Manganese

Category: Transition metal

Atomic Number: 25

Period: 4 | Group: 7

Block: d-block

25
Mn
54.938

Description

Essential in trace amounts, brittle in bulk, and the reason your steel does not shatter in the cold.

Physical Properties

Property Value
Phase at STP Solid
Density N/A
Melting Point 1519.00 K (1245.85 °C)
Boiling Point 2334.00 K (2060.85 °C)
Heat Capacity N/A

Atomic Properties

Property Value
Atomic Mass 54.9380 u
Electronegativity (Pauling) N/A
Oxidation States -3, -1, 0, +1, +2, +3, +4, +5, +6, +7
Electron Configuration

Discovery & History

Discovered By Unknown
Discovery Year 1774
Named After Latin magnes, "magnet"

Black magnesia

The mineral pyrolusite, manganese dioxide, was used as a black pigment in prehistoric cave paintings and later by glassmakers to remove color from glass. It was called black magnesia, after the Magnesia region of Greece, and was long confused with magnetic iron ore.

Scheele and Gahn (1774)

In 1774 Carl Wilhelm Scheele showed that pyrolusite contained a new element. The same year his friend Johan Gottlieb Gahn isolated the impure metal by heating pyrolusite with charcoal.

The name

The name manganese comes, through Italian, from magnesia, the same source as the name of magnesium.

Isotopes

ISOTOPE Neutrons Natural Abundance Half-life Decay Mode
Mn-54 29 - 312.20 days ε/β⁺
Mn-55 30 100% Stable -

Data: IAEA Nuclear Data Section, LiveChart of Nuclides, ground-state evaluations, retrieved October 10, 2026. Abundance is the share of atoms in the natural element; a dash means the isotope has no standard natural abundance.

Applications & Uses

Steel

About 90% of manganese goes into steel. It removes oxygen and binds sulfur, which would otherwise make steel brittle, and it increases strength and hardness. Most steels contain under 1% manganese. Hadfield steel, with about 12 to 14%, hardens under impact and is used for rail crossings, rock crushers and excavator teeth.

Batteries

Disposable batteries: manganese dioxide is the cathode material of alkaline and zinc-carbon batteries.

Lithium-ion batteries: manganese is part of the NMC and lithium manganese oxide cathodes used in electric vehicles.

Other uses

Aluminum alloys: about 1% manganese strengthens the aluminum alloy used for beverage cans.

Chemicals: potassium permanganate treats drinking water and is used as a disinfectant and oxidizer.

Agriculture: manganese sulfate is added to fertilizers and animal feed.

Abundance

Earth's Crust N/A
Universe N/A