Bromine

Category: Halogen

Atomic Number: 35

Period: 4 | Group: 17

Block: p-block

35
Br
79.904

Description

One of only two elements that are liquid at room temperature, and the one that smells like a swimming pool from hell.

Physical Properties

Property Value
Phase at STP Liquid
Density N/A
Melting Point 265.80 K (-7.35 °C)
Boiling Point 332.00 K (58.85 °C)
Heat Capacity N/A

Atomic Properties

Property Value
Atomic Mass 79.9040 u
Electronegativity (Pauling) N/A
Oxidation States -1, +1, +3, +5, +7
Electron Configuration

Discovery & History

Discovered By Unknown
Discovery Year 1826
Named After Greek bromos, "stench"

Two discoverers (1825 and 1826)

In 1825 the German student Carl Jacob Löwig obtained a red-brown liquid from the water of a mineral spring at Bad Kreuznach, but his publication was delayed. In 1826 Antoine-Jérôme Balard, a young chemist in Montpellier, found the same substance in the brine of salt marshes after treating it with chlorine, and published first, so he is credited with the discovery.

The name

Balard first proposed the name muride, from the Latin muria, brine; it was changed to brome, from the Greek bromos, meaning stench, because of its strong smell.

Early uses

Bromides were soon used in photography and, from the 1850s, as the first effective sedatives and anticonvulsants.

Isotopes

ISOTOPE Neutrons Natural Abundance Half-life Decay Mode
Br-79 44 50.65% Stable -
Br-81 46 49.35% Stable -

Data: IAEA Nuclear Data Section, LiveChart of Nuclides, ground-state evaluations, retrieved October 10, 2026. Abundance is the share of atoms in the natural element; a dash means the isotope has no standard natural abundance.

Applications & Uses

Flame retardants

The largest use of bromine is in brominated flame retardants for plastics in electronics, cables, insulation and furniture. Some of these, such as polybrominated diphenyl ethers (PBDEs), persist in the environment and are now banned or restricted under the Stockholm Convention.

Oil and gas, water and energy

Drilling fluids: dense solutions of calcium, sodium and zinc bromide control pressure in oil and gas wells.

Water treatment: bromine compounds disinfect swimming pools, hot tubs and cooling towers.

Mercury control: adding bromide to coal helps capture mercury from power plant emissions.

Batteries: zinc-bromine flow batteries store electricity for the grid.

Chemicals and medicine

Bromine is a building block for pharmaceuticals, dyes and agricultural chemicals, and silver bromide was the light-sensitive compound of photographic film. Methyl bromide, once a widely used soil fumigant, has been phased out under the Montreal Protocol, apart from quarantine and pre-shipment uses, because it damages the ozone layer. Ethylene dibromide, once added to leaded gasoline, largely disappeared with leaded fuel.

Abundance

Earth's Crust N/A
Universe N/A