Astatine

Category: Metalloid

Atomic Number: 85

Period: 6 | Group: 17

Block: p-block

85
At
210.000

Description

The rarest naturally occurring element on Earth — perhaps 25 grams exist in the entire crust at any moment.

Physical Properties

Property Value
Phase at STP Solid
Density N/A
Melting Point 575.00 K (301.85 °C)
Boiling Point 610.00 K (336.85 °C)
Heat Capacity N/A

Atomic Properties

Property Value
Atomic Mass 210.0000 u
Electronegativity (Pauling) N/A
Oxidation States -1, +1, +3, +5, +7
Electron Configuration

Discovery & History

Discovered By Unknown
Discovery Year 1940
Named After Greek astatos, "unstable"

A missing halogen

Mendeleev's periodic table left a gap below iodine for an element he called eka-iodine. Several claims to have found it in nature, under names such as alabamine (1931) and helvetium (1940), could not be confirmed.

Made at Berkeley (1940)

In 1940 Dale R. Corson, Kenneth Ross MacKenzie and Emilio Segrè at the University of California, Berkeley, produced element 85 by bombarding bismuth-209 with alpha particles in a cyclotron, making astatine-211.

Found in nature (1943)

In 1943 Berta Karlik and Traude Bernert in Vienna detected astatine isotopes in the natural decay chains of uranium and thorium.

The name (1947)

The discoverers named the element astatine in 1947, from the Greek astatos, meaning unstable.

Isotopes

ISOTOPE Neutrons Natural Abundance Half-life Decay Mode
At-207 122 - 1.81 hr ε/β⁺ (91.4%), α (8.6%)
At-208 123 - 1.63 hr ε/β⁺
At-209 124 - 5.42 hr ε/β⁺ (95.9%), α (4.1%)
At-210 125 - 8.1 hr ε/β⁺
At-211 126 - 7.214 hr ε (58.2%), α (41.8%)

Data: IAEA Nuclear Data Section, LiveChart of Nuclides, ground-state evaluations, retrieved October 10, 2026. Abundance is the share of atoms in the natural element; a dash means the isotope has no standard natural abundance.

Applications & Uses

Cancer therapy research

Astatine is used only in research, mainly in nuclear medicine. Astatine-211 emits alpha particles that travel only a few cell widths, so when it is attached to antibodies or other molecules that seek out cancer cells, it can destroy them with little damage to nearby tissue. This targeted alpha therapy is being tested in clinical trials.

Chemistry research

Chemists study astatine using only billionths of a gram at a time, with tracer techniques. These experiments test how relativistic effects change the chemistry of heavy elements and show that astatine behaves partly like iodine and partly like a metal.

Abundance

Earth's Crust N/A
Universe N/A