61 Pm Promethium 145*
Lanthanide f-block Period 6 Radioactive Synthetic

Promethium

Pm · Element 61

The only lanthanide with no stable isotope — it decayed away and had to be made in a reactor.

STATE AT 20°C Solid
ATOMIC MASS 145 u
ELECTRON CONFIGURATION [Xe] 4f⁵ 6s²

Structure

The promethium atom

Not a diagram of dots on rings — a Monte-Carlo sample of the actual probability density |ψ|² for each occupied subshell. Drag to rotate. Blue and violet mark opposite signs of the wavefunction, which is what makes bonding possible.

Orbital cloud

Measured values

Property sheet

Every bar shows where promethium sits among all 118 elements for that property.

Physical

Density 7.26 g/cm³ 46%
Melting point 1315 K 57%
Boiling point 3273 K 68%
Specific heat 0.18 J/g·K
Thermal conductivity 16.5 W/m·K 47%

Atomic

Atomic radius 183 pm 72%
Covalent radius 199 pm
Van der Waals radius 236 pm

Electronic

Electronegativity 1.13 14%
Ionisation energy 533.6 kJ/mol 10%
Electron affinity 48.2 kJ/mol 31%

Occurrence

Abundance in crust 0 mg/kg 0%

Identity

SymbolPm
Atomic number61
Atomic mass145 u
CategoryLanthanide
Blockf
Crystal structurerhombohedral
Oxidation states+3
Discovered1945
Discovered byMarinsky, Glendenin & Coryell

Sources: IUPAC 2021 standard atomic weights · CRC Handbook of Chemistry and Physics · NIST. Values marked ~ are predicted rather than measured.

Size, to scale

How big is a promethium atom?

Radius 183 pm — that is 0.183 nm, so about 2732 million of them side by side would span a millimetre.

Thermal range

Solid, liquid, gas — and when

Promethium is liquid over a 1958 K window, from 1315 K to 3273 K.

Where it sits

Position in the table

Promethium sits in the lanthanide series, printed below the main grid.

OTHER LANTHANIDES

All lanthanides

The story

What promethium is, and how we found it

The only lanthanide with no stable isotope — it decayed away and had to be made in a reactor.

The discovery of promethium

🔍 The Missing Element Mystery

Mendeleev's Prediction (1869)

When Dmitri Mendeleev organized the periodic table, he predicted the existence of an element between neodymium and samarium, calling it "eka-neodymium." For nearly 70 years, this remained chemistry's most elusive missing piece.

False Claims and Confusion (1900s-1920s)

Multiple scientists claimed discovery of element 61:

  • 1902: Bohuslav Brauner thought he found it in rare earth residues
  • 1914: Henry Moseley's X-ray studies suggested its existence
  • 1924: Italian scientists claimed isolation from Brazilian monazite

All claims were later proven incorrect due to inadequate separation techniques and contamination with neighboring elements.

The Oak Ridge Breakthrough (1945)

Charles Coryell, Jacob Marinsky, and Lawrence Glendenin at Oak Ridge National Laboratory finally isolated element 61 from uranium fission products during the Manhattan Project. Using advanced ion-exchange chromatography, they definitively identified and separated the radioactive element.

Naming Controversy (1945-1950)

The discoverers initially proposed "atomium" after the atomic age, but the name was rejected. After years of debate, they chose "promethium" after Prometheus, the Greek Titan who stole fire from the gods - symbolizing humanity's mastery over nuclear fire.

Scientific Validation

The discovery was confirmed through:

  • Beta radiation analysis showing characteristic decay patterns
  • X-ray crystallography of promethium compounds
  • Mass spectrometry confirming atomic mass 147
  • Chemical separation proving lanthanide properties
Historical Impact: Promethium's discovery marked the completion of the lanthanide series and demonstrated that all gaps in the periodic table below uranium could be filled through nuclear synthesis.

Applications

What promethium is used for

🚀 Advanced Nuclear Applications

Promethium, the only radioactive rare earth element with no stable isotopes, serves unique roles in specialized nuclear technologies. Promethium-147 generates beta radiation with a relatively safe energy level (225 keV), making it ideal for nuclear batteries that power deep-space missions where solar panels are ineffective.

Space Exploration Technology

NASA and other space agencies utilize promethium radioisotope thermoelectric generators (RTGs) for spacecraft venturing beyond Jupiter, where solar energy becomes insufficient. These compact power sources provide decades of reliable electricity for instruments on missions to Saturn, Uranus, and interstellar space.

Medical Research Applications

In nuclear medicine, promethium-147 serves as a beta-emitting tracer for studying metabolic processes and organ function. Its relatively short half-life (2.6 years) allows for detailed imaging while minimizing long-term radiation exposure to patients.

Precision Instrumentation

High-end scientific instruments employ promethium as a thickness gauge for measuring extremely thin materials in semiconductor manufacturing. The consistent beta emission provides precise measurements critical for quality control in microelectronics production.

Specialized Lighting Systems

Emergency exit signs and aircraft instrument panels utilize promethium's phosphorescent properties, where beta radiation excites phosphor coatings to produce self-powered illumination lasting years without external power sources.

⚠️ Special Handling Required: All promethium applications require strict radiation safety protocols and specialized containment systems due to its radioactive nature.

🔬 Specialized Scientific Uses

Nuclear Batteries

Promethium-147 powers betavoltaic cells used in pacemakers, remote weather stations, and scientific equipment in extreme environments. These batteries provide steady power for 10-20 years without maintenance, making them invaluable for inaccessible installations.

Luminous Paint Technology

Military and aviation industries use promethium-based radioluminescent paint for instrument dials, compass markings, and emergency lighting systems. The self-luminous property eliminates dependence on external light sources in critical applications.

Research Laboratory Equipment

Scientific research facilities employ promethium sources for beta radiation calibration of detection equipment, ensuring accurate measurements in nuclear physics experiments and environmental monitoring systems.

Quality Control Systems

Manufacturing industries utilize promethium-147 in thickness monitoring systems for paper, plastic, and metal sheet production, providing real-time quality assurance without physical contact with materials.

🚀 Emerging Applications

  • Micro-nuclear batteries for Internet of Things (IoT) sensors
  • Deep-sea exploration equipment power sources
  • Autonomous vehicle sensor calibration systems
  • Space habitat emergency lighting systems

Where it comes from

Natural occurrence

0 mg/kg of Earth's crust · more abundant than 0% of elements

🧪 Unique Synthetic Origin

No Natural Stability

Promethium holds the distinction of being the only lanthanide with no stable isotopes. Unlike other rare earth elements found in mineral deposits, promethium exists naturally only in trace amounts as a fission product in uranium ores, with concentrations so minimal they're virtually undetectable.

Nuclear Reactor Production

Virtually all promethium used today originates from nuclear reactor operations. The most useful isotope, Promethium-147, is produced by neutron bombardment of neodymium-146 in specialized research reactors, yielding approximately 1-2 grams per year globally.

Stellar Nucleosynthesis

In the cosmos, promethium forms during stellar nuclear processes but decays too rapidly to accumulate in detectable quantities. Astronomers have identified promethium spectral lines in certain variable stars, providing insights into stellar interior conditions and nucleosynthesis mechanisms.

Uranium Decay Chain

Natural uranium-235 fission occasionally produces promethium isotopes, but these decay within years to decades. Even in the most uranium-rich deposits, promethium concentrations remain below 10⁻¹⁸ grams per kilogram of ore.

Laboratory Synthesis

Research facilities produce promethium through:

  • Neutron activation of neodymium targets
  • Ion bombardment of samarium samples
  • Separation from nuclear reactor fission products
  • Particle accelerator synthesis for research quantities
💎 Ultimate Rarity: Promethium is considered one of the rarest elements on Earth, with total global inventory estimated at less than 1 kilogram at any given time.

Handling

Safety

Promethium is radioactive. It has no stable isotope — every nucleus decays. Handling requires appropriate shielding and licensing.

☢️ Radiation Safety Critical

Radiation Hazards

Primary Risk: Promethium-147 emits beta radiation (electrons) with maximum energy of 225 keV. While external exposure is relatively low-risk due to beta particles' limited penetration, internal contamination poses serious health threats.

Personal Protective Equipment

  • Laboratory coat and nitrile gloves (double-layered)
  • Safety glasses with side shields
  • Respiratory protection when handling powders
  • Personal dosimetry badges required

Handling Procedures

Work must be conducted in radiological fume hoods with negative pressure. Use remote handling tools when possible. Never eat, drink, or apply cosmetics in promethium work areas. Maintain strict inventory control of all sources.

Contamination Prevention

Work surfaces must be covered with absorbent plastic-backed paper. Monitor hands, clothing, and work areas with radiation detection equipment before leaving the laboratory. Decontaminate surfaces with appropriate cleaning solutions.

Emergency Procedures

Contamination incidents: Immediately notify radiation safety officer. Remove contaminated clothing and shower thoroughly. Seek medical evaluation for potential internal exposure. Spill cleanup requires specialized procedures and equipment.

Storage Requirements

Store in shielded containers within locked, posted radiological areas. Maintain temperature logs and visual inspection schedules. Sources must be inventoried monthly and leak-tested annually.

🚨 Emergency: Contact institutional radiation safety officer immediately for any promethium-related incidents or suspected contamination.

Quick answers

Promethium: common questions

What is Promethium?

Promethium (symbol Pm) is element 61 on the periodic table, a lanthanide in period 6. The only lanthanide with no stable isotope — it decayed away and had to be made in a reactor. At room temperature it is a solid, and it is radioactive.

What is the electron configuration of Promethium?

Promethium's ground-state electron configuration is [Xe] 4f⁵ 6s², giving 6 occupied shells holding 2, 8, 18, 23, 8, 2 electrons respectively.

What are the melting and boiling points of Promethium?

Promethium melts at 1315 K (1041.9 °C) and boils at 3273 K (2999.9 °C).

What is the atomic mass of Promethium?

Promethium has no stable isotope, so it has no standard atomic weight. The figure quoted, 145, is the mass number of its longest-lived known isotope.

How dense is Promethium?

Promethium has a density of 7.26 g/cm³. Water is 1.0 g/cm³, so a block of promethium is about 7.3× heavier.

What is the electronegativity of Promethium?

Promethium has a Pauling electronegativity of 1.13. The scale runs from 0.70 (francium, the least greedy for electrons) to 3.98 (fluorine, the most). A value this low means it readily gives its outer electrons away, forming positive ions.

Who discovered Promethium, and when?

Promethium was discovered in 1945 by Marinsky, Glendenin & Coryell. It is named after prometheus, who stole fire from the gods.

How common is Promethium on Earth?

Promethium does not occur naturally on Earth in any meaningful quantity — it is made in a reactor or an accelerator.

Is Promethium radioactive?

Yes. Promethium has no stable isotope — every one of its nuclei decays. It does not occur in usable quantities in nature and must be synthesised.