Category: Actinide
Atomic Number: 94
Period: 7 | Group: N/A
Block: f-block
The element that made the atomic age possible and powers spacecraft beyond the Sun's reach.
| Property | Value |
|---|---|
| Phase at STP | Solid |
| Density | N/A |
| Melting Point | 913.00 K (639.85 °C) |
| Boiling Point | 3505.00 K (3231.85 °C) |
| Heat Capacity | N/A |
| Property | Value |
|---|---|
| Atomic Mass | 244.0000 u |
| Electronegativity (Pauling) | N/A |
| Oxidation States | +3, +4, +5, +6, +7 |
| Electron Configuration |
| Discovered By | Unknown |
|---|---|
| Discovery Year | 1940 |
| Named After | Pluto, next out from Neptune |
World-Changing Discovery - 1940-1941
Glenn T. Seaborg, Edwin McMillan, Joseph W. Kennedy, and Arthur Wahl at the University of California, Berkeley, discovered plutonium in late 1940 and early 1941. This discovery would literally change the course of world history and end World War II.
The Experiment
Deuteron Bombardment: On December 14, 1940, the team bombarded uranium-238 with deuterons (heavy hydrogen nuclei) in Berkeley's 60-inch cyclotron. They created neptunium-238, which then decayed into an unknown element with atomic number 94.
Chemical Isolation: Seaborg's brilliant chemistry work in early 1941 successfully isolated and identified element 94. They discovered it was fissile like uranium-235 but could be chemically separated from uranium much more easily - a crucial advantage for weapons production.
Manhattan Project Impact
Wartime Secrecy: The discovery was immediately classified as top secret. The Manhattan Project realized that plutonium offered a potentially easier path to nuclear weapons than enriching uranium-235, leading to the construction of massive production reactors at Hanford, Washington.
Trinity Test: The world's first nuclear weapon test on July 16, 1945, in New Mexico used a plutonium implosion device. Three weeks later, a similar plutonium bomb was dropped on Nagasaki, Japan, ending World War II.
Naming After Pluto
Planetary Theme: Following the pattern of neptunium (Neptune), the discoverers named element 94 "plutonium" after the dwarf planet Pluto. The name seemed especially fitting given Pluto's association with the underworld, reflecting plutonium's destructive potential.
Nobel Prize Recognition
Scientific Achievement: Glenn Seaborg won the Nobel Prize in Chemistry in 1951 for discovering plutonium and other transuranium elements. His work established the actinide series and transformed our understanding of heavy element chemistry.
Historical Significance
Atomic Age Beginning: Plutonium's discovery marked the true beginning of the Atomic Age. It enabled both nuclear weapons and nuclear power, fundamentally changing international relations, military strategy, and energy production for all future generations.
| ISOTOPE | Neutrons | Natural Abundance | Half-life | Decay Mode |
|---|---|---|---|---|
| Pu-238 | 144 | - | 87.7 yrs | α |
| Pu-239 | 145 | - | 24110 yrs | α |
| Pu-240 | 146 | - | 6561 yrs | α |
| Pu-241 | 147 | - | 14.329 yrs | β⁻ |
| Pu-242 | 148 | - | 3.73 × 10⁵ yrs | α |
| Pu-244 | 150 | - | 8.13 × 10⁷ yrs | α |
Data: IAEA Nuclear Data Section, LiveChart of Nuclides, ground-state evaluations, retrieved October 10, 2026. Abundance is the share of atoms in the natural element; a dash means the isotope has no standard natural abundance.
Nuclear Power Generation
Nuclear Reactor Fuel: Plutonium-239 is one of the most important fissile materials for nuclear power generation. Mixed oxide (MOX) fuel containing plutonium provides a sustainable way to recycle nuclear waste while generating clean electricity for millions of homes worldwide.
Fast Breeder Reactors: Advanced reactor designs use plutonium as both fuel and breeding material, potentially providing centuries of clean nuclear energy while consuming existing nuclear waste. Countries like Russia, China, and India operate successful plutonium-fueled fast reactors.
Space Exploration Power
Radioisotope Thermoelectric Generators (RTGs): Plutonium-238 powers some of humanity's greatest space achievements, including the Voyager probes (now in interstellar space), the Curiosity and Perseverance Mars rovers, and the New Horizons mission to Pluto. These RTGs provide reliable power for decades in the harsh environment of space.
Deep Space Missions: Plutonium's long half-life and high energy density make it the preferred power source for missions far beyond Mars, although Juno and Europa Clipper show that large solar arrays work at Jupiter. Future missions to the outer planets and interstellar space depend on plutonium power sources.
Medical Applications
Cardiac Pacemakers: Plutonium-238 powered early cardiac pacemakers, providing reliable power for patients for over 20 years. While newer battery technologies have largely replaced them, some long-lived medical implants still use plutonium power sources.
Medical Research: Controlled amounts of plutonium isotopes are used in advanced medical research to understand radiation effects and develop new cancer treatments, though this requires the highest safety protocols.
Nuclear Physics Research
Fundamental Research: Plutonium's unique nuclear properties make it essential for studying nuclear fission, fusion reactions, and the behavior of heavy nuclei. This research advances our understanding of stellar nucleosynthesis and the origins of heavy elements in the universe.
Neutron Sources: Plutonium-beryllium neutron sources are used in research reactors, neutron activation analysis, and well-logging in the oil industry to locate underground resources.
| Earth's Crust | N/A |
|---|---|
| Universe | N/A |