67
Ho
Holmium

Holmium

Element 67 • Lanthanide
Atomic Mass 164.930330
Electron Config Unknown
Group/Period ?/6

Physical Properties

MEASURED
Atomic Mass
164.930330 u
Melting Point
1734.00 °C
Boiling Point
2993.00 °C
Ionization Energy
6.02 kJ/mol

Special Properties

CLASSIFIED
STABLE Generally safe to handle with standard precautions

Applications

CATALOGUED

The Magnetic Marvel

Holmium holds the distinction of possessing the highest magnetic moment of any naturally occurring element, making it absolutely indispensable for applications requiring extreme magnetic properties. This remarkable rare earth element has found critical roles in advanced medical procedures, scientific research, and cutting-edge technologies that depend on precise magnetic control.

🏥 Revolutionary Medical Lasers

Holmium:YAG (yttrium aluminum garnet) lasers have transformed modern medicine, particularly in urology, orthopedics, and dermatology. These specialized lasers emit at 2.1 micrometers wavelength, which is perfectly absorbed by water and soft tissues, enabling incredibly precise cutting with minimal collateral damage. Holmium lasers can fragment kidney stones, remove tumors, and perform delicate arthroscopic procedures with unprecedented accuracy.

⚛️ Nuclear Reactor Control Systems

Holmium's exceptional neutron absorption properties make it invaluable for nuclear reactor control applications. Holmium control rods and neutron flux monitors help regulate nuclear reactions with extreme precision. The element's unique nuclear properties enable safe reactor operation and accurate neutron detection in research and power generation facilities.

🧲 Ultra-High Field Magnets

Research laboratories use Holmium in specialized permanent magnets and electromagnets where the highest possible magnetic fields are required. Holmium-based magnetic materials enable breakthrough research in condensed matter physics, materials science, and fundamental particle physics experiments.

📡 Advanced Waveguide Technology

Holmium-doped fiber optic systems serve critical roles in telecommunications and laser technology. These specialized fibers can generate laser light at specific wavelengths essential for long-distance optical communications and precision spectroscopy applications.

🔬 Scientific Calibration Standards

Holmium oxide glass serves as a wavelength calibration standard for UV-visible spectrophotometers worldwide. Its characteristic absorption peaks provide precise reference points for analytical instruments, ensuring accuracy in pharmaceutical quality control, environmental analysis, and materials testing.

🎯 Precision Manufacturing

Holmium's magnetic properties enable ultra-precise positioning systems and magnetic bearings in specialized manufacturing equipment. These applications require the extreme magnetic stability that only Holmium can provide.

Common Uses

INDEXED

🌟 Specialized Applications

  • 🏥 Medical Procedures: Holmium lasers for kidney stone removal, tumor ablation, and arthroscopic surgery
  • 🔬 Laboratory Standards: Spectrophotometer calibration and analytical chemistry references
  • ⚛️ Nuclear Technology: Control rods and neutron detection systems
  • 🧲 Research Magnets: Specialized magnets for physics research and MRI systems
  • 📊 Analytical Instruments: Wavelength standards for UV-visible spectroscopy
  • 🌐 Telecommunications: Fiber optic amplifiers and laser systems

💎 Niche Market Leader

While Holmium applications are highly specialized, they represent critical functions in billion-dollar industries. Medical laser systems alone represent a $4 billion global market, with Holmium lasers commanding premium prices due to their superior performance characteristics.

📈 Growing Demand Sectors

Holmium demand is driven by aging populations requiring more medical procedures, expanding nuclear energy programs, and advanced telecommunications infrastructure. Market growth averages 8-12% annually in key application areas.

🔬 Research Frontiers

Emerging applications include quantum computing components, magnetic refrigeration systems, and advanced medical imaging contrast agents. Holmium's unique magnetic properties continue to open new technological possibilities.

Natural Occurrence

SURVEYED

🌍 Rare but Widespread Distribution

Holmium occurs in Earth's crust at an average concentration of 1.3 parts per million, making it more abundant than silver but still extremely rare. Despite its relative scarcity, Holmium can be found in trace amounts in most rare earth mineral deposits worldwide.

🏔️ Primary Mineral Sources

  • Monazite: Thorium-phosphate mineral in beach sand deposits (0.05% Ho₂O₃)
  • Bastnäsite: Rare earth carbonate in carbonatite complexes
  • Xenotime: Yttrium phosphate mineral rich in heavy rare earths
  • Ion-adsorption clays: Southern China deposits with enhanced Ho content

🌏 Global Production Sources

China (85% of production): Bayan Obo mine in Inner Mongolia and southern China's ion-adsorption clay deposits provide most commercial Holmium. Chinese producers have developed specialized separation techniques optimized for heavy rare earth recovery.

Australia: Mount Weld rare earth project produces Holmium as a byproduct of mixed rare earth concentrate processing.

United States: Mountain Pass mine in California contains Holmium-bearing bastnäsite, though current operations focus on light rare earth recovery.

⚒️ Extraction Process

Holmium separation requires sophisticated multi-stage processes due to its chemical similarity to other lanthanides. Ion-exchange chromatography using specific chelating agents can separate Holmium from adjacent elements erbium and dysprosium. Complete purification may require 50-100 separation stages to achieve 99.9% purity required for medical and scientific applications.

🌊 Marine Deposits

Deep-sea nodules and seafloor sediments contain significant Holmium concentrations, particularly in Pacific Ocean deposits. These unconventional sources may become important as terrestrial reserves face depletion.

♻️ Recovery & Recycling

Holmium recycling from end-of-life medical equipment and laboratory instruments is growing in importance. Specialized recovery processes can reclaim high-purity Holmium from laser components and optical devices, though current recycling rates remain minimal.

🔬 Analytical Challenges

Accurate Holmium analysis requires advanced techniques such as ICP-MS (inductively coupled plasma mass spectrometry) due to spectral interferences from other lanthanides. Precise quantification is essential for quality control in high-value applications.

Discovery

ARCHIVED
1879

🔬 Swiss Precision Discovery

Discovered by: Per Teodor Cleve in Uppsala, Sweden (1878)

Co-discovered by: Marc Delafontaine and Jacques-Louis Soret in Geneva, Switzerland (1878)

Named after: Holmia, the Latin name for Stockholm, Sweden

🧪 Parallel Discovery Achievement

Holmium's discovery represents a remarkable case of simultaneous scientific achievement. In 1878, two independent research groups on opposite sides of Europe identified the same new element using different analytical approaches, demonstrating the reproducibility and rigor of 19th-century analytical chemistry.

Per Teodor Cleve, working at Uppsala University in Sweden, was investigating the rare earth oxide "erbia" when he noticed spectroscopic anomalies suggesting the presence of unknown elements. Using systematic fractional crystallization techniques, Cleve separated erbia into three components, identifying both holmium and thulium in the process.

🇨🇭 The Swiss Connection

Simultaneously, Marc Delafontaine and Jacques-Louis Soret at the University of Geneva were conducting independent spectroscopic studies of rare earth minerals. Their more advanced spectroscopic equipment revealed characteristic absorption lines that didn't match any known elements.

The Swiss team's spectroscopic analysis provided crucial confirmation of Cleve's chemical separation work. Their combined evidence convinced the international scientific community that holmium was indeed a distinct element.

⚗️ Naming Controversy

Initially, both teams proposed different names for their discovered element. Cleve suggested "holmium" after Stockholm (Holmia in Latin), while the Swiss team preferred "spectrium" based on their spectroscopic discovery method. The scientific community ultimately adopted Cleve's nomenclature.

🔬 Purification Challenges

Pure holmium compounds weren't obtained until 1911, when holmium oxide was finally separated from all other rare earth impurities. Metallic holmium wasn't isolated until 1934 using calcium reduction of holmium fluoride.

🏆 Scientific Impact

The discovery of holmium advanced understanding of rare earth chemistry and demonstrated the power of combining chemical separation with spectroscopic analysis. This collaborative approach became the standard methodology for discovering additional rare earth elements.

🔬 Modern Recognition

Today, holmium's unique magnetic properties - unknown to its 19th-century discoverers - have made it indispensable for advanced medical procedures and scientific research. The element that was once merely a scientific curiosity now saves lives daily through holmium laser medical procedures.

Safety Information

CRITICAL

⚠️ Laboratory & Medical Safety

🟡 Low-Moderate Hazard Profile

Holmium and its compounds present relatively low

toxicity risks but require appropriate laboratory safety measures.
Medical-grade Holmium materials demand highest purity and handling standards.

🥽 Standard Protective Measures

  • Eye Protection: Safety glasses required for all handling operations
  • Respiratory Protection: Dust mask when working with powdered compounds
  • Hand Protection: Chemical-resistant gloves for direct handling
  • Clothing Protection: Laboratory coat and closed-toe shoes

⚗️ Specific Hazards

Laser Safety: Holmium:YAG lasers emit invisible 2.1 μm radiation requiring specialized eye protection and controlled access procedures. Class 4 laser safety protocols mandatory.

Dust Control: Holmium oxide powder may cause mild respiratory irritation. Maintain good ventilation and avoid creating airborne dust.

🏥 Medical Application Safety

Medical-grade Holmium compounds must meet USP (United States Pharmacopeia) standards for purity and sterility. Handling requires pharmaceutical-grade clean room procedures and contamination control.

🚨 Emergency Procedures

  • Eye Contact: Flush with clean water for 15 minutes, seek medical evaluation
  • Skin Contact: Wash thoroughly with soap and water
  • Inhalation: Move to fresh air, monitor for respiratory symptoms
  • Laser Exposure: Seek immediate medical attention for suspected eye exposure

🗄️ Storage Protocols

Store Holmium compounds in tightly sealed containers away from moisture and incompatible materials. Medical-grade materials require controlled temperature and humidity conditions to maintain sterility.

♻️ Waste Handling

Collect Holmium-containing waste separately for potential recycling due to its high value and specialized applications. Medical waste requires biohazard disposal procedures regardless of Holmium content.

📊 Exposure Monitoring

Workplace exposure limits: 5 mg/m³ as 8-hour time-weighted average for Holmium compounds. Regular air monitoring recommended in production facilities.

Knowledge Database

Essential information about Holmium (Ho)

Holmium is unique due to its atomic number of 67 and belongs to the Lanthanide category. With an atomic mass of 164.930330, it exhibits distinctive properties that make it valuable for various applications.

Holmium has several important physical properties:

Melting Point: 1734.00 K (1461°C)

Boiling Point: 2993.00 K (2720°C)

State at Room Temperature: solid

Atomic Radius: 176 pm

Holmium has various important applications in modern technology and industry:

The Magnetic Marvel

Holmium holds the distinction of possessing the highest magnetic moment of any naturally occurring element, making it absolutely indispensable for applications requiring extreme magnetic properties. This remarkable rare earth element has found critical roles in advanced medical procedures, scientific research, and cutting-edge technologies that depend on precise magnetic control.

🏥 Revolutionary Medical Lasers

Holmium:YAG (yttrium aluminum garnet) lasers have transformed modern medicine, particularly in urology, orthopedics, and dermatology. These specialized lasers emit at 2.1 micrometers wavelength, which is perfectly absorbed by water and soft tissues, enabling incredibly precise cutting with minimal collateral damage. Holmium lasers can fragment kidney stones, remove tumors, and perform delicate arthroscopic procedures with unprecedented accuracy.

⚛️ Nuclear Reactor Control Systems

Holmium's exceptional neutron absorption properties make it invaluable for nuclear reactor control applications. Holmium control rods and neutron flux monitors help regulate nuclear reactions with extreme precision. The element's unique nuclear properties enable safe reactor operation and accurate neutron detection in research and power generation facilities.

🧲 Ultra-High Field Magnets

Research laboratories use Holmium in specialized permanent magnets and electromagnets where the highest possible magnetic fields are required. Holmium-based magnetic materials enable breakthrough research in condensed matter physics, materials science, and fundamental particle physics experiments.

📡 Advanced Waveguide Technology

Holmium-doped fiber optic systems serve critical roles in telecommunications and laser technology. These specialized fibers can generate laser light at specific wavelengths essential for long-distance optical communications and precision spectroscopy applications.

🔬 Scientific Calibration Standards

Holmium oxide glass serves as a wavelength calibration standard for UV-visible spectrophotometers worldwide. Its characteristic absorption peaks provide precise reference points for analytical instruments, ensuring accuracy in pharmaceutical quality control, environmental analysis, and materials testing.

🎯 Precision Manufacturing

Holmium's magnetic properties enable ultra-precise positioning systems and magnetic bearings in specialized manufacturing equipment. These applications require the extreme magnetic stability that only Holmium can provide.

1879

🔬 Swiss Precision Discovery

Discovered by: Per Teodor Cleve in Uppsala, Sweden (1878)

Co-discovered by: Marc Delafontaine and Jacques-Louis Soret in Geneva, Switzerland (1878)

Named after: Holmia, the Latin name for Stockholm, Sweden

🧪 Parallel Discovery Achievement

Holmium's discovery represents a remarkable case of simultaneous scientific achievement. In 1878, two independent research groups on opposite sides of Europe identified the same new element using different analytical approaches, demonstrating the reproducibility and rigor of 19th-century analytical chemistry.

Per Teodor Cleve, working at Uppsala University in Sweden, was investigating the rare earth oxide "erbia" when he noticed spectroscopic anomalies suggesting the presence of unknown elements. Using systematic fractional crystallization techniques, Cleve separated erbia into three components, identifying both holmium and thulium in the process.

🇨🇭 The Swiss Connection

Simultaneously, Marc Delafontaine and Jacques-Louis Soret at the University of Geneva were conducting independent spectroscopic studies of rare earth minerals. Their more advanced spectroscopic equipment revealed characteristic absorption lines that didn't match any known elements.

The Swiss team's spectroscopic analysis provided crucial confirmation of Cleve's chemical separation work. Their combined evidence convinced the international scientific community that holmium was indeed a distinct element.

⚗️ Naming Controversy

Initially, both teams proposed different names for their discovered element. Cleve suggested "holmium" after Stockholm (Holmia in Latin), while the Swiss team preferred "spectrium" based on their spectroscopic discovery method. The scientific community ultimately adopted Cleve's nomenclature.

🔬 Purification Challenges

Pure holmium compounds weren't obtained until 1911, when holmium oxide was finally separated from all other rare earth impurities. Metallic holmium wasn't isolated until 1934 using calcium reduction of holmium fluoride.

🏆 Scientific Impact

The discovery of holmium advanced understanding of rare earth chemistry and demonstrated the power of combining chemical separation with spectroscopic analysis. This collaborative approach became the standard methodology for discovering additional rare earth elements.

🔬 Modern Recognition

Today, holmium's unique magnetic properties - unknown to its 19th-century discoverers - have made it indispensable for advanced medical procedures and scientific research. The element that was once merely a scientific curiosity now saves lives daily through holmium laser medical procedures.

Discovered by: <div class="discovery-section"> <h3>🔬 Swiss Precision Discovery</h3> <p><strong>Discovered by:</strong> Per Teodor Cleve in Uppsala, Sweden (1878)</p> <p><strong>Co-discovered by:</strong> Marc Delafontaine and Jacques-Louis Soret in Geneva, Switzerland (1878)</p> <p><strong>Named after:</strong> Holmia, the Latin name for Stockholm, Sweden</p> <h4>🧪 Parallel Discovery Achievement</h4> <p>Holmium's discovery represents a remarkable case of simultaneous scientific achievement. In 1878, two independent research groups on opposite sides of Europe identified the same new element using different analytical approaches, demonstrating the reproducibility and rigor of 19th-century analytical chemistry.</p> <p>Per Teodor Cleve, working at Uppsala University in Sweden, was investigating the rare earth oxide "erbia" when he noticed spectroscopic anomalies suggesting the presence of unknown elements. Using systematic fractional crystallization techniques, Cleve separated erbia into three components, identifying both holmium and thulium in the process.</p> <h4>🇨🇭 The Swiss Connection</h4> <p>Simultaneously, Marc Delafontaine and Jacques-Louis Soret at the University of Geneva were conducting independent spectroscopic studies of rare earth minerals. Their more advanced spectroscopic equipment revealed characteristic absorption lines that didn't match any known elements.</p> <p>The Swiss team's spectroscopic analysis provided crucial confirmation of Cleve's chemical separation work. Their combined evidence convinced the international scientific community that holmium was indeed a distinct element.</p> <h4>⚗️ Naming Controversy</h4> <p>Initially, both teams proposed different names for their discovered element. Cleve suggested "holmium" after Stockholm (Holmia in Latin), while the Swiss team preferred "spectrium" based on their spectroscopic discovery method. The scientific community ultimately adopted Cleve's nomenclature.</p> <h4>🔬 Purification Challenges</h4> <p>Pure holmium compounds weren't obtained until 1911, when holmium oxide was finally separated from all other rare earth impurities. Metallic holmium wasn't isolated until 1934 using calcium reduction of holmium fluoride.</p> <h4>🏆 Scientific Impact</h4> <p>The discovery of holmium advanced understanding of rare earth chemistry and demonstrated the power of combining chemical separation with spectroscopic analysis. This collaborative approach became the standard methodology for discovering additional rare earth elements.</p> <h4>🔬 Modern Recognition</h4> <p>Today, holmium's unique magnetic properties - unknown to its 19th-century discoverers - have made it indispensable for advanced medical procedures and scientific research. The element that was once merely a scientific curiosity now saves lives daily through holmium laser medical procedures.</p> </div>

Year of Discovery: 1879

🌍 Rare but Widespread Distribution

Holmium occurs in Earth's crust at an average concentration of 1.3 parts per million, making it more abundant than silver but still extremely rare. Despite its relative scarcity, Holmium can be found in trace amounts in most rare earth mineral deposits worldwide.

🏔️ Primary Mineral Sources

  • Monazite: Thorium-phosphate mineral in beach sand deposits (0.05% Ho₂O₃)
  • Bastnäsite: Rare earth carbonate in carbonatite complexes
  • Xenotime: Yttrium phosphate mineral rich in heavy rare earths
  • Ion-adsorption clays: Southern China deposits with enhanced Ho content

🌏 Global Production Sources

China (85% of production): Bayan Obo mine in Inner Mongolia and southern China's ion-adsorption clay deposits provide most commercial Holmium. Chinese producers have developed specialized separation techniques optimized for heavy rare earth recovery.

Australia: Mount Weld rare earth project produces Holmium as a byproduct of mixed rare earth concentrate processing.

United States: Mountain Pass mine in California contains Holmium-bearing bastnäsite, though current operations focus on light rare earth recovery.

⚒️ Extraction Process

Holmium separation requires sophisticated multi-stage processes due to its chemical similarity to other lanthanides. Ion-exchange chromatography using specific chelating agents can separate Holmium from adjacent elements erbium and dysprosium. Complete purification may require 50-100 separation stages to achieve 99.9% purity required for medical and scientific applications.

🌊 Marine Deposits

Deep-sea nodules and seafloor sediments contain significant Holmium concentrations, particularly in Pacific Ocean deposits. These unconventional sources may become important as terrestrial reserves face depletion.

♻️ Recovery & Recycling

Holmium recycling from end-of-life medical equipment and laboratory instruments is growing in importance. Specialized recovery processes can reclaim high-purity Holmium from laser components and optical devices, though current recycling rates remain minimal.

🔬 Analytical Challenges

Accurate Holmium analysis requires advanced techniques such as ICP-MS (inductively coupled plasma mass spectrometry) due to spectral interferences from other lanthanides. Precise quantification is essential for quality control in high-value applications.

General Safety: Holmium should be handled with standard laboratory safety precautions including protective equipment and proper ventilation.

⚠️ Laboratory & Medical Safety

🟡 Low-Moderate Hazard Profile

Holmium and its compounds present relatively low

toxicity risks but require appropriate laboratory safety measures.
Medical-grade Holmium materials demand highest purity and handling standards.

🥽 Standard Protective Measures

  • Eye Protection: Safety glasses required for all handling operations
  • Respiratory Protection: Dust mask when working with powdered compounds
  • Hand Protection: Chemical-resistant gloves for direct handling
  • Clothing Protection: Laboratory coat and closed-toe shoes

⚗️ Specific Hazards

Laser Safety: Holmium:YAG lasers emit invisible 2.1 μm radiation requiring specialized eye protection and controlled access procedures. Class 4 laser safety protocols mandatory.

Dust Control: Holmium oxide powder may cause mild respiratory irritation. Maintain good ventilation and avoid creating airborne dust.

🏥 Medical Application Safety

Medical-grade Holmium compounds must meet USP (United States Pharmacopeia) standards for purity and sterility. Handling requires pharmaceutical-grade clean room procedures and contamination control.

🚨 Emergency Procedures

  • Eye Contact: Flush with clean water for 15 minutes, seek medical evaluation
  • Skin Contact: Wash thoroughly with soap and water
  • Inhalation: Move to fresh air, monitor for respiratory symptoms
  • Laser Exposure: Seek immediate medical attention for suspected eye exposure

🗄️ Storage Protocols

Store Holmium compounds in tightly sealed containers away from moisture and incompatible materials. Medical-grade materials require controlled temperature and humidity conditions to maintain sterility.

♻️ Waste Handling

Collect Holmium-containing waste separately for potential recycling due to its high value and specialized applications. Medical waste requires biohazard disposal procedures regardless of Holmium content.

📊 Exposure Monitoring

Workplace exposure limits: 5 mg/m³ as 8-hour time-weighted average for Holmium compounds. Regular air monitoring recommended in production facilities.

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