag to rotate. Blue and violet mark opposite signs of the wavefunction, which is what makes bonding possible.

Orbital cloud

Measured values

Property sheet

Every bar shows where berkelium sits among all 118 elements for that property.

Physical

Density 14.78 g/cm³ 80%
Melting point 1323 K 58%
Boiling point 2900 K 58%
Specific heat —
Thermal conductivity 10 W/m·K 24%

Atomic

Atomic radius 244 pm 79%
Covalent radius 168 pm~
Van der Waals radius 244 pm

Electronic

Electronegativity 1.3 30%
Ionisation energy 598.2 kJ/mol 32%
Electron affinity —

Occurrence

Abundance in crust 0 mg/kg 0%

Identity

SymbolBk
Atomic number97
Atomic mass247 u
CategoryActinide
Blockf
Crystal structurehexagonal close-packed
Oxidation states+3, +4
Discovered1949
Discovered byThompson, Ghiorso & Seaborg

Sources: IUPAC 2021 standard atomic weights · CRC Handbook of Chemistry and Physics · NIST. Values marked ~ are predicted rather than measured.

Same element, different neutrons

Isotopes of berkelium

All berkelium atoms have the same number of protons, 97, and differ only in their number of neutrons: those variants are its isotopes. None of them is stable. The longest-lived known isotope, Bk-247, has 150 neutrons and a half-life of 1380 yrs.

Long-lived and well-known isotopes of berkelium
ISOTOPE Neutrons Natural Abundance Half-life Decay Mode
Bk-245 148 — 4.95 days ε
Bk-246 149 — 1.80 days ε/β⁺
Bk-247 longest-lived 150 — 1380 yrs α
Bk-248 151 — >9 yrs —
Bk-249 152 — 330 days β⁻

Here the classroom shortcut, rounded atomic mass (247) minus atomic number, gives the same answer: 150.

Decay modes

ε
electron capture
β⁺
positron emission
α
alpha decay
β⁻
beta-minus decay

Data: IAEA Nuclear Data Section, LiveChart of Nuclides, ground-state evaluations, retrieved October 10, 2026. Abundance is the share of atoms in the natural element; a dash means the isotope has no standard natural abundance.

Size, to scale

How big is a berkelium atom?

Radius 244 pm — that is 0.244 nm, so about 2.05 million of them side by side would span a millimetre.

Thermal range

Solid, liquid, gas — and when

Berkelium is liquid over a 1577 K window, from 1323 K to 2900 K.

Where it sits

Position in the table

Berkelium sits in the actinide series, printed below the main grid.

Other actinides

All actinides

The story

What berkelium is, and how we found it

Made in milligram quantities and used mainly as a target for creating even heavier elements.

The discovery of berkelium

Berkeley Lab Discovery Team

Berkelium was discovered on December 19, 1949, at the University of California, Berkeley, by a brilliant team of nuclear chemists who were systematically creating new elements beyond uranium.

The Discovery Team

The berkelium discovery team included some of the most prominent nuclear scientists of the 20th century:

  • Glenn T. Seaborg - Team leader and Nobel Prize winner who discovered numerous transuranium elements
  • Stanley G. Thompson - Expert in actinide chemistry and radiochemical separations
  • Albert Ghiorso - Ingenious instrument designer and nuclear physicist
  • Kenneth Street Jr. - Radiochemist specializing in heavy element identification

The 60-Inch Cyclotron Experiment

The discovery used Berkeley's 60-inch cyclotron, one of the most powerful particle accelerators of its time:

  • Target Material: Americium-241 (only 1 microgram available!)
  • Projectile: Helium-4 nuclei (alpha particles) accelerated to 35 MeV
  • Nuclear Reaction: Am-241 + α → Bk-243 + 2 neutrons
  • Detection: Identified by characteristic alpha decay pattern

Identification Challenge

Confirming berkelium's discovery required great skill:

  • Minute Quantities: Only a few thousand atoms were produced
  • Short Half-Life: Bk-243 decays with a 4.5-hour half-life
  • Chemical Separation: Distinguished from other actinides by ion-exchange chromatography
  • Alpha Spectroscopy: Unique alpha particle energy signature confirmed the new element

Scientific Impact

The berkelium discovery was scientifically important because it:

  • Confirmed predictions about the actinide series structure
  • Demonstrated that elements heavier than neptunium could be systematically created
  • Validated theoretical models of nuclear shell structure
  • Opened pathways to discovering even heavier elements

Recognition and Legacy

The discovery team's work was recognized with numerous honors:

  • Nobel Prize in Chemistry (1951): Glenn Seaborg for transuranium element discoveries
  • Element Naming: Named after Berkeley, California, where it was discovered
  • Scientific Legacy: Established Berkeley Lab as the world's leading center for superheavy element research

Applications

What berkelium is used for

Research Applications

Berkelium represents one of the most challenging frontiers in nuclear research, with applications that push the boundaries of atomic science and our understanding of matter itself.

Nuclear Physics Research

Berkelium serves as a crucial stepping stone in the synthesis of even heavier elements. The Bk-249 isotope is used as a target material in particle accelerators to create elements 117 (Tennessine) and beyond. These experiments help scientists understand the theoretical "island of stability" - a predicted region where superheavy elements might exist for longer periods.

Actinide Chemistry Studies

Despite its rarity, berkelium provides unique insights into actinide chemistry. Researchers study its oxidation states (primarily +3 and +4) to understand electron behavior in the 5f orbital series. These studies are crucial for developing new theories about heavy element chemistry and predicting properties of undiscovered elements.

Educational Research Tools

Berkelium isotopes serve as educational tools in advanced nuclear chemistry courses, helping students understand:

  • Alpha decay processes and nuclear stability
  • Electron capture mechanisms
  • Complex ion formation in actinide solutions
  • Radiochemical separation techniques

Technological Development

Research with berkelium contributes to the development of advanced nuclear technologies, including improved methods for:

  • Isotope separation and purification
  • Radiation detection equipment calibration
  • Nuclear waste processing techniques
  • Theoretical modeling of nuclear processes

Future Applications

While limited to research, berkelium studies may eventually contribute to:

  • Development of new nuclear energy technologies
  • Advanced materials science applications
  • Improved understanding of stellar nucleosynthesis
  • Next-generation particle physics experiments

Limited Research Applications

Berkelium has no commercial applications due to its rarity, short half-life, and high radioactivity. All uses are confined to specialized nuclear research facilities.

Primary Research Uses

  • Target Material: Bk-249 is used as a target in particle accelerators to synthesize superheavy elements like Tennessine (Element 117)
  • Nuclear Studies: Investigation of nuclear properties, decay modes, and stability patterns in the actinide series
  • Chemical Research: Studies of actinide chemistry, oxidation states, and complex ion formation
  • Calibration Standards: Used in extremely small quantities to calibrate sensitive radiation detection equipment

Academic Applications

  • Graduate Research: Advanced studies in nuclear chemistry and physics programs
  • Theoretical Work: Validation of nuclear models and periodic trends in superheavy elements
  • Educational Demonstrations: Illustrating concepts of nuclear stability and radioactive decay

Analytical Applications

Berkelium isotopes serve as reference materials for:

  • Mass spectrometry calibration
  • Radiochemical analysis techniques
  • Nuclear reaction cross-section measurements
  • Alpha spectroscopy standards

Production Scale: Just over one gram of berkelium has been produced in the United States since 1967, in milligram batches, making it one of the rarest substances on Earth. A typical Oak Ridge processing campaign yields milligrams of berkelium-249 (22 mg for the tennessine experiment).

Where it comes from

Natural occurrence

0 mg/kg of Earth's crust · more abundant than 0% of elements

Entirely Synthetic Element

Berkelium does not occur naturally on Earth and must be artificially created in nuclear reactors or particle accelerators. It represents humanity's ability to create new forms of matter that do not exist in nature.

Production Methods

Nuclear Reactor Production: The primary method involves bombarding americium-241 with neutrons in high-flux nuclear reactors:

  • Am-241 + neutron → Am-242 → Cm-242 (beta decay)
  • Cm-242 + neutron → Cm-243 + neutron → Cm-244
  • Further neutron capture and beta decay eventually leads to Bk-249

Particle Accelerator Synthesis: Alternative method using heavy ion bombardment:

  • Bombardment of curium targets with alpha particles
  • Am-241 + α → Bk-243 + 2 neutrons (the 1949 discovery reaction)
  • Requires precise energy control and sophisticated detection systems

Isolation and Purification

Berkelium separation is extremely challenging due to:

  • Similar Chemistry: Nearly identical chemical properties to other actinides
  • Tiny Quantities: Only microgram amounts produced in months of reactor operation
  • Short Half-Life: Most isotopes decay within days to months
  • Complex Mixtures: Created alongside many other radioactive elements

Global Production Centers

Only a few facilities worldwide can produce berkelium:

  • Oak Ridge National Laboratory (USA): Primary global source using High Flux Isotope Reactor
  • Research Institute of Atomic Reactors (Russia): Limited production capabilities

Total Production: Just over 1 gram of berkelium has been produced in the United States since 1967

Current Availability: Typically less than 1 milligram exists worldwide at any given time

Handling

Safety

Berkelium is radioactive. It has no stable isotope — every nucleus decays. Handling requires appropriate shielding and licensing.

Radiation Hazard

WARNING: Berkelium-249 is intensely radioactive, about 1,600 curies per gram, and is dangerous mainly if it gets into the body. It poses serious health risks through multiple pathways and requires the highest level of safety protocols.

Primary Hazards

  • Beta Radiation: Berkelium-249 decays almost entirely by beta emission, and its decay product californium-249 builds up and emits alpha particles that can cause severe cellular damage
  • Internal Contamination: Extremely dangerous if inhaled, ingested, or absorbed through wounds
  • Bone Concentration: Accumulates in bones and liver, causing long-term radiation exposure
  • Carcinogenic: Significantly increases risk of bone cancer, liver cancer, and leukemia

Required Safety Measures

  • Containment Level: Must be handled only in specialized hot cells with multiple containment barriers
  • Personal Protection: Full radiation suits, supplied air systems, and dosimetry monitoring
  • Air Filtration: HEPA filtration systems to prevent airborne contamination
  • Waste Management: All contaminated materials must be managed as radioactive waste under national rules

Emergency Procedures

In case of berkelium exposure or contamination:

  • Immediate Evacuation: Clear the area immediately and seal off contaminated zones
  • Medical Attention: Seek immediate medical treatment from radiation specialists
  • Decontamination: Professional radiological decontamination required
  • Monitoring: Long-term health monitoring for exposed individuals

Legal Restrictions: Berkelium is regulated by national radiation authorities as radioactive material; it is not nuclear material under the IAEA Statute. Only licensed facilities with specialized equipment and trained personnel may handle it.

Quick answers

Berkelium: common questions

What is berkelium?

Berkelium (symbol Bk) is element 97 on the periodic table, an actinide in period 7. Made in milligram quantities and used mainly as a target for creating even heavier elements. At room temperature it is a solid, and it is radioactive.

What is the electron configuration of berkelium?

Berkelium's ground-state electron configuration is [Rn] 5f⁹ 7s², giving 7 occupied shells with the distribution 2, 8, 18, 32, 27, 8, 2.

What are the melting and boiling points of berkelium?

Berkelium melts at 1323 K (1049.9 °C) and boils at 2900 K (2626.9 °C).

What is the atomic mass of berkelium?

Berkelium has no stable isotope, so it has no standard atomic weight. The figure quoted, 247, is the mass number of its longest-lived known isotope.

How many neutrons does berkelium have?

Berkelium has no stable isotope. Its longest-lived known isotope, Bk-247, has 150 neutrons (mass number 247 minus atomic number 97) and a half-life of 1380 yrs. The classroom shortcut, rounded atomic mass (247) minus atomic number, gives the same 150.

How dense is berkelium?

Berkelium has a density of 14.78 g/cm³. Water is 1.0 g/cm³, so a block of berkelium is about 14.8× heavier.

What is the electronegativity of berkelium?

Berkelium has a Pauling electronegativity of 1.3. The scale runs from 0.70 (francium, the least greedy for electrons) to 3.98 (fluorine, the most). Values in this middle band tend to form covalent rather than strongly ionic bonds.

Who discovered berkelium, and when?

Berkelium was discovered in 1949 by Thompson, Ghiorso & Seaborg. Origin of the name: Berkeley, California.

How common is berkelium on Earth?

Berkelium does not occur naturally on Earth in any meaningful quantity — it is made in a reactor or an accelerator.

Is berkelium radioactive?

Yes. Berkelium has no stable isotope — every one of its nuclei decays. It does not occur in usable quantities in nature and must be synthesised.