Samarium

Category: Lanthanide

Atomic Number: 62

Period: 6 | Group: N/A

Block: f-block

62
Sm
150.360

Description

A rare earth whose magnets keep working at temperatures that destroy neodymium.

Physical Properties

Property Value
Phase at STP Solid
Density N/A
Melting Point 1345.00 K (1071.85 °C)
Boiling Point 2067.00 K (1793.85 °C)
Heat Capacity N/A

Atomic Properties

Property Value
Atomic Mass 150.3600 u
Electronegativity (Pauling) N/A
Oxidation States +2, +3
Electron Configuration

Discovery & History

Discovered By Unknown
Discovery Year 1879
Named After The mineral samarskite

🔬 French Scientific Triumph

Paul-Émile Lecoq de Boisbaudran (1879)

French chemist Paul-Émile Lecoq de Boisbaudran discovered samarium while investigating the mineral samarskite from North Carolina. Using his pioneering spectroscopic techniques, he detected new spectral lines that couldn't be attributed to known elements.

Spectroscopic Detection

Boisbaudran employed flame spectroscopy to analyze rare earth concentrates, observing characteristic orange-red emission lines at wavelengths never before recorded. His meticulous observations and systematic approach established samarium as the first rare earth element discovered through spectroscopic analysis.

Naming Origins

The element was named after samarskite mineral , which itself honored Russian mining engineer Colonel Vasili Samarsky-Bykhovets. This made samarium the first element named, indirectly, after a person.

Isolation Challenges

Samarium metal was first isolated in 1903 by Wilhelm Muthmann , two years after Eugène-Anatole Demarçay obtained the first pure samarium oxide. The 24-year gap between discovery and isolation demonstrates the technical challenges of rare earth element purification.

Industrial Development

Commercial samarium production began in the 1960s with the development of ion exchange separation techniques. The discovery of samarium-cobalt magnets by Karl Strnat and Alden Ray in the 1960s transformed samarium from a laboratory curiosity into a strategically important material.

Scientific Impact

Samarium's discovery contributed to:

Rare earth chemistry understanding

Spectroscopic technique development

Periodic table completion

Lanthanide series characterization

🏆 Scientific Legacy: Boisbaudran's discovery methods established spectroscopy as the primary tool for identifying new elements, transforming analytical chemistry.

Isotopes

ISOTOPE Neutrons Natural Abundance Half-life Decay Mode
Sm-144 82 3.08% Stable -
Sm-147 85 15.00% 1.073 × 10¹¹ yrs α
Sm-148 86 11.25% 7 × 10¹⁵ yrs α
Sm-149 87 13.82% Stable -
Sm-150 88 7.37% Stable -
Sm-152 90 26.74% Stable -
Sm-153 91 - 46.284 hr β⁻
Sm-154 92 22.74% Stable -

Data: IAEA Nuclear Data Section, LiveChart of Nuclides, ground-state evaluations, retrieved October 10, 2026. Abundance is the share of atoms in the natural element; a dash means the isotope has no standard natural abundance.

Applications & Uses

🧲 Magnetic Technology

Samarium stands as one of the most strategically important rare earth elements, driving innovations in high-performance magnets, nuclear technology, and advanced materials science. Its unique magnetic and neutron-absorbing properties make it indispensable for modern technology.

Super-Strong Permanent Magnets

Samarium-cobalt (SmCo) magnets are the permanent magnets of choice for hot environments, maintaining magnetic strength at temperatures up to 350°C where neodymium magnets fail. These magnets power precision motors in satellites, military guidance systems, and high-end audio equipment.

Nuclear Reactor Control

Samarium-149 has a very large thermal neutron absorption cross-section , about 40,000 barns, which makes samarium useful in nuclear reactor control rods. This isotope naturally accumulates in reactor cores as a fission product, requiring careful management in reactor physics calculations.

Advanced Cancer Treatment

Samarium-153 serves as a radiopharmaceutical for treating bone cancer metastases. The isotope's targeted accumulation in bone tissue and controlled beta emission provides precise therapeutic radiation while minimizing damage to healthy organs.

Precision Optics and Lasers

Samarium-doped glasses create specialized optical components for infrared applications, including night vision systems, laser range finders, and fiber optic communications. The element's sharp absorption lines enable precise wavelength filtering.

Catalytic Processes

Samarium catalysts facilitate carbon-carbon bond formation in organic synthesis, particularly in pharmaceutical manufacturing. Samarium diiodide (SmI₂) enables unique reduction reactions impossible with conventional catalysts.

⚡ Innovation Driver: Samarium-cobalt magnets enable the miniaturization of high-performance motors, making possible everything from precision robotics to ultra-efficient wind turbines.

Abundance

Earth's Crust N/A
Universe N/A