97 Bk Berkelium 247*
Actinide f-block Period 7 Radioactive Synthetic

Berkelium

Bk · Element 97

Made in nanogram quantities and used mainly as a target for creating even heavier elements.

STATE AT 20°C Solid
ATOMIC MASS 247 u
ELECTRON CONFIGURATION [Rn] 5f⁹ 7s²

Structure

The berkelium atom

Not a diagram of dots on rings — a Monte-Carlo sample of the actual probability density |ψ|² for each occupied subshell. Drag to rotate. Blue and violet mark opposite signs of the wavefunction, which is what makes bonding possible.

Orbital cloud

Measured values

Property sheet

Every bar shows where berkelium sits among all 118 elements for that property.

Physical

Density 14.78 g/cm³ 80%
Melting point 1323 K 58%
Boiling point 2900 K 58%
Specific heat
Thermal conductivity 10 W/m·K 25%

Atomic

Atomic radius 244 pm 79%
Covalent radius 168 pm
Van der Waals radius 244 pm

Electronic

Electronegativity 1.3 30%
Ionisation energy 580.8 kJ/mol 26%
Electron affinity 48.2 kJ/mol 31%

Occurrence

Abundance in crust 0 mg/kg 0%

Identity

SymbolBk
Atomic number97
Atomic mass247 u
CategoryActinide
Blockf
Crystal structurehexagonal close-packed
Oxidation states+3, +4
Discovered1949
Discovered byThompson, Ghiorso & Seaborg

Sources: IUPAC 2021 standard atomic weights · CRC Handbook of Chemistry and Physics · NIST. Values marked ~ are predicted rather than measured.

Size, to scale

How big is a berkelium atom?

Radius 244 pm — that is 0.244 nm, so about 2049 million of them side by side would span a millimetre.

Thermal range

Solid, liquid, gas — and when

Berkelium is liquid over a 1577 K window, from 1323 K to 2900 K.

Where it sits

Position in the table

Berkelium sits in the actinide series, printed below the main grid.

OTHER ACTINIDES

All actinides

The story

What berkelium is, and how we found it

Made in nanogram quantities and used mainly as a target for creating even heavier elements.

The discovery of berkelium

Berkeley Lab Discovery Team

Berkelium was discovered on December 19, 1949, at the University of California, Berkeley, by a brilliant team of nuclear chemists who were systematically creating new elements beyond uranium.

The Discovery Team

The berkelium discovery team included some of the most prominent nuclear scientists of the 20th century:

  • Glenn T. Seaborg - Team leader and Nobel Prize winner who discovered numerous transuranium elements
  • Stanley G. Thompson - Expert in actinide chemistry and radiochemical separations
  • Albert Ghiorso - Ingenious instrument designer and nuclear physicist
  • Kenneth Street Jr. - Radiochemist specializing in heavy element identification

The 60-Inch Cyclotron Experiment

The discovery used Berkeley's 60-inch cyclotron, one of the most powerful particle accelerators of its time:

  • Target Material: Americium-241 (only 1 microgram available!)
  • Projectile: Helium-4 nuclei (alpha particles) accelerated to 35 MeV
  • Nuclear Reaction: Am-241 + α → Bk-243 + 2 neutrons
  • Detection: Identified by characteristic alpha decay pattern

Identification Challenge

Confirming berkelium's discovery required extraordinary skill:

  • Minute Quantities: Only a few thousand atoms were produced
  • Short Half-Life: Bk-243 decays with a 4.5-hour half-life
  • Chemical Separation: Distinguished from other actinides by ion-exchange chromatography
  • Alpha Spectroscopy: Unique alpha particle energy signature confirmed the new element

Scientific Impact

The berkelium discovery was scientifically significant because it:

  • Confirmed predictions about the actinide series structure
  • Demonstrated that elements heavier than neptunium could be systematically created
  • Validated theoretical models of nuclear shell structure
  • Opened pathways to discovering even heavier elements

Recognition and Legacy

The discovery team's work was recognized with numerous honors:

  • Nobel Prize in Chemistry (1951): Glenn Seaborg for transuranium element discoveries
  • Element Naming: Named after Berkeley, California, where it was discovered
  • Scientific Legacy: Established Berkeley Lab as the world's leading center for superheavy element research

Applications

What berkelium is used for

Research Applications

Berkelium represents one of the most challenging frontiers in nuclear research, with applications that push the boundaries of atomic science and our understanding of matter itself.

Nuclear Physics Research

Berkelium serves as a crucial stepping stone in the synthesis of even heavier elements. The Bk-249 isotope is used as a target material in particle accelerators to create elements 117 (Tennessine) and beyond. These experiments help scientists understand the theoretical "island of stability" - a predicted region where superheavy elements might exist for longer periods.

Actinide Chemistry Studies

Despite its rarity, berkelium provides unique insights into actinide chemistry. Researchers study its oxidation states (primarily +3 and +4) to understand electron behavior in the 5f orbital series. These studies are crucial for developing new theories about heavy element chemistry and predicting properties of undiscovered elements.

Educational Research Tools

Berkelium isotopes serve as educational tools in advanced nuclear chemistry courses, helping students understand:

  • Alpha decay processes and nuclear stability
  • Electron capture mechanisms
  • Complex ion formation in actinide solutions
  • Radiochemical separation techniques

Technological Development

Research with berkelium contributes to the development of advanced nuclear technologies, including improved methods for:

  • Isotope separation and purification
  • Radiation detection equipment calibration
  • Nuclear waste processing techniques
  • Theoretical modeling of nuclear processes

Future Applications

While limited to research, berkelium studies may eventually contribute to:

  • Development of new nuclear energy technologies
  • Advanced materials science applications
  • Improved understanding of stellar nucleosynthesis
  • Next-generation particle physics experiments

Limited Research Applications

Berkelium has no commercial applications due to its extreme rarity, short half-life, and high radioactivity. All uses are confined to specialized nuclear research facilities.

Primary Research Uses

  • Target Material: Bk-249 is used as a target in particle accelerators to synthesize superheavy elements like Tennessine (Element 117)
  • Nuclear Studies: Investigation of nuclear properties, decay modes, and stability patterns in the actinide series
  • Chemical Research: Studies of actinide chemistry, oxidation states, and complex ion formation
  • Calibration Standards: Used in extremely small quantities to calibrate sensitive radiation detection equipment

Academic Applications

  • Graduate Research: Advanced studies in nuclear chemistry and physics programs
  • Theoretical Work: Validation of nuclear models and periodic trends in superheavy elements
  • Educational Demonstrations: Illustrating concepts of nuclear stability and radioactive decay

Analytical Applications

Berkelium isotopes serve as reference materials for:

  • Mass spectrometry calibration
  • Radiochemical analysis techniques
  • Nuclear reaction cross-section measurements
  • Alpha spectroscopy standards

Production Scale: Only microgram quantities of berkelium have ever been produced, making it one of the rarest substances on Earth. Annual global production is measured in nanograms.

Where it comes from

Natural occurrence

0 mg/kg of Earth's crust · more abundant than 0% of elements

Entirely Synthetic Element

Berkelium does not occur naturally on Earth and must be artificially created in nuclear reactors or particle accelerators. It represents humanity's ability to create new forms of matter that do not exist in nature.

Production Methods

Nuclear Reactor Production: The primary method involves bombarding americium-241 with neutrons in high-flux nuclear reactors:

  • Am-241 + neutron → Am-242 → Cm-242 (beta decay)
  • Cm-242 + neutron → Cm-243 + neutron → Cm-244
  • Further neutron capture and beta decay eventually leads to Bk-249

Particle Accelerator Synthesis: Alternative method using heavy ion bombardment:

  • Bombardment of curium targets with alpha particles
  • Cm-245 + α → Bk-249 + neutrons
  • Requires precise energy control and sophisticated detection systems

Isolation and Purification

Berkelium separation is extremely challenging due to:

  • Similar Chemistry: Nearly identical chemical properties to other actinides
  • Tiny Quantities: Only microgram amounts produced in months of reactor operation
  • Short Half-Life: Most isotopes decay within days to months
  • Complex Mixtures: Created alongside many other radioactive elements

Global Production Centers

Only a few facilities worldwide can produce berkelium:

  • Oak Ridge National Laboratory (USA): Primary global source using High Flux Isotope Reactor
  • Research Institute of Atomic Reactors (Russia): Limited production capabilities
  • Institute Laue-Langevin (France): Occasional production for European research

Total Production: Less than 1 gram of berkelium has been produced since its discovery in 1949

Current Availability: Typically less than 1 milligram exists worldwide at any given time

Handling

Safety

Berkelium is radioactive. It has no stable isotope — every nucleus decays. Handling requires appropriate shielding and licensing.

significant radiation hazard in quantity

WARNING: Berkelium is among the most radiotoxic materials known to science. It poses extreme health risks through multiple pathways and requires the highest level of safety protocols.

Primary Hazards

  • Alpha Radiation: Intense alpha particle emission can cause severe cellular damage
  • Internal Contamination: Extremely dangerous if inhaled, ingested, or absorbed through wounds
  • Bone Concentration: Accumulates in bones and liver, causing long-term radiation exposure
  • Carcinogenic: Significantly increases risk of bone cancer, liver cancer, and leukemia

Required Safety Measures

  • Containment Level: Must be handled only in specialized hot cells with multiple containment barriers
  • Personal Protection: Full radiation suits, supplied air systems, and dosimetry monitoring
  • Air Filtration: HEPA filtration systems to prevent airborne contamination
  • Waste Management: All materials must be treated as high-level radioactive waste

Emergency Procedures

In case of berkelium exposure or contamination:

  • Immediate Evacuation: Clear the area immediately and seal off contaminated zones
  • Medical Attention: Seek immediate medical treatment from radiation specialists
  • Decontamination: Professional radiological decontamination required
  • Monitoring: Long-term health monitoring for exposed individuals

Legal Restrictions: Berkelium is regulated as a nuclear material under international atomic energy agencies. Only licensed facilities with specialized equipment and trained personnel may handle it.

Quick answers

Berkelium: common questions

What is Berkelium?

Berkelium (symbol Bk) is element 97 on the periodic table, a actinide in period 7. Made in nanogram quantities and used mainly as a target for creating even heavier elements. At room temperature it is a solid, and it is radioactive.

What is the electron configuration of Berkelium?

Berkelium's ground-state electron configuration is [Rn] 5f⁹ 7s², giving 7 occupied shells holding 2, 8, 18, 32, 27, 8, 2 electrons respectively.

What are the melting and boiling points of Berkelium?

Berkelium melts at 1323 K (1049.9 °C) and boils at 2900 K (2626.9 °C).

What is the atomic mass of Berkelium?

Berkelium has no stable isotope, so it has no standard atomic weight. The figure quoted, 247, is the mass number of its longest-lived known isotope.

How dense is Berkelium?

Berkelium has a density of 14.78 g/cm³. Water is 1.0 g/cm³, so a block of berkelium is about 14.8× heavier.

What is the electronegativity of Berkelium?

Berkelium has a Pauling electronegativity of 1.3. The scale runs from 0.70 (francium, the least greedy for electrons) to 3.98 (fluorine, the most). Values in this middle band tend to form covalent rather than strongly ionic bonds.

Who discovered Berkelium, and when?

Berkelium was discovered in 1949 by Thompson, Ghiorso & Seaborg. It is named after berkeley, California.

How common is Berkelium on Earth?

Berkelium does not occur naturally on Earth in any meaningful quantity — it is made in a reactor or an accelerator.

Is Berkelium radioactive?

Yes. Berkelium has no stable isotope — every one of its nuclei decays. It does not occur in usable quantities in nature and must be synthesised.