58 Ce Cerium 140.116
Lanthanide f-block Period 6

Cerium

Ce · Element 58

The most abundant rare earth, more common in the crust than copper.

STATE AT 20°C Solid
ATOMIC MASS 140.116 u
ELECTRON CONFIGURATION [Xe] 4f¹ 5d¹ 6s²

Structure

The cerium atom

Not a diagram of dots on rings — a Monte-Carlo sample of the actual probability density |ψ|² for each occupied subshell. Drag to rotate. Blue and violet mark opposite signs of the wavefunction, which is what makes bonding possible.

Orbital cloud

Measured values

Property sheet

Every bar shows where cerium sits among all 118 elements for that property.

Physical

Density 6.77 g/cm³ 38%
Melting point 1068 K 44%
Boiling point 3716 K 79%
Specific heat 0.192 J/g·K
Thermal conductivity 11.1 W/m·K 34%

Atomic

Atomic radius 182 pm 70%
Covalent radius 204 pm
Van der Waals radius 235 pm

Electronic

Electronegativity 1.12 13%
Ionisation energy 534.5 kJ/mol 11%
Electron affinity 48.2 kJ/mol 31%

Occurrence

Abundance in crust 66.5 mg/kg 79%

Identity

SymbolCe
Atomic number58
Atomic mass140.116 u
CategoryLanthanide
Blockf
Crystal structureface-centered cubic
Oxidation states+3, +4
Discovered1803
Discovered byBerzelius, Hisinger & Klaproth

Sources: IUPAC 2021 standard atomic weights · CRC Handbook of Chemistry and Physics · NIST. Values marked ~ are predicted rather than measured.

Size, to scale

How big is a cerium atom?

Radius 182 pm — that is 0.182 nm, so about 2747 million of them side by side would span a millimetre.

Thermal range

Solid, liquid, gas — and when

Cerium is liquid over a 2648 K window, from 1068 K to 3716 K.

Where it sits

Position in the table

Cerium sits in the lanthanide series, printed below the main grid.

OTHER LANTHANIDES

All lanthanides

The story

What cerium is, and how we found it

The most abundant rare earth, more common in the crust than copper.

The discovery of cerium

The Discovery Chronicles

1803 - The German Discovery

Martin Heinrich Klaproth, a German chemist famous for discovering uranium and zirconium, was the first to identify cerium. Working independently, he isolated cerium oxide from a mineral sample sent from Sweden.

1803 - The Swedish Discovery

Simultaneously, Swedish chemists Jöns Jakob Berzelius and Wilhelm Hisinger also discovered cerium while analyzing the same mineral - later named cerite in honor of the dwarf planet Ceres.

Astronomical Connection

The element was named after Ceres, the dwarf planet discovered just two years earlier in 1801 by Giuseppe Piazzi. This made cerium the first element named after an astronomical object.

The Race for Discovery

The simultaneous discovery of cerium by German and Swedish chemists created one of chemistry's first priority disputes. However, both parties graciously shared credit, establishing a precedent for international scientific cooperation.

"The new earth possesses properties so distinct that it cannot be confounded with any hitherto known."

— Berzelius and Hisinger, 1803

Early Research Challenges

Early researchers struggled with cerium's multiple oxidation states. The element appeared to change properties unpredictably, leading to confusion about whether multiple elements were present. It wasn't until the development of modern separation techniques that cerium's true nature was understood.

Key Breakthrough

The breakthrough came when scientists realized that cerium could exist as both Ce³⁺ and Ce⁴⁺ ions, unlike other rare earth elements. This unique property, initially a source of confusion, became cerium's greatest asset in modern applications.

Scientific Legacy

Cerium's discovery opened the door to understanding the entire rare earth series. The analytical techniques developed to study cerium laid the groundwork for separating and characterizing all 15 lanthanide elements.

Applications

What cerium is used for

Advanced Industrial Applications

Cerium is the most abundant rare earth element and the workhorse of the lanthanide series. Its unique ability to easily switch between Ce³⁺ and Ce⁴⁺ oxidation states makes it invaluable in countless applications.

Automotive Revolution

Catalytic converters in every modern car contain cerium oxide (ceria), which helps convert toxic carbon monoxide and nitrogen oxides into low-hazard gases. Cerium's oxygen storage capacity makes it a crucial component in reducing vehicle emissions by up to 95%.

Glass & Ceramics Industry

Cerium dioxide is the universal glass polishing compound. From smartphone screens to telescope mirrors, cerium oxide provides the finest polish achievable. It's also used to:

  • Decolorize glass by neutralizing iron impurities
  • UV protection in sunglasses and windows
  • Self-cleaning glass coatings for buildings
  • Optical fiber manufacturing for telecommunications

Pyrotechnics & Lighting

The brilliant white light in carbon arc lamps comes from cerium carbide. Movie theaters, searchlights, and studio lighting all rely on cerium for intense, sun-like illumination.

Nuclear Technology

Cerium's neutron absorption properties make it valuable in:

  • Nuclear fuel processing
  • Reactor control systems
  • Radiation shielding materials
  • Nuclear waste treatment

Chemical Processing

As a powerful oxygen storage material, cerium oxide is used in:

  • Water-gas shift reactions for hydrogen production
  • Three-way catalysts in automotive applications
  • Fuel cell technologies
  • Chemical synthesis processes

Everyday Applications

Electronics & Displays

  • Smartphone screen polishing (every major manufacturer)
  • Computer monitor glass polishing
  • TV screen manufacturing
  • LED phosphor materials
  • Optical fiber production

Automotive Industry

  • Catalytic converters (emissions control)
  • Glass polishing for windshields
  • Fuel additives for cleaner combustion
  • Diesel engine particulate filters

Household Items

  • Self-cleaning oven coatings
  • UV-blocking window glass
  • Gas mantles for camping lanterns
  • Ceramic cookware glazes

Medical & Dental

  • Dental porcelain colorants
  • Medical device polishing
  • Radiation therapy equipment
  • Surgical instrument coatings

Tools & Manufacturing

  • Precision optics polishing
  • Glass cutting tools
  • Welding electrode coatings
  • High-temperature ceramics

Market Impact

The global demand for cerium is approximately 60,000 tons annually, making it the most commercially important rare earth element. Glass polishing alone accounts for over 40% of cerium consumption worldwide.

Where it comes from

Natural occurrence

66.5 mg/kg of Earth's crust · more abundant than 79% of elements

Natural Distribution

Cerium is the most abundant rare earth element and the 25th most abundant element in Earth's crust - more common than copper, lead, or zinc.

Abundance Statistics

  • Earth's Crust: 68 parts per million (ppm)
  • Ranking: 25th most abundant element
  • Ocean Water: 1.5 × 10⁻⁶ ppm
  • Relative Abundance: Makes up 50% of all rare earth elements

Primary Mineral Sources

Bastnäsite

Chemical formula: (Ce,La,Pr,Nd)CO₃F
Ce content: 45-50%
Major deposits: Mountain Pass (California), Bayan Obo (China)

Monazite

Chemical formula: (Ce,La,Nd,Th)PO₄
Ce content: 40-50%
Major deposits: India, Australia, Brazil, Malaysia

Allanite

Chemical formula: (Ce,Ca,Y)₂(Al,Fe)₃(SiO₄)₃(OH)
Ce content: 5-20%
Location: Pegmatites worldwide

Global Production Centers

  • China: 85% of world production (Inner Mongolia, Sichuan)
  • United States: Mountain Pass mine (Molycorp operation)
  • India: Beach sand mining in Kerala and Tamil Nadu
  • Australia: Mount Weld project (Lynas Corporation)
  • Brazil: Araxa and Catalao complexes
  • Russia: Kola Peninsula deposits

Geological Formation

Cerium concentrates in alkaline igneous complexes and carbonatites formed from deep mantle sources. The element substitutes for calcium in many minerals due to similar ionic radius, leading to its widespread distribution in igneous and metamorphic rocks.

Secondary Sources

  • Electronic waste recycling (phosphors, magnets)
  • Catalyst recycling from automotive industry
  • Glass polishing waste recovery
  • Mining tailings reprocessing

Handling

Safety

Safety Information

Low to Moderate Hazard Level

Cerium metal and most compounds are considered relatively safe with appropriate handling. However, some cerium compounds require special precautions.

Fire and Explosion Hazards

Cerium Metal: Pyrophoric when finely divided - can ignite spontaneously in air.

  • Store under inert atmosphere (argon or nitrogen)
  • Avoid grinding or creating fine particles
  • Class D fire extinguisher required (dry sand or special powder)
  • Never use water on cerium fires - can cause violent reactions

Respiratory Considerations

  • Cerium Dust: Can cause respiratory irritation
  • Inhalation Risk: Potential pneumoconiosis with chronic exposure
  • Protection: Use NIOSH-approved respirators when handling powders

Contact Hazards

  • Eye Contact: Cerium compounds can cause severe irritation
  • Skin Contact: Generally non-irritating, but prolonged contact should be avoided
  • PPE: Safety glasses and nitrile gloves recommended

Emergency Procedures

Metal Fire

Use class D fire extinguisher. Evacuate area and call fire department. Do not use water.

Inhalation

Move to fresh air immediately. If breathing problems persist, seek medical attention.

Eye Contact

Flush with water for 15 minutes while holding eyelids open. Seek medical attention.

Skin Contact

Wash with soap and water. Remove contaminated clothing.

Storage and Handling

  • Metal: Store under inert gas in sealed containers
  • Compounds: Cool, dry storage away from acids
  • Separation: Keep away from strong oxidizers and water
  • Labeling: Clearly mark all containers with contents and hazards

Special Considerations

Cerium Nitrate: Strong oxidizer - can cause fires when in contact with organic materials. Requires special storage and handling procedures.

Quick answers

Cerium: common questions

What is Cerium?

Cerium (symbol Ce) is element 58 on the periodic table, a lanthanide in period 6. The most abundant rare earth, more common in the crust than copper. At room temperature it is a solid.

What is the electron configuration of Cerium?

Cerium's ground-state electron configuration is [Xe] 4f¹ 5d¹ 6s², giving 6 occupied shells holding 2, 8, 18, 19, 9, 2 electrons respectively.

What are the melting and boiling points of Cerium?

Cerium melts at 1068 K (794.9 °C) and boils at 3716 K (3442.9 °C).

What is the atomic mass of Cerium?

The standard atomic weight of Cerium is 140.116 u. That is a weighted average across its naturally occurring isotopes, which is why it is rarely a whole number.

How dense is Cerium?

Cerium has a density of 6.77 g/cm³. Water is 1.0 g/cm³, so a block of cerium is about 6.8× heavier.

What is the electronegativity of Cerium?

Cerium has a Pauling electronegativity of 1.12. The scale runs from 0.70 (francium, the least greedy for electrons) to 3.98 (fluorine, the most). A value this low means it readily gives its outer electrons away, forming positive ions.

Who discovered Cerium, and when?

Cerium was discovered in 1803 by Berzelius, Hisinger & Klaproth. It is named after the dwarf planet Ceres.

How common is Cerium on Earth?

Cerium makes up about 66.5 mg/kg of the Earth's crust — uncommon, but not rare.