Zirconium

Category: Transition metal

Atomic Number: 40

Period: 5 | Group: 4

Block: d-block

40
Zr
91.224

Description

Effectively transparent to neutrons, which is why it lines the fuel rods in nearly every nuclear reactor.

Physical Properties

Property Value
Phase at STP Solid
Density N/A
Melting Point 2128.00 K (1854.85 °C)
Boiling Point 4682.00 K (4408.85 °C)
Heat Capacity N/A

Atomic Properties

Property Value
Atomic Mass 91.2240 u
Electronegativity (Pauling) N/A
Oxidation States +2, +3, +4
Electron Configuration

Discovery & History

Discovered By Unknown
Discovery Year 1789
Named After Persian zargun, "gold-coloured"

The Gemstone Element

Martin Heinrich Klaproth discovered zirconium in 1789 while analyzing zircon gemstones. Jöns Jakob Berzelius first isolated impure zirconium metal in 1824, though pure zirconium was first made by the van Arkel-de Boer crystal bar process in 1925.

Isotopes

ISOTOPE Neutrons Natural Abundance Half-life Decay Mode
Zr-90 50 51.45% Stable -
Zr-91 51 11.22% Stable -
Zr-92 52 17.15% Stable -
Zr-94 54 17.38% Stable -
Zr-96 56 2.80% 2.0 × 10¹⁹ yrs -

Data: IAEA Nuclear Data Section, LiveChart of Nuclides, ground-state evaluations, retrieved October 10, 2026. Abundance is the share of atoms in the natural element; a dash means the isotope has no standard natural abundance.

Applications & Uses

Zirconium: The Nuclear Guardian

Zirconium's exceptional corrosion resistance and low neutron absorption make it indispensable for nuclear reactors, while its biocompatibility and strength enable advanced medical implants and aerospace applications.

Nuclear Reactor Applications

Zircaloy fuel cladding encases uranium fuel pellets in nuclear reactors, providing corrosion resistance in high-temperature water while allowing neutron transmission for sustained nuclear fission. Zirconium's low neutron absorption cross-section makes it ideal for reactor core components where neutron economy is critical.

Chemical Processing

Zirconium equipment handles highly corrosive chemicals including hydrochloric acid, sulfuric acid, and organic acids at temperatures and concentrations that destroy stainless steel within hours. Pharmaceutical and fine chemical manufacturing rely on zirconium's chemical inertness for high-purity processing.

Aerospace Applications

Zirconium alloys provide exceptional strength-to-weight ratios for aircraft components operating in corrosive environments. Space applications utilize zirconium's resistance to atomic oxygen and thermal cycling in satellite structural components.

Abundance

Earth's Crust N/A
Universe N/A